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US4739042A
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Halftone gravure printing inks containing pyridone azo dyestuffs
Assignee: Bayer AG
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Filing: 1986-08-04
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Granted: 1988-04-19
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Expires: 2006-08-04
Abstract
Abstract Halftone gravure printing inks containing pyridone azo dyestuffs wherein the dyestuffs are obtained by reacting a pyridone dyestuff of the formula ##STR1## with a dicarboxylic or polycarboxylic acid or a pyridone azo dyestuff of the formula ##STR2## with a dihydroxy or polyhydroxy compound.
Inventors
- 👤 Manfred Lorenz
- 👤 Artur Haus
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-30 20:50
CPC Classifications
C; C09; C09D; C09D11/00; C09D11/02; C09D11/03; C09D11/037; C09B; C09B43/00; C09B43/18; C09B43/26; C09B43/263; C09B43/30; Y; Y10; Y10S; Y10S534/00; Y10S534/02
Claims Analysis
Total Claims: 5
Claim 1
Independent Claim
262 words
A dyestuff which is obtained by reacting a pyridone azo dyestuffs of the formula ##STR52## in which D denotes the radical of a diazo component, T 1 denotes alkyl, aryl or --COOT 4 , T 2 denotes H, --CN, --COOT 4 or --CONH--T 5 (OH) n , T 4 denotes hydrogen or alkyl, if n is 0, T 3 and T 5 each independently represent C 1 -C 22 -alkyl, C 2 -C 22 -alkenyl, C 3 -C 7 -cycloalkyl, benzyl, phenethyl, C 2 -C 18 -alkoxyalkyl, phenoxy-C 1 -C 22 -alkyl or phenoxy-C 2 -C 18 -alkoxy? alkyl and if n is 1, 2, 3 or 4,T 3 and T 5 each independently represent a C 2 -C 18 -alkyl or C 2 -C 18 -alkyl which is interrupted by 1-6 oxygen atoms and m and n denote 0, 1, 2, 3 or 4, subject to the proviso that the sum of m+n is 1, 2, 3 or 4, with oxalic acid or a carboxylic acid of the formula [G']-(COOH).sub.a in which G' denotes an aliphatic or aromatic hydrocarbon radical having 1-51 carbon atoms and a denotes 2, 3 or 4 or a carboxylic acid of the formula [G"]-(OCH.sub.2 CH.sub.2 -COOH).sub.a ' in which G" denotes a saturated or unsaturated hydrocarbon radical having 2 to 20 carbon atoms or a saturated or unsaturated hydrocarbon radical in which the carbon chain can be interrupted by 1-9 non-adjacent oxygen atoms and a' denotes 2, 3, 4 or 5 to form an ester linkage between at least two identical or different pyridone azo dyestuffs.
Claim 2
Dependent Claim
262 words
A dyestuff which is obtained by reacting a pyridone azo dyestuffs of the formula ##STR52## in which D denotes the radical of a diazo component, T 1 denotes alkyl, aryl or --COOT 4 , T 2 denotes H, --CN, --COOT 4 or --CONH--T 5 (OH) n , T 4 denotes hydrogen or alkyl, if n is 0, T 3 and T 5 each independently represent C 1 -C 22 -alkyl, C 2 -C 22 -alkenyl, C 3 -C 7 -cycloalkyl, benzyl, phenethyl, C 2 -C 18 -alkoxyalkyl, phenoxy-C 1 -C 22 -alkyl or phenoxy-C 2 -C 18 -alkoxy? alkyl and if n is 1, 2, 3 or 4,T 3 and T 5 each independently represent a C 2 -C 18 -alkyl or C 2 -C 18 -alkyl which is interrupted by 1-6 oxygen atoms and m and n denote 0, 1, 2, 3 or 4, subject to the proviso that the sum of m+n is 1, 2, 3 or 4, with oxalic acid or a carboxylic acid of the formula [G']-(COOH).sub.a in which G' denotes an aliphatic or aromatic hydrocarbon radical having 1-51 carbon atoms and a denotes 2, 3 or 4 or a carboxylic acid of the formula [G"]-(OCH.sub.2 CH.sub.2 -COOH).sub.a ' in which G" denotes a saturated or unsaturated hydrocarbon radical having 2 to 20 carbon atoms or a saturated or unsaturated hydrocarbon radical in which the carbon chain can be interrupted by 1-9 non-adjacent oxygen atoms and a' denotes 2, 3, 4 or 5 to form an ester linkage between at least two identical or different pyridone azo dyestuffs.
