Patent US4469809A successfully refreshed from Google Patents.
US4469809A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Method for making a dicyclopentadiene thermoset polymer
Assignee: Metton America Inc
•
Filing: 1983-03-07
•
Granted: 1984-09-04
•
Expires: 2003-03-07
Abstract
Abstract A method of making a thermoset polydicyclopentadiene by first combining a plurality of reactant streams, one containing the activator of a metathesis-catalyst system, a second containing the catalyst of a metathesis-catalyst system and at least one containing dicyclopentadiene; then immediately injecting this combination into a mold where polymerization results in the formation of a tough, rigid thermoset polymer with high modulus and excellent impact strength.
Inventors
- 👤 Daniel W. Klosiewicz
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-25 11:34
CPC Classifications
C; C08; C08G; C08G61/00; C08G61/02; C08G61/04; C08G61/06; C08G61/08
Claims Analysis
Total Claims: 5
Claim 1
Independent Claim
175 words
A catalyst part of a metathesis-catalyst system comprising: a catalyst; a Lewis base or chelant; a phenolic compound; a solvent; an alkylaluminum activator; and a moderator, wherein the molar ratio of catalyst to Lewis base or chelant is about 1:5; wherein said catalyst is selected from the group consisting of tungsten hexahalide and tungsten oxyhalide; wherein said phenolic compound is selected from the group consisting of phenol, alkyl-phenols and halogenated phenols, where the phenolic compound is present in a molar ratio of tungsten compound to phenolic compound of from about 1:1 to about 1:3; wherein said solvent is selected from the group consisting of benzene, toluene, chlorobenzene, dichlorobenzene and trichlorobenzene; wherein the solvent is present in a sufficient amount so that the catalyst concentration is between about 0:1 and about 0.7 mole per liter of solvent; wherein said alkylaluminum activator is selected from the group consisting of trialkylaluminum, dialkylaluminum halides, and alkylaluminum dihalides; and wherein said moderator is selected from the group consisting of isopropyl ether, di-n-butyl ether, ethyl benzoate, phenylethyl acetate and diisopropyl ketone.
Claim 2
Dependent Claim
175 words
A catalyst part of a metathesis-catalyst system comprising: a catalyst; a Lewis base or chelant; a phenolic compound; a solvent; an alkylaluminum activator; and a moderator, wherein the molar ratio of catalyst to Lewis base or chelant is about 1:5; wherein said catalyst is selected from the group consisting of tungsten hexahalide and tungsten oxyhalide; wherein said phenolic compound is selected from the group consisting of phenol, alkyl-phenols and halogenated phenols, where the phenolic compound is present in a molar ratio of tungsten compound to phenolic compound of from about 1:1 to about 1:3; wherein said solvent is selected from the group consisting of benzene, toluene, chlorobenzene, dichlorobenzene and trichlorobenzene; wherein the solvent is present in a sufficient amount so that the catalyst concentration is between about 0:1 and about 0.7 mole per liter of solvent; wherein said alkylaluminum activator is selected from the group consisting of trialkylaluminum, dialkylaluminum halides, and alkylaluminum dihalides; and wherein said moderator is selected from the group consisting of isopropyl ether, di-n-butyl ether, ethyl benzoate, phenylethyl acetate and diisopropyl ketone.
Claim 3
Dependent Claim
8 words
The catalyst of claim 1 further comprising dicyclopentadiene.
Claim 4
Dependent Claim
25 words
The catalyst of claim 1 wherein said catalyst is WOCl 4 , WCl 6 or a combination of WCl 6 and an alcohol or phenol.
Claim 5
Dependent Claim
19 words
The catalyst of claim 1 wherein the chelant is selected from the group consisting of acetylacetones and alkyl acetoacetates.
References Cited (Backward Citations)
US3492245A
Cited
US3778385A
Cited
US3649709A
Cited
US3784631A
Cited
US3897512A
Cited
US3813453A
Cited
US3956178A
Cited
US4172932A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1987-09-04 | 1988-03-05 | 1988-09-04 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1991-09-04 | 1992-03-05 | 1992-09-04 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1995-09-04 | 1996-03-05 | 1996-09-04 | $7700.00 | Window Closed / Lapsed |