Patent US4444922A successfully refreshed from Google Patents.
US4444922A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Low energy polymer-solvent separations
Assignee: Massachusetts Institute of Technology
•
Filing: 1981-09-08
•
Granted: 1984-04-24
•
Expires: 2001-09-08
Abstract
Abstract A method for processing a polymer solution by changing the thermodynamic state of the solution to produce a dilute phase and a concentrated phase such that the thermodynamic state is sufficiently changed that the two phases are formed by spinodal decomposition.
Inventors
- 👤 Timothy G. Gutowski
- 👤 Nam P. Suh
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 12:33
CPC Classifications
C; C08; C08C; C08C2/00
Claims Analysis
Total Claims: 23
Claim 1
Independent Claim
95 words
A method for processing a conjugated diene polymer solution, the conjugated diene chosen from the group of polybutadiene and isoprene, the method comprising the steps of: (a) rapidly changing the thermodynamic state of said solution so as to produce a first phase having a relatively low polymer concentration and a second phase having a relatively high polymer concentration, said thermodynamic state being sufficiently changed that said first and said second phases are formed by spinodal decomposition; (b) permitting said second phase to separate physically from said first phase; and (c) removing said separated second phase.
Claim 2
Independent Claim
95 words
A method for processing a conjugated diene polymer solution, the conjugated diene chosen from the group of polybutadiene and isoprene, the method comprising the steps of: (a) rapidly changing the thermodynamic state of said solution so as to produce a first phase having a relatively low polymer concentration and a second phase having a relatively high polymer concentration, said thermodynamic state being sufficiently changed that said first and said second phases are formed by spinodal decomposition; (b) permitting said second phase to separate physically from said first phase; and (c) removing said separated second phase.
Claim 3
Independent Claim
116 words
A method for processing a conjugated diene polymer solution, the conjugated diene chosen from the group of polybutadiene and isoprene, and the solution having a first polymer concentration, the method comprising the steps of: (a) adding a solvent to said solution to dilute said solution so as to produce a solution having a second polymer concentration lower than said first polymer concentration; (b) rapidly heating said diluted solution to a temperature sufficient to form by spinodal decomposition, a first phase having a relatively low polymer concentration and a second phase having a relatively high polymer concentration; (c) permitting said second phase to separate from said first phase by gravity; and (d) removing said separated second phase.
Claim 4
Independent Claim
116 words
A method for processing a conjugated diene polymer solution, the conjugated diene chosen from the group of polybutadiene and isoprene, and the solution having a first polymer concentration, the method comprising the steps of: (a) adding a solvent to said solution to dilute said solution so as to produce a solution having a second polymer concentration lower than said first polymer concentration; (b) rapidly heating said diluted solution to a temperature sufficient to form by spinodal decomposition, a first phase having a relatively low polymer concentration and a second phase having a relatively high polymer concentration; (c) permitting said second phase to separate from said first phase by gravity; and (d) removing said separated second phase.
Claim 5
Dependent Claim
20 words
The method of claim 2 wherein the step of adding solvent further comprises adding a heated solvent to said solution.
Claim 6
Dependent Claim
30 words
The method of claim 2 wherein the method further comprises recycling at least a portion of said first, separated, phase to dilute said solution to said solution of second concentration.
Claim 7
Dependent Claim
33 words
The method of claim 4 wherein the step of feeding back at least a portion of said solvent phase further comprises heating and then recycling at least a portion of said solvent phase.
Claim 8
Dependent Claim
29 words
The method of claim 4 wherein the method further comprises removing moisture from said first, separated, solvent phase prior to recycling said phase back to dilute said incoming solution.
Claim 9
Dependent Claim
33 words
A method for separating polybutadiene-hexane solutions according to the method of claim 2 wherein the step of heating said dilute solution further comprises heating said dilute solution to a temperature above 130° C.
Claim 10
Dependent Claim
48 words
A method for separating polybutadiene-hexane solutions according to the method of claim 2 wherein the method further comprises starting with a polymer solution with an initial concentration of at least about 5 percent polymer and diluting said solution to a concentration not less than about 3 percent polymer.
Claim 11
Independent Claim
135 words
A method for processing a conjugated diene polymer solution, the conjugated diene chosen from the group of polybutadiene and isoprene, and the solution being at first pressure, the method comprising the steps of: (a) raising the pressure of said solution to a second pressure substantially higher than said first pressure; (b) heating said solution at said second pressure to a level below the temperature at which said solution decomposes into two phases; (c) rapidly reducing the pressure of said heated solution to a third pressure sufficiently low to cause said solution to form by spinodal decomposition, a first phase having a relatively low polymer concentration and a second phase having a relatively high polymer concentration; (d) permitting said second phase to separate from said first phase by gravity; and (e) removing said separated second phase.
