Patent US4761069A successfully refreshed from Google Patents.
US4761069A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Contact lens and method of molding
Assignee: Carl Zeiss Vision Australia Holdings Ltd
•
Filing: 1986-03-27
•
Granted: 1988-08-02
•
Expires: 2006-03-27
Abstract
Abstract A soft contact lens made of a hydrated polymer with an overall water content in the range of 40% to 90% by weight has a water content at the front surface of the lens which is at least 3 percentage points higher than the water content at its rear cornea-contacting surface, as measured by use of an Abbe refractometer. The lens is made from a monomer capable of polymerizing to form a clear transparent partially swollen hydrogel polymer and a diluent forming from 15 to 50% by weight of the moulding mixture, which is moulded between a convex and a concave mould member of different materials chosen so that the lens has the different water contents at its surfaces, as mentioned above. After curing, the mould members are separated with the partially swollen lens adhering to the convex mould member and the whole immersed in an aqueous medium, which may be a weak alkali solution, so as to cause the lens to separate from the convex mould member, to substitute water for any replaceable non-aqueous diluent in the lens, and to cause the lens to swell to substantially its fully hydrated state. The swollen lens is then transferred into saline solution which replaces the water and is packaged and sealed in saline solution in a container. The lens may be sterilized by treatment in an autoclave before and/or after packaging and sealing.
Inventors
- 👤 Van-Tan Truong
- 👤 Rodney D. Watkins
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-24 06:18
CPC Classifications
G; G02; G02C; G02C7/00; G02C7/02; G02C7/04; Y; Y10; Y10S; Y10S425/00; Y10S425/808
Claims Analysis
Total Claims: 18
Claim 1
Independent Claim
72 words
A soft contact lens made of a hydrated polymer, having a front surface and a rear cornea-contacting surface and an overall water content in the range of 40% to 90% by weight, wherein the hydrated polymer has a water content at the front surface of the lens which is at least 3 percentage points higher than the water content at its rear cornea-contacting surface, as measured by use of an Abbe refractometer.
Claim 2
Dependent Claim
72 words
A soft contact lens made of a hydrated polymer, having a front surface and a rear cornea-contacting surface and an overall water content in the range of 40% to 90% by weight, wherein the hydrated polymer has a water content at the front surface of the lens which is at least 3 percentage points higher than the water content at its rear cornea-contacting surface, as measured by use of an Abbe refractometer.
Claim 3
Dependent Claim
32 words
A contact lens according to claim 1 wherein the water content at the front surface is from 4 to 25 percentage points higher than the water content at the rear cornea-contacting surface.
Claim 4
Dependent Claim
51 words
A contact lens according to claim 2 wherein the water content at the front surface is in the range from 74 to 91% by weight, while the water content at the rear surface is in the range from 60 to 82% by weight, as measured by use of an Abbe refractometer.
Claim 5
Dependent Claim
236 words
A process for making a soft contact lens, comprising the steps of (a) introducing into a lens casting mould a mixture comprising at least one monomer capable of polymerising to form a clear, transparent, partially swollen hydrogel polymer and a diluent forming from 15 to 50% by weight of the mixture, and causing the monomer or monomers to polymerise to form said hydrogel polymer, the mould cavity being formed between a convex member and a concave member, said mould members having opposed mould surfaces made of different materials chosen so that the lens formed in the mould from the hydrogel polymer has a water content at its convex front surface which is at least 3 percentage points higher than the water content at its concave rear surface, as measured by use of an Abbe refractometer, (b) separating the mould members with the partially swollen lens adhering to the convex mould member, (c) immersing the partially swollen lens, while still adhering to the convex mould member, in an aqueous medium so as to cause the lens to separate from the convex mould member, to substitute water for any replaceable non-aqueous diluent in the lens and to cause the lens to swell to substantially its fully hydrated state, (d) transferring the swollen lens into saline solution to replace substantially all the water by saline solution, and (e) packaging and sealing the lens in saline solution in a container.
