Integrated cross-linkers and amine functional siloxane scavengers for RTV silicone rubber compositions

Claim 2

A shelf-stable, fast-curing one-component RTV silicone rubber composition comprising, (A) an organopolysiloxane polymer having a viscosity varying in the range of 100 to 1,000,000 centipoise at 25° C. where the organo groups are monovalent hydrocarbon radicals, and wherein in said polymer, the terminal silicon atoms in the polymer chain have bonded to them at least one alkoxy group; (B) an effective amount of a condensation catalyst; and (C) an effective amount of a scavenging compound of the formula, ##EQU1## where R 1 and R 2 are individually selected from C 1-13 monovalent hydrocarbon radicals and A is a radical selected from the group consisting of simple amine radicals of the formula, ##STR18## where R 10 and R 11 are individually selected from hydrogen C 1-8 monovalent hydrocarbon radicals, and multi-amine functional radicals of the formula, ##STR19## where R 3 is selected from the group consisting of hydrogen, C 1-8 monovalent hydrocarbon radicals, and a radical of the formula ##STR20## wherein R 8 and R 9 are individually selected from the group consisting of hydrogen and C 1-8 monovalent hydrocarbon radicals and R 7 is a C 2-8 divalent hydrocarbon radical; R 4 is a C 2-8 divalent hydrocarbon radical, R 5 and R 6 are individually selected from the group consisting of hydrogen and C 1-8 monovalent hydrocarbon radicals; x varies in the range of 0.00 to 2.50; y varies in the range of 0.00 to 2.50; and w varies in the range of 0.05 to 1.5; and the sum of x+y+w varies in the range of 2.10 to 3.00.

Claim 3

The composition of claim 1 wherein the condensation catalyst is a tin condensation catalyst.

Claim 4

The composition of claim 2 further comprising having an effective amount of cross-linking silane of the formula, ##STR21## where R 1 and R 2 are individually selected from C 1-13 monovalent hydrocarbon radicals and b is a whole number equal to 0 or 1.

Claim 5

The composition of claim 3 further comprising an effective amount of a cure accelerator selected from the group consisting of substituted guanidines, amines and mixtures thereof.

Claim 6

The composition of claim 4 further comprising a polyalkoxy-terminated organopolysiloxane polymer of the formula, ##STR22## where R, R 1 , R 2 are each individually selected from C 1-13 monovalent hydrocarbon radicals; b is a whole number equal to 0 or 1; e is a whole number which equals to 0 or 1, inclusive; n is an integer having a value of from about 50 to 2,500, inclusive; and X is a hydrolyzable leaving group selected from the class consisting of amido, cyclic amido, silazanyl, carbamato, enoxy, imidato, isocyanato, oximato, thioisocyanato, ureido radicals, and radicals selected from the class consisting of simple amine radicals of the formula, ##STR23## where R 10 , R 11 are individually selected from hydrogen, C 1-8 monovalent hydrocarbon radicals, and multi-amine functional radicals of the formula, ##STR24##

Claim 7

where R 3 is selected from the class consisting of hydrogen, C 1-8 monovalent hydrocarbon radicals, and a radical of the formula, ##STR25## wherein R 8 , R 9 are individually selected from the class consisting of hydrogen and C 1-8 monovalent hydrocarbon radicals and R 7 is a C 2-8 divalent hydrocarbon radical; R 5 and R 6 are individually selected from the class consisting of hydrogen and C 1-8 monovalent hydrocarbon radicals, R 4 is a C 2-8 divalent hydrocarbon radical.

Claim 8

where R 3 is selected from the class consisting of hydrogen, C 1-8 monovalent hydrocarbon radicals, and a radical of the formula, ##STR25## wherein R 8 , R 9 are individually selected from the class consisting of hydrogen and C 1-8 monovalent hydrocarbon radicals and R 7 is a C 2-8 divalent hydrocarbon radical; R 5 and R 6 are individually selected from the class consisting of hydrogen and C 1-8 monovalent hydrocarbon radicals, R 4 is a C 2-8 divalent hydrocarbon radical.

