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Process and apparatus for producing high purity oxidation on a semiconductor substrate

Assignee: International Business Machines Corp
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Filing: 1985-10-10
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Granted: 1986-08-19
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Expires: 2005-10-10
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Abstract

Abstract High purity oxidation is produced on a semiconductor substrate. The process includes heating the semiconductor substrate in the presence of an oxidizing ambient in a multi-walled reaction chamber containing a heating element. A halogen-containing ambient flows in an outer portion of the reaction chamber intermediate between the inner portion and the heating element to react with heating element contaminant. In a portion of the reaction chamber position intermediate of the inner portion and the outer portion, a gaseous ambient flows to remove water by-product from the reaction with the halogen which occurs in the outer portion of the reaction chamber. The apparatus for carrying out the above process is also provided.

Inventors

  • 👤 Samuel E. Blum

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 18:50
CPC Classifications
H; H10; H10P; H10P14/00; H10P14/60; H10P14/63; H10P14/6302; H10P14/6304; H10P14/6306; H10P14/6308; H10P14/6309; H10P14/6322; Y; Y10; Y10S; Y10S438/00; Y10S438/935

Claims Analysis

Total Claims: 22
Claim 1
Independent Claim 139 words
A process for producing high-purity oxidation on a semiconductor substrate in a reaction chamber which comprises: heating a semiconductor substrate in the presence of an oxidizing ambient in a multi-walled reaction chamber containing heating element; wherein the semiconductor substrate is placed in the inner portion of the reaction chamber and an oxidizing ambient is caused to flow therein; wherein a halogen-containing ambient is caused to flow in an outer portion of said reaction chamber intermediate between said inner portion and said heating element; reacting said halogen-containing ambient with heating element contaminant coextensive with the surface of the reaction chamber; and causing a gaseous ambient to flow through a portion of said chamber positioned intermediate said inner portion and said outer portion, wherein said gaseous ambient removes water by-product of the reacting with the halogen occurring in the outer portion.
Claim 2
Dependent Claim 139 words
A process for producing high-purity oxidation on a semiconductor substrate in a reaction chamber which comprises: heating a semiconductor substrate in the presence of an oxidizing ambient in a multi-walled reaction chamber containing heating element; wherein the semiconductor substrate is placed in the inner portion of the reaction chamber and an oxidizing ambient is caused to flow therein; wherein a halogen-containing ambient is caused to flow in an outer portion of said reaction chamber intermediate between said inner portion and said heating element; reacting said halogen-containing ambient with heating element contaminant coextensive with the surface of the reaction chamber; and causing a gaseous ambient to flow through a portion of said chamber positioned intermediate said inner portion and said outer portion, wherein said gaseous ambient removes water by-product of the reacting with the halogen occurring in the outer portion.
Claim 3
Dependent Claim 21 words
The process of claim 1 wherein the substrate is heated to a temperature of about 800° C. to about 1200° C.
Claim 4
Dependent Claim 21 words
The process of claim 1 wherein the substrate is heated to a temperature of about 900° C. to about 1100° C.
Claim 5
Dependent Claim 17 words
The process of claim 1 wherein the substrate is heated to a temperature of about 1000° C.
Claim 6
Dependent Claim 15 words
The process of claim 1 wherein a dry oxygen containing gas provides said oxidizing ambient.
Claim 7
Dependent Claim 12 words
The process of claim 4 wherein said oxygen containing gas is oxygen.
Claim 8
Dependent Claim 19 words
The process of claim 4 wherein said oxygen containing gas is a mixture of oxygen with a diluent gas.
Claim 9
Dependent Claim 10 words
The process of claim 6 wherein said mixture is air.
Claim 10
Dependent Claim 13 words
The process of claim 6 wherein said diluent gas is nitrogen or argon.
Claim 11
Dependent Claim 21 words
The process of claim 1 wherein said halogen containing ambient is at a temperature of about 800° C. to 1100° C.
Claim 12
Dependent Claim 18 words
The process of claim 1 wherein said halogen containing ambient is at a temperature of about 1000° C.
Claim 13
Dependent Claim 21 words
The process of claim 1 wherein said halogen containing ambient is a mixture of dry oxygen and a halogen containing gas.
Claim 14
Dependent Claim 16 words
The process of claim 11 wherein said halogen containing gas is HCl or a chlorinated hydrocarbon.
Claim 15
Dependent Claim 31 words
The process of claim 11 wherein the mixture contains about 90% to about 99% by volume of oxygen and about 1% to about 10% by volume of said halogen containing gas.
Claim 16
Dependent Claim 13 words
The process of claim 13 wherein said halogen containing gas is 1,1,1 trichloroethane.
Claim 17
Dependent Claim 10 words
The process of claim 1 wherein said substrate is silicon.
Claim 18
Dependent Claim 22 words
The process of claim 1 wherein said gaseous ambient is selected from the group of dry air, dry oxygen, and dry nitrogen.
Claim 19
Dependent Claim 12 words
The process of claim 1 wherein said gaseous ambient is dry oxygen.
Claim 20
Dependent Claim 12 words
The process of claim 1 wherein said gaseous ambient is dry nitrogen.
Claim 21
Dependent Claim 20 words
The process of claim 1 wherein said gaseous ambient is at a temperature of about 800° C. to 1100° C.
Claim 22
Dependent Claim 17 words
The process of claim 1 wherein said gaseous ambient is at a temperature of about 1000° C.

References Cited (Backward Citations)

US3297411A Cited
US3446659A Cited
US4123229A Cited
US4258658A Cited
US4347431A Cited
GB2082384A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1989-08-18 1990-02-17 1990-08-19 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1993-08-18 1994-02-17 1994-08-19 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1997-08-18 1998-02-17 1998-08-19 $7700.00 Window Closed / Lapsed

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