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Electrical device containing a radiation-sensitive polyimide precursor composition derived from a diaryl fluoro compound

Assignee: EIDP Inc
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Filing: 1982-09-29
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Granted: 1984-06-12
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Expires: 2002-09-29
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Abstract

Abstract An electrical device coated with a polymerized polyimide structure resulting from a radiation-sensitive polyimide precursor composition which comprises a polymer of the formula ##STR1## wherein n is a positive integer corresponding to the number of units in the polymer and is sufficiently large to provide the polymer with a number average molecular weight of about 1500-15,000 as determined by vapor pressure osmometry, and wherein for any particular unit in the polymer:→denotes isomerism; R 1 is a divalent aromatic, aliphatic or cycloaliphatic radical containing at least 2 carbon atoms; R 2 and R 3 are selected from the group consisting of a hydrogen radical and any organic radical containing a photopolymerizable olefinic double bond; and R 4 and R 5 are selected from the group consisting of perfluoro and perhalofluoro aliphatic hydrocarbons having 1 to 8 carbons.

Inventors

  • 👤 David L. Goff

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 02:59
CPC Classifications
C; C08; C08F; C08F290/00; C08F290/08; C08F290/14; C08G; C08G73/00; C08G73/06; C08G73/10; C08G73/1039; C08L; C08L79/00; C08L79/04; C08L79/08; G; G03; G03F; G03F7/00; G03F7/004; G03F7/027; G03F7/032; G03F7/037; Y; Y10; Y10S; Y10S430/00; Y10S430/1053; Y10S430/1055; Y10S430/114; Y10S430/117; Y10S430/12

Claims Analysis

Total Claims: 4
Claim 1
Independent Claim 175 words
An electrical device coated with a polymerized polyimide structure resulting from a radiation-sensitive polyimide precursor composition, said precursor composition comprising: a. a polymer of the formula ##STR14## wherein n is a positive integer corresponding to the number of units in the polymer and is sufficiently large to provide the polymer with a number average molecular weight of about 1500-15,000 as determined by vapor pressure osmometry, and wherein for any particular unit in the polymer: → denotes isomerism; R 1 is a divalent aromatic, aliphatic or cycloaliphatic radical containing at least 2 carbon atoms; R 2 and R 3 are selected from the group consisting of a hydrogen radical and any organic radical containing a photopolymerizable olefinic double bond, at least one of R 2 and R 3 being said organic radical; and R 4 and R 5 are selected from the group consisting of perfluoro and perhalofluoro aliphatic hydrocarbons having 1 to 8 carbons; b. a radiation sensitive polymerizable polyfunctional acrylate compound; and c. a photopolymerization initiator system comprising hydrogen donor initiator and aromatic biimidazole.
Claim 2
Dependent Claim 175 words
An electrical device coated with a polymerized polyimide structure resulting from a radiation-sensitive polyimide precursor composition, said precursor composition comprising: a. a polymer of the formula ##STR14## wherein n is a positive integer corresponding to the number of units in the polymer and is sufficiently large to provide the polymer with a number average molecular weight of about 1500-15,000 as determined by vapor pressure osmometry, and wherein for any particular unit in the polymer: → denotes isomerism; R 1 is a divalent aromatic, aliphatic or cycloaliphatic radical containing at least 2 carbon atoms; R 2 and R 3 are selected from the group consisting of a hydrogen radical and any organic radical containing a photopolymerizable olefinic double bond, at least one of R 2 and R 3 being said organic radical; and R 4 and R 5 are selected from the group consisting of perfluoro and perhalofluoro aliphatic hydrocarbons having 1 to 8 carbons; b. a radiation sensitive polymerizable polyfunctional acrylate compound; and c. a photopolymerization initiator system comprising hydrogen donor initiator and aromatic biimidazole.
Claim 3
Dependent Claim 19 words
An electrical device as recited in claim 1, wherein R 4 and R 5 have the formula--CF 3 .
Claim 4
Dependent Claim 37 words
An electrical device as recited in claim 1 or 2, wherein R 2 and R 3 are selected from the group consisting of a hydrogen radical, a hydroxy alkyl acrylate radical, and a hydroxy alkyl methacrylate radical.

References Cited (Backward Citations)

US3479185A Cited
US3957512A Cited
US4271259A Cited
US4310641A Cited
US4311785A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-06-12 1987-12-12 1988-06-12 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-06-12 1991-12-12 1992-06-12 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-06-12 1995-12-12 1996-06-12 $7700.00 Window Closed / Lapsed

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