Claim 3
Dependent Claim
175 words
A dyestuff according to claim 1 obtained by reacting pyridone azo dyestuffs of the formula ##STR53## in which T 2 ' denotes H, --CN or --COOT 4 , if n is 0, T 9 represents C 1 -C 22 -alkyl, C 2 -C 22 -alkenyl, C 3 -C 7 -cycloalkyl, benzyl, phenethyl, C 2 -C 18 -alkoxyalkyl, phenoxy-C 1 -C 22 -alkyl or phenoxy-C 2 -C 18 -alkoxyalkyl, if n is 1, 2, 3 or 4,T 9 represents a C 1 -C 12 -alkyl, and D' denotes the radical of a diazo component, with a dihydroxy or polyhydroxy compound of the formula [G'.sub.1 ]--(OH)a.sub.1 in whch G' 1 denotes an aliphatic hydrocarbon radical having 2-54 C atoms and Al denotes 2, 3, 4 or 5 or a diglycol or polyglycol having 3-20 ethylene oxide units, dipropylene or polypropylene glycol having 3-20 propylene oxide units, a copolymer formed from ethylene oxide and propylene oxide, 1,4-bis-(2-hydroxyethoxy)-benzene, 4,4'-bis-(2-hydroxyethoxy)-diphenyl sulphone, 2,2-bis-[4-(2-hydroxyethoxy)-phenyl]-propane, I,5-,2,6-, 2,7-or 1,7-bis-(2-hydroxyethoxy)-naphthaline to form an ester linkage between at least two identical or different pyridone azo dyestuffs.
Claim 4
Dependent Claim
245 words
A dyestuff of the formula [P.sub.y1 ]--N═N--L'-N═N-[P.sub.y2 ] in which [P y1 ] and [P y2 ] denote pyridone radicals which, in one of their tautomeric forms, correspond to the formulae ##STR54## in which T 1 denotes alkyl, aryl or --COOT 4 , T 2 denotes H, --CN, --COOT 4 , or --CONH--T 5 (OH) n , if n is 0, T 3 and T 5 each independently reprsents C 1 -C 22 -alkyl, C 2 -C 22 -alkenyl, C 3 -C 7 -cycloalkyl, benzyl, phenethyl, C 2 -C 18 -alkoxyalkyl, phenoxy-C 1 -C 22 -alkyl or phenoxy-C 2 -C 18 -alkoxy-alkyl, if n is 1,2,3 or 4, T 3 represents a C 2 -C 18 -alkyl or C 2 -C 18 -alkyl which is intrrupted by 1-6 oxygen atoms, T 2 ' denotes H, --CN or --COOT 4 T 4 denotes hydrogen or alkyl, if n is 0, T 9 represents C 1 -C 22 -alkyl, C 2 -C 22 -alkenyl, C 3 -C 7 -cycloalkyl, benzyl, phenethyl, C 2 -C 18 -alkoxyalkyl, phenoxy-C 1 -C 22 -alkyl or phenoxy-C 2 -C 18 -alkoxyalkyl, if n is 1, 2, 3 or 4, T 9 represents a C 1 -C 12 -alkyl, n denotes 0,1,2,3 or 4 and L' rrepresents ##STR55## wherein the cyclopentylene and cyclohexylene radicals are unsubstituted or are substituted C 1 -C 4 -alkyl, and the phenylene radical is unsubstituted or substituted by C 1 -C 4 -alkyl, --NO 2 and Cl.
Claim 5
Dependent Claim
245 words
A dyestuff of the formula [P.sub.y1 ]--N═N--L'-N═N-[P.sub.y2 ] in which [P y1 ] and [P y2 ] denote pyridone radicals which, in one of their tautomeric forms, correspond to the formulae ##STR54## in which T 1 denotes alkyl, aryl or --COOT 4 , T 2 denotes H, --CN, --COOT 4 , or --CONH--T 5 (OH) n , if n is 0, T 3 and T 5 each independently reprsents C 1 -C 22 -alkyl, C 2 -C 22 -alkenyl, C 3 -C 7 -cycloalkyl, benzyl, phenethyl, C 2 -C 18 -alkoxyalkyl, phenoxy-C 1 -C 22 -alkyl or phenoxy-C 2 -C 18 -alkoxy-alkyl, if n is 1,2,3 or 4, T 3 represents a C 2 -C 18 -alkyl or C 2 -C 18 -alkyl which is intrrupted by 1-6 oxygen atoms, T 2 ' denotes H, --CN or --COOT 4 T 4 denotes hydrogen or alkyl, if n is 0, T 9 represents C 1 -C 22 -alkyl, C 2 -C 22 -alkenyl, C 3 -C 7 -cycloalkyl, benzyl, phenethyl, C 2 -C 18 -alkoxyalkyl, phenoxy-C 1 -C 22 -alkyl or phenoxy-C 2 -C 18 -alkoxyalkyl, if n is 1, 2, 3 or 4, T 9 represents a C 1 -C 12 -alkyl, n denotes 0,1,2,3 or 4 and L' rrepresents ##STR55## wherein the cyclopentylene and cyclohexylene radicals are unsubstituted or are substituted C 1 -C 4 -alkyl, and the phenylene radical is unsubstituted or substituted by C 1 -C 4 -alkyl, --NO 2 and Cl.
References Cited (Backward Citations)
DE2434432A1
Cited
US4329283A
Cited
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