Patent US4524012A successfully refreshed from Google Patents.
US4524012A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Fabric softening and fluffing detergent composition
Assignee: Colgate Palmolive Co
•
Filing: 1983-06-08
•
Granted: 1985-06-18
•
Expires: 2003-06-08
Abstract
Abstract A fabric softening and fluffing particulate detergent composition comprises a detersive proportion of an anionic synthetic organic detergent, such as sodium linear higher alkylbenzene sulfonate, a building proportion of a builder for the detergent, such as sodium tripolyphosphate, sodium carbonate and/or sodium silicate, a fabric softening proportion of bentonite, and a softening and fluffing proportion of a magnesium salt, which is at least slightly water soluble, such as magnesium sulfate. The basic detergent composition, containing the detergent and builder, sometimes with inert filler and preferably with desirable adjuvants, is preferably in the form of spray dried beads, and the bentonite and magnesium salt are preferably agglomerated together to particles of about the same size as the spray dried beads, and are mixed with the spray dried beads. The invention also relates to the mentioned agglomerate and to processes for making the detergent composition and the agglomerate.
Inventors
- 👤 Harold E. Wixon
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-02 13:33
CPC Classifications
C; C11; C11D; C11D3/00; C11D3/02; C11D3/04; C11D3/046; C11D3/0005; C11D3/001; C11D3/12; C11D3/124; C11D3/1246; C11D3/1253; C11D3/126
Claims Analysis
Total Claims: 24
Claim 1
Independent Claim
115 words
A fabric softening and fabric fluffing particulate detergent composition which comprises spray dried beads containing a detersive proportion of an anionic synthetic organic detergent and a building proportion of a builder for such detergent, a fabric softening proportion of bentonite, which is capable of softening fabrics during washing thereof with the anionic detergent and builder, and a softening and fluffing proportion of a magnesium compound which is at least slightly water soluble, in such proportion that it improves the softening effect of the bentonite and improves the fluffiness of the fabrics washed with the detergent composition, which bentonite and magnesium compound are external to the spray dried beads of anionic synthetic organic detergent and builder.
Claim 2
Dependent Claim
115 words
A fabric softening and fabric fluffing particulate detergent composition which comprises spray dried beads containing a detersive proportion of an anionic synthetic organic detergent and a building proportion of a builder for such detergent, a fabric softening proportion of bentonite, which is capable of softening fabrics during washing thereof with the anionic detergent and builder, and a softening and fluffing proportion of a magnesium compound which is at least slightly water soluble, in such proportion that it improves the softening effect of the bentonite and improves the fluffiness of the fabrics washed with the detergent composition, which bentonite and magnesium compound are external to the spray dried beads of anionic synthetic organic detergent and builder.
Claim 3
Dependent Claim
23 words
A detergent composition according to claim 1 wherein the bentonite is in the form of an agglomerate which disintegrates readily in wash water.
Claim 4
Dependent Claim
29 words
A detergent composition according to claim 2 wherein the magnesium compound is a magnesium salt and is present with bentonite in at least a portion of the bentonite agglomerate.
Claim 5
Dependent Claim
36 words
A detergent composition according to claim 3 which consists essentially of 5 to 35% of anionic synthetic organic detergent, 10 to 80% of builder, 4 to 30% of bentonite, and 0.2 to 5% of magnesium salt.
Claim 6
Dependent Claim
33 words
A detergent composition according to claim 4 wherein the magnesium salt is magnesium sulfate, 1 to 4% thereof is present in the composition, and it is distributed evenly in all the bentonite agglomerate.
Claim 7
Dependent Claim
25 words
A detergent composition according to claim 5 wherein the proportion of magnesium sulfate to bentonite in the magnesium sulfate-bentonite agglomerate is from 1:20 to 1:1.
Claim 8
Dependent Claim
86 words
A detergent composition according to claim 6 consisting essentially of from 5 to 35% of sodium higher linear alkylbenzene sulfonate wherein the linear alkyl is of 12 to 13 carbon atoms, 5 to 40% of sodium tripolyphosphate, 2 to 10% of sodium silicate, 5 to 20% of sodium carbonate, 5 to 40% of sodium sulfate, 5 to 20% of bentonite, 1 to 4% of magnesium sulfate and 4 to 15% of moisture, the particles of which are in the range of Nos. 10-120, U.S. Sieve Series.