Claim 6
Dependent Claim
236 words
A process for making a soft contact lens, comprising the steps of (a) introducing into a lens casting mould a mixture comprising at least one monomer capable of polymerising to form a clear, transparent, partially swollen hydrogel polymer and a diluent forming from 15 to 50% by weight of the mixture, and causing the monomer or monomers to polymerise to form said hydrogel polymer, the mould cavity being formed between a convex member and a concave member, said mould members having opposed mould surfaces made of different materials chosen so that the lens formed in the mould from the hydrogel polymer has a water content at its convex front surface which is at least 3 percentage points higher than the water content at its concave rear surface, as measured by use of an Abbe refractometer, (b) separating the mould members with the partially swollen lens adhering to the convex mould member, (c) immersing the partially swollen lens, while still adhering to the convex mould member, in an aqueous medium so as to cause the lens to separate from the convex mould member, to substitute water for any replaceable non-aqueous diluent in the lens and to cause the lens to swell to substantially its fully hydrated state, (d) transferring the swollen lens into saline solution to replace substantially all the water by saline solution, and (e) packaging and sealing the lens in saline solution in a container.
Claim 7
Dependent Claim
25 words
A process according to claim 4 comprising the further step of sterilising the lens by treatment in an autoclave before and/or after packaging and sealing.
Claim 8
Dependent Claim
32 words
A process according to claim 4 wherein the lens is immersed in a weak alkali solution so as to replace hydrogen on carboxyl groups within the polymer matrix by the alkali cation.
Claim 9
Dependent Claim
41 words
A process according to claim 6 wherein the immersion in weak alkali solution is effected by employing the weak alkali solution as the aqueous medium in which the partially swollen lens is immersed while still adhering to the convex mould member.
Claim 10
Dependent Claim
30 words
A process according to claim 4 wherein the convex mould surface is made of a material having a higher surface energy than the material of the opposed concave mould surface.
Claim 11
Dependent Claim
49 words
A process according to claim 4 wherein the convex mould surface is made of a hydrophilic material having a fine surface finish whereas the opposed concave mould surface is made of a material having a hydrophobic character when in contact with the moulding mixture and an open surface morphology.
Claim 12
Dependent Claim
25 words
A process according to claim 4 wherein the convex mould surface is made of glass and the opposed concave mould surface is made of polypropylene.
Claim 13
Dependent Claim
15 words
A process according to claim 4, wherein the moulding mixture includes an organic polymerisation initiator.
Claim 14
Dependent Claim
18 words
A process according to claim 4 wherein the principal monomer component of the moulding mixture is hydroxyethyl methacrylate.
Claim 15
Dependent Claim
23 words
A process according to claim 12 wherein the moulding mixture also includes one or more of N-vinyl pyrrolidone, methacrylic acid and its esters.
Claim 16
Dependent Claim
28 words
A process according to claim 12 wherein the moulding mixture also includes a minor proportion of difunctional or polyfunctional polymerisable monomers to enhance cross-linking of the hydrogel polymer.
Claim 17
Dependent Claim
32 words
A process according to claim 14 wherein the difunctional or polyfunctional monomers are chosen from divinylbenzene, ethylene glycol diacrylate, ethylene glycol dimethacrylate, propylene glycol diacrylate, propylene glycol dimethacrylate and trimethylol propane trimethacrYlate.
Claim 18
Dependent Claim
51 words
A process according to claim 12, wherein the polymerisation is caused by heating the mou1ding mixture in the mou1d at a temperature rising from substantially 65° C. to substantially 100° C. over a period of substantially 11/4 hours, followed by a secondary cure at substantially 120° C. for substantially 1/2 hour.
References Cited (Backward Citations)
US3361858A
Cited
US4055378A
Cited
US4347198A
Cited
US4495313A
Cited
US4597918A
Cited
US4534916A
Cited
US4680336A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1991-08-02 | 1992-02-01 | 1992-08-02 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1995-08-02 | 1996-02-01 | 1996-08-02 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1999-08-02 | 2000-02-01 | 2000-08-02 | $7700.00 | Window Closed / Lapsed |