Tabular silver halide emulsions with ledges

Claim 2

A photographic emulsion comprised of tabular silver halide grains having opposed major faces, characterized in that tabular grains are present having ledges of relatively reduced thickness extending laterally beyond at least one of said major faces.

Claim 3

An emulsion according to claim 1 further characterized in that said tabular grains include laterally offset ledges.

Claim 4

An emulsion according to claim 1 further characterized in that said tabular grains include ledges laterally spaced from both major faces.

Claim 5

An emulsion according to claim 1 further characterized in that said tabular grains include ledges each spaced from one major face and forming an extension of another major face.

Claim 6

An emulsion according to claim 4 further characterized in that next adjacent of said ledges form extensions of different major faces.

Claim 7

An emulsion according to claim 1 further characterized in that said tabular grains having ledges account for at least 50 percent of the total silver halide grain projected area of said emulsion.

Claim 8

An emulsion according to claim 6 further characterized in that said tabular grains having ledges have an average projected area of at least 70 percent of the grain projected area of said emulsion.

Claim 9

An emulsion according to claim 1 in which said ledges account for at least 5 percent of the total projected area of said tabular grains having ledges.

Claim 10

An emulsion according to claim 1 further characterized in that said tabular grains having ledges are comprised of silver bromide or silver bromoiodide.

Claim 11

An emulsion according to claim 1 further characterized in that said silver halide in said tabular grains having ledges consists essentially of silver bromide.

Claim 12

An emulsion according to claim 1 further characterized in that said silver halide in said tabular grains having ledges consists essentially of silver bromoiodide.

Claim 13

An emulsion according to claim 1 further characterized in that said tabular grains having ledges include at least three strata and each of said ledges form extensions of at least two of said strata.

Claim 14

An emulsion according to claim 12 further characterized in that at least a portion of said tabular grains having ledges include at least four strata.

Claim 15

An emulsion according to claim 12 further characterized in that said ledges form at least one acute angle edge lip.

Claim 16

An emulsion according to claim 1 further characterized in that said tabular grains having ledges are of a cubic crystal lattice structure and have opposed major faces lying in {111} crystallographic planes.

Claim 17

An emulsion according to claim 15 further characterized in that said emulsion contains a grain growth modifier capable of selectively restraining deposition of silver halide on grain faces lying in rhombic dodecahedral and trisoctahedral crystallographic planes while permitting deposition of silver halide on grain faces lying in cubic and icositetrahedral crystallographic planes.

Claim 18

An emulsion according to claim 16 further characterized in that said tabular grains having ledges consist essentially of silver bromide or silver bromoiodide containing up to 6 mole percent iodide, based on silver and contain an azaindene grain growth modifier.

Claim 19

An emulsion according to claim 17 further characterized in that said azaindene is a tetraazaindene.

Claim 20

A photographic emulsion comprised of a 5-bromo-4-hydroxy-6-methyl-1,3,3a,7-tetraazaindene and tabular silver bromide grains having opposed major faces lying in {111} crystallographic planes, characterized in that tabular grains accounting for at least 50 percent of the total grain projected area are present having ledges of a thickness less than the spacing between said opposed major faces and extending laterally beyond at least one of said major faces, said ledges accounting for at least 5 percent of the total projected area of said tabular grains having ledges.

Claim 21

A photographic emulsion comprised of a 5-bromo-4-hydroxy-6-methyl-1,3,3a,7-tetraazaindene and tabular silver bromide grains having opposed major faces lying in {111} crystallographic planes, characterized in that tabular grains accounting for at least 50 percent of the total grain projected area are present having ledges of a thickness less than the spacing between said opposed major faces and extending laterally beyond at least one of said major faces, said ledges accounting for at least 5 percent of the total projected area of said tabular grains having ledges.

Claim 22

A photographic emulsion comprised of a 5-bromo-4-hydroxy-6-methyl-1,3,3a,7-tetraazaindene and tabular silver bromoiodide grains containing up to 2 mole percent iodide, based on silver, and having opposed major faces lying in {111} crystallographic planes, characterized in that tabular grains accounting for at least 50 percent of the total grain projected area are present having ledges of a thickness less than the spacing between said opposed major faces and extending laterally beyond at least one of said major faces, said ledges accounting for at least 5 percent of the total projected area of said tabular grains having ledges.

Claim 23

A photographic emulsion comprised of a 5-bromo-4-hydroxy-6-methyl-1,3,3a,7-tetraazaindene and tabular silver bromoiodide grains containing up to 2 mole percent iodide, based on silver, and having opposed major faces lying in {111} crystallographic planes, characterized in that tabular grains accounting for at least 50 percent of the total grain projected area are present having ledges of a thickness less than the spacing between said opposed major faces and extending laterally beyond at least one of said major faces, said ledges accounting for at least 5 percent of the total projected area of said tabular grains having ledges.