Claim 9
Dependent Claim
31 words
A detergent composition according to claim 6 wherein the builder is a water softening and calcium ion exchanging zeolite and the proportion thereof in the composition is from 5 to 40%.
Claim 10
Dependent Claim
86 words
A detergent composition according to claim 7 wherein the sodium linear higher alkylbenzene sulfonate, sodium tripolyphosphate, sodium silicate, sodium carbonate and sodium sulfate are in spray dried bead form, of particle sizes in the Nos. 10-100 range, U.S. Sieve Series, and the bentonite-magnesium sulfate agglomerates are of particle sizes in the Nos. 30-100 range, include as a binding agent from 0.5 to 5%, on the basis of the agglomerate weight, of sodium silicate, and are of a moisture content in the range of 4 to 15%.
Claim 11
Dependent Claim
14 words
A detergent composition according to claim 1 wherein the magnesium compound is magnesium sulfate.
Claim 12
Dependent Claim
64 words
A detergent composition according to claim 1 wherein the builder is a mixture of builders, the anionic synthetic organic detergent and builder are in the form of spray dried beads, the magnesium compound is magnesium sulfate and the bentonite and magnesium sulfate are agglomerated to particles of about the same size as the spray dried beads of anionic synthetic organic detergent and mixed builders.
Claim 13
Dependent Claim
76 words
A particulate fabric softening and fluffing composition suitable for incorporation in detergent compositions for softening and fluffing laundry washed with such compositions, which comprises agglomerates of finely divided bentonite which is capable of softening fabrics during washing thereof with such detergent composition, and a magnesium compound which is at least slightly water soluble, in such proportion that it improves the softening effect of the bentonite and improves the fluffiness of fabrics washed with the detergent composition.
Claim 14
Dependent Claim
76 words
A particulate fabric softening and fluffing composition suitable for incorporation in detergent compositions for softening and fluffing laundry washed with such compositions, which comprises agglomerates of finely divided bentonite which is capable of softening fabrics during washing thereof with such detergent composition, and a magnesium compound which is at least slightly water soluble, in such proportion that it improves the softening effect of the bentonite and improves the fluffiness of fabrics washed with the detergent composition.
Claim 15
Dependent Claim
18 words
An agglomerated fabric softening and fluffing composition according to claim 12 wherein the magnesium compound is magnesium sulfate.
Claim 16
Dependent Claim
60 words
A composition according to claim 13 which consists essentially of about 7 to 64% of magnesium sulfate, 26 to 87% of bentonite, 0.5 to 5% of a binder in the agglomerate to assist in maintaining the integrity of the agglomerate until it is added to water, in which it is readily disintegrable and dispersible, and 4 to 15% of moisture.
Claim 17
Dependent Claim
53 words
A composition according to claim 14 wherein the binder is sodium silicate, the proportions of magnesium sulfate, bentonite, sodium silicate, and moisture are about 10 to 30%, 60 to 80%, 1 to 3% and 5 to 12%, respectively, and the particles are of sizes within the range of Nos. 10-120, U.S. Sieve Series.
Claim 18
Dependent Claim
181 words
A process for manufacturing a fabric softening and fluffing particulate detergent composition which comprises making an aqueous crutcher mix containing 40 to 70% of solids, including anionic synthetic organic detergent and a building proportion of a builder for such detergent, spray drying the crutcher mix to produce spray dried beads of particle sizes in the Nos. 10-120 range, U.S. Sieve Series, agglomerating a powdered bentonite which is capable of softening fabrics during washing thereof in wash water containing the anionic detergent and builder, with a magnesium compound which is at least slightly soluble in water, which improves the fabric softening effect of the bentonite and which improves the fluffiness of washed fabrics, said agglomerate being of particle sizes in the Nos. 10-120 sieve range, and mixing together the spray dried and agglomerated particles in such proportion that the fabric softening bentonite is present in the composition in a fabric softening proportion and the proportion of magnesium compound present is such as to improve the fabric softening properties of the bentonite and improve the fluffiness of fabrics washed with the detergent composition.