Claim 9

The composition of claim 5 wherein the cross-linking silane is methyltrimethoxysilane, the condensation catalyst is selected from the class consisting of dibutyltindiacetate and dibutyltindilaurate, and the curing accelerator is selected from the class consisting of di-n-hexylamine and di-n-butylamine.

Claim 10

The composition of claim 5 wherein the condensation catalyst is selected from the class consisting of dibutyltindiacetate and dibutyltindilaurate and the cure accelerator is selected from the class consisting of di-n-hexylamine and di-n-butylamine.

Claim 11

The composition of claim 5 wherein R, R 1 and R 2 are methyl and the tin condensation catalyst is selected from the class consisting of dibutyltindiacetate and dibutyltindilaurate.

Claim 12

A shelf-stable, fast-curing one-component RTV silicone rubber composition, comprising, (A) a silanol-terminated diorganopolysiloxane polymer having a viscosity in the range of 100 to 1,000,000 centipoise at 25° C. where the organo groups are monovalent hydrocarbon radicals; (B) an integrated cross-linker, scavenger compound of the formula, ##STR26## where R 1 and R 2 are individually selected from C 1-13 monovalent hydrocarbon radicals and A is a radical selected from the group consisting of simple amine radicals of the formula, ##STR27## where R 10 and R 11 are individually selected from hydrogen, C 1-8 monovalent hydrocarbon radicals, and multi-amine functional radicals of the formula, ##STR28## where R 3 is selected from the group consisting of hydrogen, C 1-8 monovalent hydrocarbon radicals, and a radical of the formula ##STR29## wherein R 8 and R 9 are individually selected from the group consisting of hydrogen and C 1-8 monovalent hydrocarbon radicals and R 7 is a C 2-8 divalent hydrocarbon radical, R 4 is a C 2-8 divalent hydrocarbon radical, R 5 and R 6 are individually selected from the group consisting of hydrogen and C 1-8 monovalent hydrocarbon radicals; m varies in the range of 0.15 to 2.50; n varies in the range of 0.1 to 1.9; an o varies in the range of 0.05 to 2.00; and the sum of m+n+o varies in the range of 2.10 to 3.00, which forms with the silanol-terminated polymer, an alkoxy terminated polymer; and (C) an effective amount of a condensation catalyst.

Claim 13

A shelf-stable, fast-curing one-component RTV silicone rubber composition, comprising, (A) a silanol-terminated diorganopolysiloxane polymer having a viscosity in the range of 100 to 1,000,000 centipoise at 25° C. where the organo groups are monovalent hydrocarbon radicals; (B) an integrated cross-linker, scavenger compound of the formula, ##STR26## where R 1 and R 2 are individually selected from C 1-13 monovalent hydrocarbon radicals and A is a radical selected from the group consisting of simple amine radicals of the formula, ##STR27## where R 10 and R 11 are individually selected from hydrogen, C 1-8 monovalent hydrocarbon radicals, and multi-amine functional radicals of the formula, ##STR28## where R 3 is selected from the group consisting of hydrogen, C 1-8 monovalent hydrocarbon radicals, and a radical of the formula ##STR29## wherein R 8 and R 9 are individually selected from the group consisting of hydrogen and C 1-8 monovalent hydrocarbon radicals and R 7 is a C 2-8 divalent hydrocarbon radical, R 4 is a C 2-8 divalent hydrocarbon radical, R 5 and R 6 are individually selected from the group consisting of hydrogen and C 1-8 monovalent hydrocarbon radicals; m varies in the range of 0.15 to 2.50; n varies in the range of 0.1 to 1.9; an o varies in the range of 0.05 to 2.00; and the sum of m+n+o varies in the range of 2.10 to 3.00, which forms with the silanol-terminated polymer, an alkoxy terminated polymer; and (C) an effective amount of a condensation catalyst.

Claim 14

The composition of claim 9 wherein the silanol-terminated diorganopolysiloxane polymer has the formula, ##STR30## wherein each R is individually selected from C 1-13 monovalent hydrocarbon radicals and n is a whole number that varies from 50 to 2,500.

