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US4444873A Expired / Lapsed US ⏱️ 0.0 years remaining

Color photographic processing

Assignee: Fujifilm Holdings Corp
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Filing: 1982-12-29
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Granted: 1984-04-24
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Expires: 2002-12-29
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Abstract

Abstract A process for processing a silver halide color photographic material is disclosed. The process particularly relates to bleaching and fixing of a color developed silver halide color photographic material. The color developed material is processed with an acid bleaching solution containing a ferric salt, inorganic salt and a halide. Immediately after the bleaching step, the photographic material is processed with the fixing solution containing 5 g/l to 50 g/l of polycarboxylic acids. By utilizing the bleaching and fixing steps disclosed it is possible to process a silver halide color photographic material rapidly utilizing a reduced number of baths, obtain an excellent bleaching rate and produce an image having excellent stability.

Inventors

  • 👤 Takatoshi Ishikawa
  • 👤 Kiyoshi Imai
  • 👤 Mamoru Tashiro
  • 👤 Junya Nakajima

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 16:22
CPC Classifications
G; G03; G03C; G03C7/00; G03C7/30; G03C7/42; G03C7/421

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 55 words
A process for bleaching and fixing a color developed silver halide color photographic material, comprising the steps of: processing the photographic material with an acid bleaching solution containing a ferric salt, an organic acid and a halide; and processing the bleached photographic material with a fixing solution containing 5g/l to 50 g/l of polycarboxylic acids.
Claim 2
Dependent Claim 55 words
A process for bleaching and fixing a color developed silver halide color photographic material, comprising the steps of: processing the photographic material with an acid bleaching solution containing a ferric salt, an organic acid and a halide; and processing the bleached photographic material with a fixing solution containing 5g/l to 50 g/l of polycarboxylic acids.
Claim 3
Dependent Claim 29 words
A process for bleaching and fixing as claimed in claim 1, wherein the ferric salt is selected from the group consisting of ferric chloride, ferric bromide and ferric citrate.
Claim 4
Dependent Claim 27 words
A process for bleaching and fixing as claimed in claim 2, wherein the ferric salt is selected from the group consisting of ferric chloride and ferric bromide.
Claim 5
Dependent Claim 26 words
A process for bleaching and fixing as claimed in claim 1, wherein the organic acid is selected from the group consisting of water-soluble aliphatic carboxylic acids.
Claim 6
Dependent Claim 29 words
A process for bleaching and fixing as claimed in claim 4, wherein the organic acid is selected from the group consisting of citric acid and the water-soluble salts thereof.
Claim 7
Dependent Claim 31 words
A process for bleaching and fixing as claimed in claim 1, wherein the ferric salts are present in an amount of 10 g to 400 g per liter of bleaching solution.
Claim 8
Dependent Claim 31 words
A process for bleaching and fixing as claimed in claim 1, wherein the organic acid is present in an amount of 5 g to 300 g per liter of bleaching solution.
Claim 9
Dependent Claim 30 words
A process for bleaching and fixing as claimed in claim 1, wherein the halide is present in an amount of 2 g to 200 g per liter of bleaching solution.
Claim 10
Dependent Claim 69 words
A process for bleaching and fixing as claimed in claim 1, wherein the ferric salt is present in an amount of 20 g to 300 g per liter of bleaching solution, the organic acid is present in an amount of 10 g to 100 g per liter of bleaching solution and the halide is present in an amount of 5 g to 100 g per liter of bleaching solution.
Claim 11
Dependent Claim 22 words
A process for bleaching and fixing as claimed in claim 1, wherein the bleaching solution has a pH of 3 or less.
Claim 12
Dependent Claim 22 words
A process for bleaching and fixing as claimed in claim 10, wherein the bleaching solution has a pH of 1 or less.
Claim 13
Dependent Claim 24 words
A process for bleaching and fixing as claimed in claim 1, wherein the fixing solution contains 10 g/l to 40 g/l of polycarboxylic acids.
Claim 14
Dependent Claim 38 words
A process for bleaching and fixing as claimed in claim 1, wherein the polycarboxylic acid is selected from the group consisting of ethylenediaminetetraacetic acid, diethylenetriaminepentaacetic acid, ethylenediamine-N-(β-oxyethyl)-N,N', N'-triacetic acid and propylenediaminetetraacetic acid, and sodium and potassium salts thereof.
Claim 15
Dependent Claim 25 words
A process for bleaching and fixing as claimed in claim 1, wherein the fixing solution has a pH within the range of 5 to 9.

References Cited (Backward Citations)

US3997348A Cited
US4277556A Cited
US4301236A Cited
US4292401A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-04-24 1987-10-24 1988-04-24 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-04-24 1991-10-24 1992-04-24 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-04-24 1995-10-24 1996-04-24 $7700.00 Window Closed / Lapsed

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