Claim 19
Dependent Claim
181 words
A process for manufacturing a fabric softening and fluffing particulate detergent composition which comprises making an aqueous crutcher mix containing 40 to 70% of solids, including anionic synthetic organic detergent and a building proportion of a builder for such detergent, spray drying the crutcher mix to produce spray dried beads of particle sizes in the Nos. 10-120 range, U.S. Sieve Series, agglomerating a powdered bentonite which is capable of softening fabrics during washing thereof in wash water containing the anionic detergent and builder, with a magnesium compound which is at least slightly soluble in water, which improves the fabric softening effect of the bentonite and which improves the fluffiness of washed fabrics, said agglomerate being of particle sizes in the Nos. 10-120 sieve range, and mixing together the spray dried and agglomerated particles in such proportion that the fabric softening bentonite is present in the composition in a fabric softening proportion and the proportion of magnesium compound present is such as to improve the fabric softening properties of the bentonite and improve the fluffiness of fabrics washed with the detergent composition.
Claim 20
Dependent Claim
121 words
A process according to claim 16 wherein the crutcher mix is at a temperature in the range of 50° to 90° C., the crutcher mix comprises sodium higher linear alkylbenzene sulfonate wherein the linear alkyl is of 12 to 13 carbon atoms, sodium tripolyphosphate, sodium silicate, sodium carbonate, sodium sulfate and water, in such proportions that upon spray drying the crutcher mix and blending it with the agglomerate the composition resulting comprises 10 to 35%, 5 to 40%, 4 to 10%, 5 to 20% and 5 to 40% of such non-aqueous components, respectively, from the spray dried portion of the composition, and 1 to 4% of magnesium sulfate and 5 to 20% of bentonite from the agglomerated portion of the composition.
Claim 21
Dependent Claim
45 words
A process according to claim 17 wherein about 0.5 to 5% of a binder is present with the bentonite in the agglomerate and said binder is sprayed onto tumbling bentonite powder as a mobile aqueous solution of a concentration of 0.5 to 20% in water.
Claim 22
Dependent Claim
21 words
A process according to claim 18 wherein the binder is sodium silicate of Na 2 O:SiO 2 ratio of about 1:2.4.
Claim 23
Dependent Claim
109 words
A process for manufacturing a particulate fabric softening and fluffing agglomerate, useful for incorporation in detergent compositions for softening and fluffing laundry washed with such compositions, which comprises mixing together bentonite and magnesium sulfate, tumbling such mixture and spraying onto such mixture until it agglomerates into suitably sized larger particles, a mobile aqueous solution of sodium silicate of Na 2 O:SiO 2 ratio of about 1:2.4 so as to produce agglomerates of particle sizes in the range of Nos. 30-100, U.S. Sieve Series, and containing about 10 to 30% of magnesium sulfate, 60 to 80% of bentonite, 1 to 3% of sodium silicate and 5 to 12% of moisture.
Claim 24
Dependent Claim
109 words
A process for manufacturing a particulate fabric softening and fluffing agglomerate, useful for incorporation in detergent compositions for softening and fluffing laundry washed with such compositions, which comprises mixing together bentonite and magnesium sulfate, tumbling such mixture and spraying onto such mixture until it agglomerates into suitably sized larger particles, a mobile aqueous solution of sodium silicate of Na 2 O:SiO 2 ratio of about 1:2.4 so as to produce agglomerates of particle sizes in the range of Nos. 30-100, U.S. Sieve Series, and containing about 10 to 30% of magnesium sulfate, 60 to 80% of bentonite, 1 to 3% of sodium silicate and 5 to 12% of moisture.
References Cited (Backward Citations)
US4292035A
Cited
US4326971A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1988-06-17 | 1988-12-17 | 1989-06-18 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1992-06-17 | 1992-12-17 | 1993-06-18 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1996-06-17 | 1996-12-17 | 1997-06-18 | $7700.00 | Window Closed / Lapsed |