Claim 15

The composition of claim 9 wherein the alkoxy-terminated polymer that is formed has the formula, ##STR31## where R, R 1 and R 2 are individually selected from C 1-13 monovalent hydrocarbon radicals; s is a whole number equal to 0 or 1; n is an integer that varies from 50 to 2,500, inclusive; t is a whole number equal to 1 or 2, inclusive; and the sum of s+t is equal to 1 to 2; and A is as previously defined.

Claim 16

The composition of claim 9 wherein the condensation catalyst is a tin condensation catalyst.

Claim 17

The composition of claim 12 further comprising having an effective amount of a cross-linking silane of the formula, ##STR32## where R 1 and R 2 are individually selected from C 1-13 monovalent hydrocarbon radicals; and b is a whole number equal to 0 or 1.

Claim 18

The composition of claim 13 further comprising adding an effective amount of a cure accelerator selected from the group consisting of substituted guanidines, amines and mixtures thereof.

Claim 19

The composition of claim 14 further comprising having therein a polyalkoxy-terminated organopolysiloxane polymer of the formula, ##STR33## where R, R 1 , R 2 are individually selected from C 1-13 monovalent hydrocarbon radicals; b+e are whole numbers equal to 0 or 1; e is a whole number which equals to 0 or 1, inclusive; and the sum of b+e is equal to 0 or 1, inclusive; n is an integer having a value of from about 50 to 2,500, inclusive; and X is a hydrolyzable leaving group selected from the class consisting of amido, cyclic aido, silazanyl, carbamato, enoxy, imidato, isocyanato, oximato, thioisocyanato, ureido radicals, and radicals selected from the class consisting of simple amine radicals of the formula, ##STR34## where R 10 , R 11 are individually selected from hydrogen, C 1-8 monovalent hydrocarbon radicals, and multi-amine functional radicals of the formula, ##STR35## where R 3 is selected from the class consisting of hydrogen, C 1-8 monovalent hydrocarbon radicals, and a radical of the formula, ##STR36## wherein R 8 , R 9 are individually selected from the class consisting of hydrogen and C 1-8 monovalent hydrocarbon radicals and R 7 is a C 2-8 divalent hydrocarbon radical; R 5 and R 6 are individually selected from the class consisting of hydrogen and C 1-8 monovalent hydrocarbon radicals, R 4 is a C 2-8 divalent hydrocarbon radical.

Claim 20

The composition of claim 15 wherein the cross-linking silane is methyltrimethoxy silane, the condensation catalyst is selected from the class consisting of dibutyltindiacetate and dibutyltindilaurate and a curing accelerator selected from the class consisting of di-n-hexylamine and di-n-butylamine.

Claim 21

The composition of claim 15 wherein the condensation catalyst is selected from the class consisting of dibutyltindiacetate and dibutyltindilaurate and the cure accelerator is selected from the class consisting of di-n-hexylamine and di-n-butylamine.

Claim 22

The composition of claim 15 wherein R, R 1 , and R 2 are methyl and the tin condensation catalyst is selected from the class consisting of dibutyltindiacetate and dibutyltindilaurate.

Claim 23

A process for producing a shelf-stable, fast-curing one-component RTV silicone rubber composition comprising, mixing anhydrously, (A) an organopolysiloxane polymer having a viscosity varying in the range of 100 to 1,000,000 centipoise at 25° C. where the organo groups are monovalent hydrocarbon radicals, and wherein the terminal silicon atoms of said polymer have bonded to them at least one alkoxy group; (B) an effective amount of a condensation catalyst; and (C) an effective amount of a scavenging compound of the formula ##STR37## where R 1 and R 2 are individually selected from C 1-13 monovalent hydrocarbon radicals and A is a radical selected from the group consisting of simple amine radicals of the formula, ##STR38## where R 10 and R 11 are individually selected from hydrogen, C 1-8 monovalent hydrocarbon radicals, and multi-amine functional radicals of the formula, ##STR39## where R 3 is selected from the group consisting of hydrogen, C 1-8 monovalent hydrocarbon radicals, and a radical of the formula ##STR40## wherein R 8 and R 9 are individually selected from the group consisting of hydrogen and C 1-8 monovalent hydrocarbon radicals and R 7 is a C 2-8 divalent hydrocarbon radical, R 4 is a C 2-8 divalent hydrocarbon radical, R 5 and R 6 are individually selected from the group consisting of hydrogen and C 1-8 monovalent hydrocarbon radicals; x varies in the range of 0.00 to 2.50; y varies in the range of 0.00 to 2.50; and w varies in the range of 0.05 to 1.5; and the sum of x+y+w varies in the range of 2.10 to 3.00.

