Thermosetting high solids solvent-based polyester-urethane one-component coating compositions

Claim 2

A high solids, solvent-based, thermosetting, one-component coating composition having a sprayability of at least 40 percent, which when cured is flexible and hard in that when the coating composition is deposited on an elastomeric substrate and cured, the coated substrate can be bent around a 1/2-inch mandrel with the coating facing outwardly and the coating exhibits substantially no breaks or cracks when tested at 35° F.; and in that when the coating composition is deposited on a metallic substrate and cured, the coated substrate has a Sward hardness of at least 14; said coating composition contains a film-former comprising a polyester-urethane polyol and a curing agent; the polyester-urethane polyol has a hydroxyl value of at least 50 and comprises: (A) about 60 to 95 percent by weight acyclic moieties, and optionally (B) up to about 30 percent by weight cyclic moieties; the sum of the weight percentage of cyclic moieties and the weight percentage of urethane moieties multiplied by 3 is from about 15 to 65.

Claim 3

A composition of claim 1, wherein the polyester-urethane polyol has a hydroxyl value of 140 to 250.

Claim 4

A composition of claim 1, wherein the polyester-urethane polyol contains from about 10 to 25 percent cyclic moieties.

Claim 5

A composition of claim 1, wherein the polyester-urethane polyol contains from about 1 to 20 percent urethane moieties.

Claim 6

A composition of claim 1, wherein the polyester-urethane polyol contains from about 5 to 10 percent urethane moieties.

Claim 7

A composition of claim 1, wherein the curing agent is a blocked isocyanate, an aminoplast or phenoplast.

Claim 8

A composition of claim 1, wherein the polyester-urethane polyol is prepared by reacting an organic polyisocyanate with a polyester polyol formed from reacting an organic polycarboxylic acid with a polyol.

Claim 9

A composition of claim 7, wherein the organic polycarboxylic acid is a dicarboxylic acid or a derivative thereof and the polyol is a diol.

Claim 10

A composition of claim 8, wherein the organic dicarboxylic acid contains cyclic groups.

Claim 11

The composition of claim 9, wherein the organic dicarboxylic acid is selected from the class consisting of o-phthalic, isophthalic, terephthalic, o-hexahydrophthalic, p-hexahydrophthalic, iso-hexahydrophthalic, tetrahydrophthalic or hydrocarbyl-substituted hexahydrophthalic acid or a derivative thereof, wherein the hydrocarbyl group is an alkyl, alkaryl or aryl group.

Claim 12

A composition of claim 10, wherein the organic dicarboxylic acid is aliphatic and is selected from the group consisting of hexahydrophthalic acid and methyl hexahydrophthalic acid.

Claim 13

A composition of claim 8, wherein the diol is aliphatic.

Claim 14

The composition of claim 12, wherein the aliphatic diol is a mixture of a straight chain diol containing from 2 to 20 carbon atoms and a diol containing neopentyl group branching.

Claim 15

A composition of claim 7, wherein the polyisocyanate is a diisocyanate.

Claim 16

A composition of claim 14, wherein the diisocyanate is aliphatic.

Claim 17

The composition of claim 15, wherein the diisocyanate contains alkyl branching.

Claim 18

A composition of claim 16, wherein the aliphatic diisocyanate is trimethylhexamethylene diisocyanate.

Claim 19

The composition of claim 1 which contains from 10 to 60 percent by weight neopentyl group branching.

Claim 20

A composition of claim 7 in which the equivalent ratio of polyol to polycarboxylic acid is about 2:1 and the equivalent ratio of polyisocyanate to polyester polyol is about 1:3-4.

Claim 21

A high solids, solvent-based, thermosetting, one-component coating composition having a sprayability of at least 40 percent, which when cured is weather-durable, and flexible and hard in that when the coating composition is deposited on an elastomeric substrate and cured, the coated substrate can be bent around a 1/2-inch mandrel with the coating facing outwardly and the coating exhibits substantially no breaks or cracks when tested at 20° F.; and in that when the coating composition is deposited on a metallic substrate and cured, the coated substrate has a Sward hardness of at least 18; said coating composition contains a film-former comprising a polyester-urethane polyol and a curing agent; the polyester-urethane polyol has a hydroxyl value of at least 80 and is prepared by reacting: (1) an aliphatic diisocyanate containing alkyl branching with (2) a polyester polyol formed from reacting: (a) hexahydrophthalic acid or alkyl-substituted hexahydrophthalic acid with (b) a mixed diol comprising: (i) a straight chain aliphatic diol containing from 2 to 20 carbon atoms, (ii) an aliphatic diol containing neopentyl group branching; said polyester-urethane polyol containing 70 to 95 percent by weight acyclic moieties and the sum of the weight percentage of cyclic moieties and the weight percentage of urethane moieties multiplied by 3 is from 15 to 65.

Claim 22

A high solids, solvent-based, thermosetting, one-component coating composition having a sprayability of at least 40 percent, which when cured is weather-durable, and flexible and hard in that when the coating composition is deposited on an elastomeric substrate and cured, the coated substrate can be bent around a 1/2-inch mandrel with the coating facing outwardly and the coating exhibits substantially no breaks or cracks when tested at 20° F.; and in that when the coating composition is deposited on a metallic substrate and cured, the coated substrate has a Sward hardness of at least 18; said coating composition contains a film-former comprising a polyester-urethane polyol and a curing agent; the polyester-urethane polyol has a hydroxyl value of at least 80 and is prepared by reacting: (1) an aliphatic diisocyanate containing alkyl branching with (2) a polyester polyol formed from reacting: (a) hexahydrophthalic acid or alkyl-substituted hexahydrophthalic acid with (b) a mixed diol comprising: (i) a straight chain aliphatic diol containing from 2 to 20 carbon atoms, (ii) an aliphatic diol containing neopentyl group branching; said polyester-urethane polyol containing 70 to 95 percent by weight acyclic moieties and the sum of the weight percentage of cyclic moieties and the weight percentage of urethane moieties multiplied by 3 is from 15 to 65.

Claim 23

A composition of claim 20, wherein the diisocyanate is trimethylhexamethylene diisocyanate.

Claim 24

A composition of claim 20, wherein the acid is hexahydrophthalic.

Claim 25

A composition of claim 20, wherein the diol containing the neopentyl groups is neopentyl glycol.

Claim 26

A composition of claim 20, wherein the straight chain diol is 1,6-hexanediol.

Claim 27

A composition of claim 20, wherein the equivalent ratio of diol to diacid is about 2:1 and the equivalent ratio of the diisocyanate to the polyester polyol is about 1:3-4.