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US4448895A
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Process for preparation of catalyst for cleaning exhaust gases and catalyst prepared by the process
Assignee: Nippon Shokubai Co Ltd
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Filing: 1982-11-04
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Granted: 1984-05-15
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Expires: 2002-11-04
Abstract
Abstract A process for preparing a catalyst for cleaning exhaust gases comprising a refractory carrier composed mainly of alumina and having deposited thereon, iron oxide, cerium oxide and at least one noble metal element, which comprises impregnating said carrier with (a) an aqueous solution A prepared by adding aqueous ammonia to an aqueous solution containing a water-soluble iron salt as a material for iron and a cerium salt of an organic acid as a material for cerium to adjust the pH of the aqueous solution to 6.0-9.0, and optionally adding an ammonium salt of an organic acid, and (b) an aqueous solution B containing a compound of the noble metal element.
Inventors
- 👤 Tetsuji Ono
- 👤 Kazuo Tsuchitani
- 👤 Shin Yamauchi
- 👤 Kiyoshi Yonehara
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-26 16:13
CPC Classifications
B; B01; B01D; B01D53/00; B01D53/34; B01D53/92; B01D53/94; B01D53/9445; B01D53/945; B01J; B01J23/00; B01J23/70; B01J23/89; B01J23/8933; B01J23/894; Y; Y02; Y02T; Y02T10/00; Y02T10/10; Y02T10/12
Claims Analysis
Total Claims: 12
Claim 1
Independent Claim
141 words
A process for preparing a catalyst for cleaning exhaust gases comprising a refractory carrier composed mainly of alumina and having deposited thereon, iron oxide, cerium oxide and at least one platinum group noble metal element, which comprises impregnating said carrier with (a) an aqueous solution A prepared by adding aqueous ammonia to an aqueous solution containing a water-soluble iron salt as a material for iron and a cerium salt of an organic acid as a material for cerium to adjust the pH of the aqueous solution to 6.0-9.0, and optionally adding an ammonium salt of an organic acid, and (b) an aqueous solution B containing a compound of the platinum group noble metal element; drying and calcining said impregnated carrier, the catalyst containing 0.5 to 20 g of iron and 0.5 to 20 g of cerium per liter of the catalyst.
Claim 2
Dependent Claim
141 words
A process for preparing a catalyst for cleaning exhaust gases comprising a refractory carrier composed mainly of alumina and having deposited thereon, iron oxide, cerium oxide and at least one platinum group noble metal element, which comprises impregnating said carrier with (a) an aqueous solution A prepared by adding aqueous ammonia to an aqueous solution containing a water-soluble iron salt as a material for iron and a cerium salt of an organic acid as a material for cerium to adjust the pH of the aqueous solution to 6.0-9.0, and optionally adding an ammonium salt of an organic acid, and (b) an aqueous solution B containing a compound of the platinum group noble metal element; drying and calcining said impregnated carrier, the catalyst containing 0.5 to 20 g of iron and 0.5 to 20 g of cerium per liter of the catalyst.
Claim 3
Dependent Claim
20 words
The process of claim 1 wherein an iron salt of an organic salt is used as the material for iron.
Claim 4
Dependent Claim
21 words
The process of claim 2 wherein the iron salt of an organic acid is basic iron acetate or ammonium iron citrate.
Claim 5
Dependent Claim
15 words
The process of claim 1 wherein cerous acetate is used as the material for cerium.
Claim 6
Dependent Claim
71 words
The process of any one of claims 1 to 4 wherein one of the aqueous solutions A and B was impregnated in an amount 0.7 to 1.3 times the saturated amount of water absorbable by the carrier, water is fully removed from the carrier, and then the other aqueous solution is impregnated in the carrier in an amount 0.7 to 1.3 times the saturated amount of water absorbable by the carrier.
Claim 7
Dependent Claim
41 words
The process of any one of claims 1 to 4 wherein a mixture of the aqueous solutions A and B is impregnated in the carrier in an amount 0.7 to 1.3 times the saturated amount of water absorbable by the carrier.
Claim 8
Dependent Claim
50 words
The process of claim 5 wherein the aqueous solution B containing a compound of at least one platinum group noble metal and the aqueous solution A which further contains a compound of at least one platinum group noble metal other than the one in the aqueous solution B are used.
Claim 9
Dependent Claim
136 words
The process of any one of claims 1 to 4 wherein the aqueous solution B containing a compound of at least one platinum group noble metal and the aqueous solution A which further contains a compound of at least one platinum group noble metal other than the one used in the aqueous solution B are used, and first one of the aqueous solutions is impregnated in the carrier in an amount 0.15 to 0.85 times the saturated amount of water absorbable by the carrier, and subsequently without drying, the other aqueous solution is impregnated in the carrier in an amount 0.15 to 0.85 times the saturated amount of water absorbable by the carrier, the total amount of the two aqueous solutions impregnated being 0.7 to 1.3 times the saturated amount of water absorbable by the carrier.
Claim 10
Dependent Claim
25 words
The process of any one of claims 1 to 8 wherein the platinum group noble metal compound is a compound of platinum, palladium or rhodium.
Claim 11
Dependent Claim
33 words
The process of claim 7 or 8 wherein the aqueous solution B containing a compound of rhodium and the aqueous solution A which further contains a compound of platinum and/or palladium are used.
Claim 12
Dependent Claim
103 words
A catalyst for cleaning exhaust gases prepared by the process of any one of claims 1 to 10, said catalyst comprising an alumina carrier having an apparent density of not more than 0.8 g/cc, a BET surface area of 25 to 300 m 2 /g, an average pore diameter of 60 to 1000 Å, a total pore volume of at least 0.5 cc/g and an average diameter of at least 2 mm, and substantial portions of catalyst ingredients deposited in that region of the alumina carrier which leads to a depth of about 300 microns toward the inside the carrier from its surface.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1987-05-15 | 1987-11-14 | 1988-05-15 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1991-05-15 | 1991-11-14 | 1992-05-15 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1995-05-15 | 1995-11-14 | 1996-05-15 | $7700.00 | Window Closed / Lapsed |