Claim 24

A process for producing a shelf-stable, fast-curing one-component RTV silicone rubber composition comprising, mixing anhydrously, (A) an organopolysiloxane polymer having a viscosity varying in the range of 100 to 1,000,000 centipoise at 25° C. where the organo groups are monovalent hydrocarbon radicals, and wherein the terminal silicon atoms of said polymer have bonded to them at least one alkoxy group; (B) an effective amount of a condensation catalyst; and (C) an effective amount of a scavenging compound of the formula ##STR37## where R 1 and R 2 are individually selected from C 1-13 monovalent hydrocarbon radicals and A is a radical selected from the group consisting of simple amine radicals of the formula, ##STR38## where R 10 and R 11 are individually selected from hydrogen, C 1-8 monovalent hydrocarbon radicals, and multi-amine functional radicals of the formula, ##STR39## where R 3 is selected from the group consisting of hydrogen, C 1-8 monovalent hydrocarbon radicals, and a radical of the formula ##STR40## wherein R 8 and R 9 are individually selected from the group consisting of hydrogen and C 1-8 monovalent hydrocarbon radicals and R 7 is a C 2-8 divalent hydrocarbon radical, R 4 is a C 2-8 divalent hydrocarbon radical, R 5 and R 6 are individually selected from the group consisting of hydrogen and C 1-8 monovalent hydrocarbon radicals; x varies in the range of 0.00 to 2.50; y varies in the range of 0.00 to 2.50; and w varies in the range of 0.05 to 1.5; and the sum of x+y+w varies in the range of 2.10 to 3.00.

Claim 25

A process for forming a shelf-stable, fast-curing one-component RTV silicone rubber composition, comprising, mixing in a substantially anhydrous manner, (A) a silanol-terminated diorganopolysiloxane polymer having a viscosity in the range of 100 to 1,000,000 centipoise at 25° C. where the organo groups are monovalent hydrocarbon radicals; (B) an effective amount of a scavenging compound of the formula, ##STR41## where R 1 and R 2 are individually selected from C 1-13 monovalent hydrocarbon radicals and A is a radical selected from the group consisting of a simple amine radical of the formula, ##STR42## where R 10 and R 11 are each individually selected from hydrogen, C 1-8 monovalent hydrocarbon radicals, and multi-amine functional radicals of the formula, ##STR43## where R 3 is selected from the group consisting of hydrogen, C 1-8 monovalent hydrocarbon radicals, and a radical of the formula ##STR44## wherein R 8 and R 9 are individually selected from the group consisting of hydrogen and C 1-8 monovalent hydrocarbon radicals and R 7 is a C 2-8 divalent hydrocarbon radical, R 4 is a C 2-8 divalent hydrocarbon radical, R 5 and R 6 are individually selected from the group consisting of hydrogen and C 1-8 monovalent hydrocarbon radicals; m varies in the range of 0.15 to 2.50; n varies in the range of 0.1 to 1.9; and o varies in the range of 0.05 to 2.00; and the sum of m+n+o varies in the range of 2.10 to 3.00. (C) an effective amount of a condensation catalyst.