Claim 12
Independent Claim
135 words
A method for processing a conjugated diene polymer solution, the conjugated diene chosen from the group of polybutadiene and isoprene, and the solution being at first pressure, the method comprising the steps of: (a) raising the pressure of said solution to a second pressure substantially higher than said first pressure; (b) heating said solution at said second pressure to a level below the temperature at which said solution decomposes into two phases; (c) rapidly reducing the pressure of said heated solution to a third pressure sufficiently low to cause said solution to form by spinodal decomposition, a first phase having a relatively low polymer concentration and a second phase having a relatively high polymer concentration; (d) permitting said second phase to separate from said first phase by gravity; and (e) removing said separated second phase.
Claim 13
Dependent Claim
22 words
The method of claim 9 which method further compreses recycling said first phase for reuse in forming said solution to be processed.
Claim 14
Dependent Claim
19 words
The method of claim 10 wherein the step of recycling further comprises heating and then recycling said first phase.
Claim 15
Dependent Claim
32 words
A method for separating polybutadiene-hexane solutions according to the method of claim 9 wherein the step of pressurizing said solution further comprises raising said solution to a second pressure above 450 psi.
Claim 16
Dependent Claim
34 words
A method for separating polybutadiene-hexane solutions according to the method of claim 9 wherein the step of heating said solution at said second pressure further comprises heating said solution to temperature above 130° C.
Claim 17
Independent Claim
77 words
A method for processing a conjugated diene polymer solution, the conjugated diene chosen from the group of polybutadiene and isoprene, and the solution being at an elevated pressure and temperature, the method comprising the step of rapidly reducing the pressure of said heated solution to a pressure sufficiently low to cause said solution to form by spinodal decomposition a first phase having a relatively low polymer concentration and a second phase having a relatively high polymer concentration.
Claim 18
Independent Claim
77 words
A method for processing a conjugated diene polymer solution, the conjugated diene chosen from the group of polybutadiene and isoprene, and the solution being at an elevated pressure and temperature, the method comprising the step of rapidly reducing the pressure of said heated solution to a pressure sufficiently low to cause said solution to form by spinodal decomposition a first phase having a relatively low polymer concentration and a second phase having a relatively high polymer concentration.
Claim 19
Independent Claim
144 words
A method for processing a conjugated diene polymer solution, the conjugated diene chosen from the group of polybutadiene and isoprene, and the solution having a first polymer concentration at a first pressure, the method comprising the steps of; (a) adding solvent to said solution to dilute the solution to a second, lower, concentration; (b) raising the pressure of said solution at said second concentration to a second pressure substantially higher than said first pressure; (c) heating said solution at said second pressure and said second concentration to a level below the temperature at which said solution decomposes into two solvent phases; (d) rapidly reducing the pressure of said heated solution to a third pressure sufficiently low to cause said solution to form by spinodal decomposition, a first phase having a relatively low polymer concentration and a second phase having a relatively high polymer concentration.
Claim 20
Independent Claim
144 words
A method for processing a conjugated diene polymer solution, the conjugated diene chosen from the group of polybutadiene and isoprene, and the solution having a first polymer concentration at a first pressure, the method comprising the steps of; (a) adding solvent to said solution to dilute the solution to a second, lower, concentration; (b) raising the pressure of said solution at said second concentration to a second pressure substantially higher than said first pressure; (c) heating said solution at said second pressure and said second concentration to a level below the temperature at which said solution decomposes into two solvent phases; (d) rapidly reducing the pressure of said heated solution to a third pressure sufficiently low to cause said solution to form by spinodal decomposition, a first phase having a relatively low polymer concentration and a second phase having a relatively high polymer concentration.
Claim 21
Dependent Claim
17 words
The method of claim 15 wherein the step of adding solvent further comprises adding a heated solvent.
Claim 22
Dependent Claim
19 words
A method of processing polybutadiene polymers in non-polar solvent solutions according to claim 1, 2, 9, 14, or 15.
Claim 23
Dependent Claim
19 words
A method of processing polyisoprene polymers in hexane solvent solutions according to claim 1, 2, 9, 14, or 15.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1987-04-24 | 1987-10-24 | 1988-04-24 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1991-04-24 | 1991-10-24 | 1992-04-24 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1995-04-24 | 1995-10-24 | 1996-04-24 | $7700.00 | Window Closed / Lapsed |