Platinum and/or palladium containing organopolysiloxane-ammonium compounds, method for their preparation and uses

Claim 1

A platinum and/or palladium containing organopolysiloxane-ammonium compounds comprising at least one unit and is represented by the structural formula: ##STR8## wherein R 1 , R 2 and R 3 are the same or different and represent the structural formula: R.sup.5 --SiO.sub.3/2 ( 2) wherein R 5 is a linear or branched chain alkylene containing from 1 to 12 carbon atoms, cycloalkylene with 5, 7, or 8 carbon atoms or a member represented by the structural formula: ##STR9## and the free valences of the oxygen atom are saturated either by silicon atoms or additional groups of the formula (2) and/or crosslinking bridging agents having the formula: SiO 4/2 , SiR'O 3/2 , SiR 2 'O 2/2 , TiO 4/2 , TiR'O 3/2 , TiR 2 'O 2/2 , AlO 3/2 , AlR'O 2/2 wherein R' is methyl or ethyl and the relationship between silicon in formula (2) to the bridging atoms silicon, titanium and aluminum ranges from 1:0 to 1:10, R 4 has the same meaning as R 1 , R 2 and R 3 and can also be hydrogen, linear or branched alkyl chain of 1 to 10 carbon atoms, cycloalkyl of 5 to 8 carbon atoms or benzyl, Y x- represents at least one Pt or Pd containing member from the group consisting of: PtCl 4 2- , PtCl 6 2- , PtBr 4 2- , PtBr 6 2- , PdCl 4 2- , PdCl 6 2- , PdBr 4 2- , PdBr 6 2- the corresponding salt thereof with an inorganic or organic, 1 to 3 valent anion of an inorganic or organic protonic acid which is capable of reacting with an amine to form a stable salt, and the corresponding hydroxy group terminated member and x is a number from 1 to 3.

Claim 9

A method for the preparation of platinum and/or palladium containing polymeric organosiloxane-ammonium compounds comprising reacting an organopolysiloxane-ammonium compound according to formula (I): ##STR10## wherein R 1 , R 2 and R 3 are the same or different and represent the structural formula: R.sup.5 --SiO.sub.3/2 ( 2) wherein R 5 is a linear or branched chain alkylene containing from 1 to 12 carbon atoms, cycloalkylene with 5, 7 or 8 carbon atoms or a member represented by the structural formula: ##STR11## and the free valences of the oxygen atom are saturated either by silicon atoms or additional groups of the formula (2) and/or crosslinking bridging agents having the formula: SiO 4/2 , SiR'O 3/2 , SiR 2 'O 2/2 , TiO 4/2 , TiR'O 3/2 , TiR 2 'O 2/2 , AlO 3/2 , AlR'O 2/2 wherein R' is methyl or ethyl and the relationship between silicon in formula (2) to the bridging atoms silicon, titanium and aluminum ranges from 1:0 to 1:10, R 4 has the same meaning as R 1 , R 2 and R 3 and can also be hydrogen, linear or branched chain alkyl of 1 to 10 carbon atoms, cycloalkyl of 5 to 8 carbon atoms or benzyl, wherein Y x- represents a 1 to 3 functional anion of an inorganic or organic protonic acid, wherein Y x- represents a 1 to 3 valent anion of an inorganic or organic protonic acid which is capable of reacting with an amine to form a stable salt, with a stoichiometric excess or insufficiency of a compound represented by the formula: M 2 PtCl 4 , M 2 PtCl 6 , M 2 PtBr 4 , M 2 PtBr 6 , M 2 PdCl 4 , M 2 PdCl 6 , M 2 PdBr 4 , M 2 PdBr 6 , or the corresponding water of crystallization containing compound wherein M represents lithium, sodium, potassium, ammonium or hydrogen, in water or a polar organic solvent wherein the platinum or palladium compound is at least partially soluble for the mutual partial or complete exchange of the anions according to the static or dynamic principle, and washing the metal containing solid material.

