Patent US4551497A successfully refreshed from Google Patents.
US4551497A
Expired / Lapsed
US
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Method of producing surface-treated barium sulfate
Assignee: Onahama Sakai Kagaku KK
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Filing: 1984-12-31
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Granted: 1985-11-05
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Expires: 2004-12-31
Abstract
Abstract A method of producing surface-treated barium sulfate is disclosed which has an improved dispersibility in resins and coating compositions. The method comprises adding an aqueous solution of an alkali silicate to an aqueous slurry of barium sulfate which contains barium ion in excess to deposit barium silicate on the surface of barium sulfate, and then adding to the slurry a mineral acid to decompose the barium silicate to hydrous silica. The thus surface-treated barium sulfate may be further coated with hydrous metal oxides such as alumina or with a silane coupling agent so as to have a more improved dispersibility.
Inventors
- 👤 Kiyoshi Shinozuka
- 👤 Koichi Otu
- 👤 Hiroshi Fukumoto
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-03 20:14
CPC Classifications
C; C09; C09C; C09C1/00; C09C1/02; C09C1/027; C08; C08K; C08K9/00; C08K9/02; C01; C01P; C01P2004/00; C01P2004/60; C01P2004/61; C01P2004/80; C01P2006/00; C01P2006/60
Claims Analysis
Total Claims: 16
Claim 1
Independent Claim
112 words
A resin composition which includes surface-treated barium sulfate particles therein, the barium sulfate particles being produced by a method which comprises: (a) adding an aqueous solution of an alkali silicate to an aqueous feed slurry of barium sulfate which contains barium ions in excess, the alkali silicate being added in amounts of 0.1-30% by weight in terms of silicate based on the weight of barium sulfate in the slurry, to deposit barium silicate on the surface of barium sulfate in the slurry; and then, (b) adding a mineral acid to the resultant slurry and adjusting it to a pH not greater than about 7 to decompose the barium silicate to hydrous silica.
Claim 2
Dependent Claim
112 words
A resin composition which includes surface-treated barium sulfate particles therein, the barium sulfate particles being produced by a method which comprises: (a) adding an aqueous solution of an alkali silicate to an aqueous feed slurry of barium sulfate which contains barium ions in excess, the alkali silicate being added in amounts of 0.1-30% by weight in terms of silicate based on the weight of barium sulfate in the slurry, to deposit barium silicate on the surface of barium sulfate in the slurry; and then, (b) adding a mineral acid to the resultant slurry and adjusting it to a pH not greater than about 7 to decompose the barium silicate to hydrous silica.
Claim 3
Dependent Claim
29 words
The resin composition as claimed in claim 1 wherein barium sulfate particles in the feed slurry are spherical and not more than 0.5 microns in average primary particle size.
Claim 4
Dependent Claim
29 words
The resin composition as claimed in claim 1 wherein barium sulfate particles in the feed slurry are platelets and not more than 0.2-20 microns in average primary particle size.
Claim 5
Dependent Claim
29 words
The resin composition as claimed in claim 1 wherein the feed slurry contains barium ions in amounts of about 0.1-20 mole % based on barium sulfate in the slurry.
Claim 6
Dependent Claim
22 words
The resin composition as claimed in claim 1 wherein the alkali silicate in sodium silicate, potassium silicate or a mixture of these.
Claim 7
Dependent Claim
113 words
The resin composition as claimed in claim 1 wherein the method further includes the steps of (c) adding an aqueous solution of a water-soluble metal compound to the aqueous slurry of barium sulfate having hydrous silica thereon, the metal compound being added in amounts of about 0.1-30% by weight in terms of the weight of anhydrous oxide of the metal based on the weight of barium sulfate in the slurry, and then (d) adjusting the slurry to a pH not greater than about 7 so as to decompose the metal compound to water-insoluble hydrous oxide of the metal and to deposit the hydrous oxide of the metal on the surface of barium sulfate.
Claim 8
Dependent Claim
49 words
The resin composition as claimed in claim 6 wherein the water-soluble compound is at least one compound selected from the group consisting of water-soluble sulfates, basic sulfates, complex salts, halides and nitrates of a metal which is selected from the group consisting of magnesium, aluminum, zinc, zirconium and titanium.
Claim 9
Dependent Claim
15 words
The resin composition as claimed in claim 6 wherein the water-soluble compound is sodium aluminate.
Claim 10
Dependent Claim
28 words
The resin composition as claimed in claim 1 wherein the method further includes a step of treating barium sulfate having hydrous silica thereon with a silane coupling agent.
Claim 11
Dependent Claim
12 words
The resin composition as claimed in claim 1 as a resin molding.
Claim 12
Dependent Claim
12 words
The resin composition as claimed in claim 1 as a coating composition.
Claim 13
Dependent Claim
12 words
The resin composition as claimed in claim 6 as a resin molding.
Claim 14
Dependent Claim
12 words
The resin composition as claimed in claim 6 as a coating composition.
Claim 15
Dependent Claim
12 words
The resin composition as claimed in claim 9 as a resin molding.
Claim 16
Dependent Claim
12 words
The resin composition as claimed in claim 9 as a coating composition.
References Cited (Backward Citations)
US3840381A
Cited
GB1279672A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1988-11-04 | 1989-05-06 | 1989-11-05 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1992-11-04 | 1993-05-06 | 1993-11-05 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1996-11-04 | 1997-05-06 | 1997-11-05 | $7700.00 | Window Closed / Lapsed |