Patent US4652089A successfully refreshed from Google Patents.
US4652089A
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Liquid crystalline compounds and mixtures
Assignee: F Hoffmann La Roche AG
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Filing: 1984-10-22
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Granted: 1987-03-24
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Expires: 2004-10-22
Abstract
Abstract This invention concerns compounds of the formula: <IMAGE> I wherein n is 1 and X is -COO-, -OOC- or -CH2CH2-; or n is O and X is -CH2CH2-; ring A is p-phenylene or trans-1,4-cyclohexylene; R2 is cyano, p-cyanophenyl or, when X is -COO- or -OOC-, R2 may also be p-R3-phenyl or trans-4-R3-cyclohexyl; and R1 and R3 each are straight-chain C1-C10-alkyl. their manufacture and their use for electro-optical purposes and in gas chromatography are described.
Inventors
- 👤 Gottfried Oesterhelt
- 👤 Martin Petrzilka
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 10:44
CPC Classifications
C; C07; C07D; C07D239/00; C07D239/02; C07D239/24; C07D239/26; C07C; C07C255/00; C09; C09K; C09K19/00; C09K19/04; C09K19/06; C09K19/08; C09K19/30; C09K19/3001; C09K19/3028; C09K19/3066; C09K19/3068; C07C2601/00; C07C2601/12; C07C2601/14; C07C2603/00; C07C2603/02; C07C2603/04; C07C2603/22; C07C2603/24; C07C2603/26; C07C2603/40; C07C2603/42; C07C2603/48; C07C2603/50
Claims Analysis
Total Claims: 12
Claim 1
Independent Claim
77 words
A compound of the formula: ##STR9## wherein n is 1 and X is --COO--, --OOC-- or --CH 2 CH 2 --; or n is 0 and X is --CH 2 CH 2 --; ring A is p-phenylene or trans-1,4-cyclohexylene; R 2 is cyano, p-cyanophenyl or, when X is --COO-- or --OOC--, R 2 may also be p-R 3 -phenyl or trans-4-R 3 -cyclohexyl; and R 1 and R 3 each are straight-chain C 1 -C 10 -alkyl.
Claim 2
Dependent Claim
77 words
A compound of the formula: ##STR9## wherein n is 1 and X is --COO--, --OOC-- or --CH 2 CH 2 --; or n is 0 and X is --CH 2 CH 2 --; ring A is p-phenylene or trans-1,4-cyclohexylene; R 2 is cyano, p-cyanophenyl or, when X is --COO-- or --OOC--, R 2 may also be p-R 3 -phenyl or trans-4-R 3 -cyclohexyl; and R 1 and R 3 each are straight-chain C 1 -C 10 -alkyl.
Claim 3
Dependent Claim
9 words
The compound of claim 1, wherein n is 1.
Claim 4
Dependent Claim
20 words
The compound of claim 1, wherein ring A is trans-1,4-cyclohexylene and R 2 is cyano, p-cyanophenyl or p-R 3 -phenyl.
Claim 5
Dependent Claim
17 words
The compound of claim 1 wherein ring A is p-phenylene and R 2 is trans-4-R 3 -cyclohexyl.
Claim 6
Dependent Claim
9 words
The compound of claim 1 wherein X is --COO--.
Claim 7
Dependent Claim
13 words
The compound of claim 1 wherein X is --CH 2 CH 2 --.
Claim 8
Dependent Claim
24 words
The compound of claim 1 wherein R 2 is p-R 3 -phenyl or trans-4-R 3 -cyclohexyl and R 3 is propyl, butyl or pentyl.
Claim 9
Dependent Claim
91 words
A liquid crystalline mixture having at least two components, wherein at least one component is a compound of formula I: ##STR10## wherein n is 1 and X is--COO--, --OOC-- or --CH 2 CH 2 --; or n is 0 and X is --CH 2 CH 2 --; ring A is p-phenylene or trans-1,4-cyclohexylene; R 2 is cyano, p-cyanophenyl or, when X is --COO-- or --OOC--, R 2 may also be p-R 3 -phenyl or trans-4-R 3 -cyclohexyl; and R 1 and R 3 each are straight-chain C 1 -C 10 -alkyl.
Claim 10
Dependent Claim
91 words
A liquid crystalline mixture having at least two components, wherein at least one component is a compound of formula I: ##STR10## wherein n is 1 and X is--COO--, --OOC-- or --CH 2 CH 2 --; or n is 0 and X is --CH 2 CH 2 --; ring A is p-phenylene or trans-1,4-cyclohexylene; R 2 is cyano, p-cyanophenyl or, when X is --COO-- or --OOC--, R 2 may also be p-R 3 -phenyl or trans-4-R 3 -cyclohexyl; and R 1 and R 3 each are straight-chain C 1 -C 10 -alkyl.
Claim 11
Dependent Claim
109 words
An electro-optical cell comprising: (a) two plate means; (b) a liquid crystal means disposed between two plate means and including a compound of the formula: ##STR11## wherein n is 1 and X is --COO--, --OOC-- or --CH 2 CH 2 --; or n is 0 and X is --CH 2 CH 2 --; ring A is p-phenylene or trans-1,4-cyclohexylene; R 2 is cyano, p-cyanophenyl or, when X is --COO-- or --OOC--, R 2 may also be p-R 3 -phenyl or trans-4-R 3 -cyclohexyl; and R 1 and R 3 each are straight-chain C 1 -C 10 -alkyl; and (c) means for applying an electrical potential to said plate means.
Claim 12
Dependent Claim
109 words
An electro-optical cell comprising: (a) two plate means; (b) a liquid crystal means disposed between two plate means and including a compound of the formula: ##STR11## wherein n is 1 and X is --COO--, --OOC-- or --CH 2 CH 2 --; or n is 0 and X is --CH 2 CH 2 --; ring A is p-phenylene or trans-1,4-cyclohexylene; R 2 is cyano, p-cyanophenyl or, when X is --COO-- or --OOC--, R 2 may also be p-R 3 -phenyl or trans-4-R 3 -cyclohexyl; and R 1 and R 3 each are straight-chain C 1 -C 10 -alkyl; and (c) means for applying an electrical potential to said plate means.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1990-03-23 | 1990-09-22 | 1991-03-24 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1994-03-23 | 1994-09-22 | 1995-03-24 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1998-03-23 | 1998-09-22 | 1999-03-24 | $7700.00 | Window Closed / Lapsed |