Claim 26

A process for forming a shelf-stable, fast-curing one-component RTV silicone rubber composition, comprising, mixing in a substantially anhydrous manner, (A) a silanol-terminated diorganopolysiloxane polymer having a viscosity in the range of 100 to 1,000,000 centipoise at 25° C. where the organo groups are monovalent hydrocarbon radicals; (B) an effective amount of a scavenging compound of the formula, ##STR41## where R 1 and R 2 are individually selected from C 1-13 monovalent hydrocarbon radicals and A is a radical selected from the group consisting of a simple amine radical of the formula, ##STR42## where R 10 and R 11 are each individually selected from hydrogen, C 1-8 monovalent hydrocarbon radicals, and multi-amine functional radicals of the formula, ##STR43## where R 3 is selected from the group consisting of hydrogen, C 1-8 monovalent hydrocarbon radicals, and a radical of the formula ##STR44## wherein R 8 and R 9 are individually selected from the group consisting of hydrogen and C 1-8 monovalent hydrocarbon radicals and R 7 is a C 2-8 divalent hydrocarbon radical, R 4 is a C 2-8 divalent hydrocarbon radical, R 5 and R 6 are individually selected from the group consisting of hydrogen and C 1-8 monovalent hydrocarbon radicals; m varies in the range of 0.15 to 2.50; n varies in the range of 0.1 to 1.9; and o varies in the range of 0.05 to 2.00; and the sum of m+n+o varies in the range of 2.10 to 3.00. (C) an effective amount of a condensation catalyst.

Claim 27

The process of claim 20 wherein the silanol terminated diorganopolysiloxane polymer has the formula, ##STR45## wherein each R is individually selected from C 1-13 monovalent hydrocarbon radicals and n is a whole number that varies from 50 to 2,500.

Claim 28

The process of claim 20 wherein the alkoxy-terminated polymer that is formed has the formula, ##STR46## where R, R 1 , and R 2 are individually selected from C 1-13 monovalent hydrocarbon radicals; s is a whole number equal to 0 or 1; t is a whole number equal to 1 or 2, inclusive; and the sum of s+t is equal to 1 to 2; and A is as previously defined.

Claim 29

The process of claim 20 wherein the condensation catalyst is a tin condensation catalyst.

Claim 30

The process of claim 23 further comprising adding an effective amount of a cross-linking silane of the formula, ##STR47## where R 1 and R 2 are each individually selected from C 1-13 monovalent hydrocarbon radicals and b is a whole number that is equal to 0 or 1.

Claim 31

The process of claim 24 further comprising an effective amount of a cure accelerator selected from the group consisting of substituted guanidines, amines and mixtures thereof.

Claim 32

The process of claim 25 further comprising polyalkoxy-terminated organopolysiloxane polymer of the formula, ##STR48## where R, R 1 , R 2 are individually selected from C 1-13 monovalent hydrocarbon radicals; b is a whole number equal to 0 or 1; e is a whole number which equals 0 or 1, inclusive; the sum of b+e is equal to 0 or 1, inclusive; n is an integer having a value of from about 50 to 2,500, inclusive; and X is a radical selected from the class consisting of amido, cyclic amido, silazanyl, carbamato, enoxy, imidato, isocyanato, oximato, thioisocyanato, ureido radicals, and simple amine radicals of the formula, ##STR49## where R 10 , R 11 are individually selected from hydrogen, C 1-8 monovalent hydrocarbon radicals, and multi-amine functional radicals of the formula, ##STR50## where R 3 is selected from the class consisting of hydrogen, C 1-8 monovalent hydrocarbon radicals, and a radical of the formula, ##STR51## wherein R 8 , R 9 are individually selected from the class consisting of hydrogen and C 1-8 monovalent hydrocarbon radicals and R 7 is a C 2-8 divalent hydrocarbon radical; R 5 and R 6 are individually selected from the class consisting of hydrogen and C 1-8 monovalent hydrocarbon radicals, R 4 is a C 2-8 divalent hydrocarbon radical.

Claim 33

The process of claim 26 wherein the cross-linking silane is methyltrimethoxysilane, the condensation catalyst is selected from the class consisting of dibutyltindiacetate and dibutyltindilaurate, and the curing accelerator is selected from the class consisting of di-n-hexylamine and di-n-butylamine.

Claim 34

The process of claim 26, wherein the condensation catalyst is selected from the class consisting of dibutyltindiacetate and dibutyltindilaurate and the accelerator is selected from the class consisting of di-n-hexylamine and di-n-butylamine.

Claim 35

The process of claim 26 wherein R, R 1 , and R 2 are methyl and the tin condensation catalyst is selected from the class consisting of dibutyltindiacetate and dibutyltindilaurate.