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US4492774A
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Method for converting synthesis gas using an activated cobalt-substituted layered aluminosilicate
Assignee: Shell Internationale Research Maatschappij BV
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Filing: 1982-12-27
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Granted: 1985-01-08
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Expires: 2002-12-27
Abstract
Abstract A process for converting synthesis gas to liquid hydrocarbons using a catalyst prepared from synthetic layered aluminosilicate having a montmorillonite-type structure and containing cobalt substituted in the crystal lattice and activated for the conversion by a sequential reduction, oxidation and reduction treatment.
Inventors
- 👤 Charles L. Kibby
- 👤 Thaddeus P. Kobylinski
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-31 07:36
CPC Classifications
B; B01; B01J; B01J29/00; B01J29/04; B01J29/049; B01J21/00; B01J21/16; C; C07; C07C; C07C1/00; C07C1/02; C07C1/04; C07C1/0425; C07C1/0445; C07C2521/00; C07C2521/16; C07C2523/00; C07C2523/70; C07C2523/74; C07C2523/75
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
186 words
A method for converting synthesis gas to a product predominating in liquid hydrocarbons which comprises contacting said synthesis gas under conversion conditions with a synthesis gas conversion catalyst obtainable by the multi-stage activation of a layered aluminosilicate having cobalt incorporated into the crystal lattice and having the general formula: Al.sub.4-n-x Co.sub.(3/2)n O.sub.8 (OH,F).sub.4 Si.sub.8-y Al.sub.y O.sub.12.(3x+y)NH.sub.4.sup.+.zH.sub.2 O where n is between about 0.02 and about 4; x is up to about 1; n+x is between about 0.02 and about 4; y is between about 0.05 and about 2; and z is up to about 10; said activation procedure comprising the steps: (a) heating the layered aluminosilicate in a reducing atmosphere at a temperature between about 500° and about 750° C. until a significant amount of the cobalt is reduced; (b) heating the reduced aluminosilicate in an oxidizing atmosphere at a temperature between about 100° and about 600° C. until a significant amount of the cobalt is oxidized, and (c) heating the oxidized aluminosilicate in a reducing atmosphere at a temperature between about 200° and about 500° C. until a signficant quantity of the cobalt is reduced.
Claim 2
Independent Claim
186 words
A method for converting synthesis gas to a product predominating in liquid hydrocarbons which comprises contacting said synthesis gas under conversion conditions with a synthesis gas conversion catalyst obtainable by the multi-stage activation of a layered aluminosilicate having cobalt incorporated into the crystal lattice and having the general formula: Al.sub.4-n-x Co.sub.(3/2)n O.sub.8 (OH,F).sub.4 Si.sub.8-y Al.sub.y O.sub.12.(3x+y)NH.sub.4.sup.+.zH.sub.2 O where n is between about 0.02 and about 4; x is up to about 1; n+x is between about 0.02 and about 4; y is between about 0.05 and about 2; and z is up to about 10; said activation procedure comprising the steps: (a) heating the layered aluminosilicate in a reducing atmosphere at a temperature between about 500° and about 750° C. until a significant amount of the cobalt is reduced; (b) heating the reduced aluminosilicate in an oxidizing atmosphere at a temperature between about 100° and about 600° C. until a significant amount of the cobalt is oxidized, and (c) heating the oxidized aluminosilicate in a reducing atmosphere at a temperature between about 200° and about 500° C. until a signficant quantity of the cobalt is reduced.
Claim 3
Dependent Claim
30 words
The synthesis gas conversion process in accordance with claim 1 in which said layered aluminosilicate is calcined in air at an elevated temperature between about 200° and about 500° C.
Claim 4
Dependent Claim
44 words
The synthesis gas conversion process in accordance with claim 1 where n is between about 2 and about 3; x is between about 0.1 and about 0.2; n+x is between about 2 and about 3; and y is between about 0.5 and about 2.
Claim 5
Dependent Claim
55 words
The synthesis gas conversion process in accordance with claim 1 in which the reducing temperature in step (a) is between about 550° and about 650° C., the oxidizing temperature of step (b) is between about 200° and about 500° C., and the reducing temperature of step (c) is between about 300° and about 400° C.
Claim 6
Dependent Claim
41 words
The synthesis gas conversion process in accordance with claim 1 in which at least one additional oxidation treatment and at least one additional reduction treatment are carried out on the catalyst at the conditions specified in steps (b) and (c), respectively.
Claim 7
Dependent Claim
26 words
The synthesis gas conversion process in accordance with claim 1 wherein the molar ratio of hydrogen to carbon monoxide is from about 0.5:1 to about 4:1.
Claim 8
Dependent Claim
26 words
The synthesis gas conversion process in accordance with claim 3 wherein the molar ratio of hydrogen to carbon monoxide is from about 1:1 to about 2.5:1.
Claim 9
Dependent Claim
27 words
The synthesis gas conversion process in accordance with claim 1 wherein the synthesis gas conversion conditions include a temperature of from about 160° to about 350° C.
Claim 10
Dependent Claim
27 words
The synthesis gas conversion process in accordance with claim 7 wherein the synthesis gas conversion conditions include a temperature of from about 170° to about 250° C.
Claim 11
Dependent Claim
22 words
The synthesis gas conversion process in accordance with claim 1 wherein the total pressure is from about 1 to about 50 atmospheres.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1988-01-08 | 1988-07-09 | 1989-01-08 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1992-01-08 | 1992-07-09 | 1993-01-08 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1996-01-08 | 1996-07-09 | 1997-01-08 | $7700.00 | Window Closed / Lapsed |