Claim 10

A method for the preparation of platinum and/or palladium containing polymeric organosiloxane-ammonium compounds comprising reacting an organopolysiloxane-ammonium compound according to formula (I): ##STR10## wherein R 1 , R 2 and R 3 are the same or different and represent the structural formula: R.sup.5 --SiO.sub.3/2 ( 2) wherein R 5 is a linear or branched chain alkylene containing from 1 to 12 carbon atoms, cycloalkylene with 5, 7 or 8 carbon atoms or a member represented by the structural formula: ##STR11## and the free valences of the oxygen atom are saturated either by silicon atoms or additional groups of the formula (2) and/or crosslinking bridging agents having the formula: SiO 4/2 , SiR'O 3/2 , SiR 2 'O 2/2 , TiO 4/2 , TiR'O 3/2 , TiR 2 'O 2/2 , AlO 3/2 , AlR'O 2/2 wherein R' is methyl or ethyl and the relationship between silicon in formula (2) to the bridging atoms silicon, titanium and aluminum ranges from 1:0 to 1:10, R 4 has the same meaning as R 1 , R 2 and R 3 and can also be hydrogen, linear or branched chain alkyl of 1 to 10 carbon atoms, cycloalkyl of 5 to 8 carbon atoms or benzyl, wherein Y x- represents a 1 to 3 functional anion of an inorganic or organic protonic acid, wherein Y x- represents a 1 to 3 valent anion of an inorganic or organic protonic acid which is capable of reacting with an amine to form a stable salt, with a stoichiometric excess or insufficiency of a compound represented by the formula: M 2 PtCl 4 , M 2 PtCl 6 , M 2 PtBr 4 , M 2 PtBr 6 , M 2 PdCl 4 , M 2 PdCl 6 , M 2 PdBr 4 , M 2 PdBr 6 , or the corresponding water of crystallization containing compound wherein M represents lithium, sodium, potassium, ammonium or hydrogen, in water or a polar organic solvent wherein the platinum or palladium compound is at least partially soluble for the mutual partial or complete exchange of the anions according to the static or dynamic principle, and washing the metal containing solid material.

Claim 19

The method for the preparation of a platinum containing polymeric organosiloxane-ammonium compound comprising reacting a polymeric organosiloxane-ammonium compound represented by the recurring units of having the formula: ##STR12## wherein R 1 , R 2 and R 3 represent a group having a structural formula: R.sup.5 --SiO.sub.3/2 ( 2) in which R 5 is linear or branched chain alkyl containing from 1 to 12 carbon atoms, cycloalkyl having 5, 7 or 8 carbon atoms or a member represented by the formula: ##STR13## wherein R 1 , R 2 and R 3 can be the same or different and the free valences of the oxygen are satisfied either by silicon atoms or additional groups of formula (2) or are satisfied by crosslinking bridging agents having the formulae: SiO 4/2 , SiR'O 3/2 , SiR 2 'O 2/2 , TiO 4/2 , TiR'O 3/2 , TiR 2 'O 2/2 , AlO 3/2 , AlR'O 2/2 wherein R' represents methyl or ethyl and the ratio between the silicon atom in formula (2) to the bridging atoms silicon, titanium and aluminum ranges from 1:0 to 1:10, with a stoichiometrically insufficient or excess amount of H 2 PtCl 6 or H 2 PtBr 6 or the corresponding water of crystallization containing materials in water or in a lower alcohol having 1 to 5 carbon atoms according to static or dynamic principles at room temperature or at elevated temperature until a conversion is achieved and the desired product is obtained.

Claim 20

The method for the preparation of a platinum containing polymeric organosiloxane-ammonium compound comprising reacting a polymeric organosiloxane-ammonium compound represented by the recurring units of having the formula: ##STR12## wherein R 1 , R 2 and R 3 represent a group having a structural formula: R.sup.5 --SiO.sub.3/2 ( 2) in which R 5 is linear or branched chain alkyl containing from 1 to 12 carbon atoms, cycloalkyl having 5, 7 or 8 carbon atoms or a member represented by the formula: ##STR13## wherein R 1 , R 2 and R 3 can be the same or different and the free valences of the oxygen are satisfied either by silicon atoms or additional groups of formula (2) or are satisfied by crosslinking bridging agents having the formulae: SiO 4/2 , SiR'O 3/2 , SiR 2 'O 2/2 , TiO 4/2 , TiR'O 3/2 , TiR 2 'O 2/2 , AlO 3/2 , AlR'O 2/2 wherein R' represents methyl or ethyl and the ratio between the silicon atom in formula (2) to the bridging atoms silicon, titanium and aluminum ranges from 1:0 to 1:10, with a stoichiometrically insufficient or excess amount of H 2 PtCl 6 or H 2 PtBr 6 or the corresponding water of crystallization containing materials in water or in a lower alcohol having 1 to 5 carbon atoms according to static or dynamic principles at room temperature or at elevated temperature until a conversion is achieved and the desired product is obtained.