Apparatus for decontaminating PCB-contaminated dielectric fluids

Claim 2

Apparatus for reducing the quantity of polychlorinated aromxtic hydrocarbons in an inert organic solvent, said apparatus comprising in combination: A. at least three reactors; B. a main inlet line; C. a separate, valved branch inlet line connecting said main inlet line to each of said reactors; D. a first pump for pumping the solvent through said main and branch inlet lines into said reactors; E. a heater included in said main inlet line for heating the solvent pumped therethrough; F. means for separately introducing metered quantities of reagents to each of said reactors; G. a main outlet line; H. a separate valve branch outlet line connecting each said reactor to said main outlet conduit; I. a separate second pump included in each said branch outlet line for pumping the solvent from said reactors through said branch outlet and main outlet lines; and J. a controller for controlling the operations of said pumps, heater, reagents introducing means, and said valved inlet and outlet branch lines in repeating, timed phased batch sequence such that while solvent is being pumped through said main inlet line to fill one of said reactors during a batch charging cycle, solvent is being pumped through said main outlet line to empty a second one of said reactors during a batch discharging cycle and the polychlorinated aromatic hydrocarbons in the solvent in the third one of said reactors is undergoing reaction with said reagents during a batch reaction cycle.

Claim 3

The apparatus defined in claim 1, wherein said controller controls said repeating, time phased batch sequence such that solvent flow through said main inlet and main outlet lines is substantially uninterrupted from batch to batch.

Claim 4

The apparatus defined in claim 1, which further includes a heat exchanger included in said main inlet and main outlet lines for coupling the solvent concurrently pump therethrough in heat exchanging relation.

Claim 5

The apparatus defined in claim 3, which further includes means connected with said main outlet line for separating the inert organic solvent from the reaction byproducts of said reagents with the polychlorinated aromatic hydrocarbons.

Claim 6

The apparatus defined in claim 4, wherein said reagents are an alkali metal hydroxide and a glycol.

Claim 7

The apparatus defined in claim 5, which further includes means controlled by said controller for introducing during each reaction cycle a metered quantity of a cleansing agent into the solvent in a selected one of said reactors upon completion of the reaction therein of said reagents with the polyhalogenated aromatic hydrocarbons.

Claim 8

The apparatus defined in claim 6, which further includes means for maintaining a blanketing inert gas atmosphere in said reactors.

Claim 9

The apparatus defined in claim 7, which further includes a first recirculating line connecting each said branch outlet line with said main inlet line, whereby the solvent in one of said reactors is pumped through said first recirculating line, said main inlet line, said heater and the associated one of said branch inlet lines back into said one reactor under the control of said controller.

Claim 10

The apparatus defined in claim 8, wherein each said reactor is equipped with an agitator operating under the control of said controller to promote the reaction therein of said reagents with the polyhalogenated aromatic hydrocarbon.

Claim 11

The apparatus defined in claim 9, wherein each said reactor includes a second, separate recirculating line connected between a reactor inlet and the associated one of said branch outlet lines, whereby to provide separate recirculation loops accommodating the flow of the solvent into and out of said reactors under the control of said controller.

Claim 12

The apparatus defined in claim 10, wherein said cleansing agent introducing means is connected to separately introduce said cleansing agent into each said recirculation loop.

Claim 13

The apparatus defined in claim 11, which further includes liquid level sensors for monitoring the level of solvent in each said reactor, said controller operating to control the operations of said first pump and said second pumps in response to signals received from said liquid level sensors.

Claim 14

The apparatus defined in claim 12, which further includes temperture sensors for sensing the temperature of the solvent in said reactors, said controller controlling the energization of said heater and the activation of said reagents introducing means in response to signals received from said temperature sensors.

Claim 15

The apparatus defined in claim 13, wherein said separating means comprises a decanting tank.

Claim 16

Apparatus for decontaminating PCB-contaminated dielectric fluids, said apparatus comprising, in combination: A. at least three reactors; B. a main inlet line; C. a separate branch inlet line connecting said main inlet line to each said reactor; D. a first pump for pumping contaminated dielectric fluid through said main inlet and branch inlet lines into said reactors during separate batch charging cycles; E. a heater included in said main inlet line for heating contaminated dielectric fluid pumped therethrough; F. means separately introducing metered quantities of at least one reagent into each said reactor; G. a main outlet line; H. a separate branch outlet line connecting each said reactor to said main outlet line; I. a separate second pump for pumping decontaminated dielectric fluid from each said reactor through said branch outlet and main outlet lines during separate batch discharging cycles, said batch charging and batch discharging cycles for each said reactor being separated in time by an intervening reaction cycle during which PCBs in the dielectric fluid are chemically decomposed; J. a heat exchanger included in both said main inlet and main outlet lines for coupling the dielectric fluids pumped therethrough in heat exchanging relation; and K. a controller for controlling said pumps, heater and reagent introducing means such that dielectric fluid is normally processed through said reactors on a repetitive, sequential batch basis with said charging, reaction and discharging cycles of the respective reactor batches being respectively phased 120° apart in time.

Claim 17

Apparatus for decontaminating PCB-contaminated dielectric fluids, said apparatus comprising, in combination: A. at least three reactors; B. a main inlet line; C. a separate branch inlet line connecting said main inlet line to each said reactor; D. a first pump for pumping contaminated dielectric fluid through said main inlet and branch inlet lines into said reactors during separate batch charging cycles; E. a heater included in said main inlet line for heating contaminated dielectric fluid pumped therethrough; F. means separately introducing metered quantities of at least one reagent into each said reactor; G. a main outlet line; H. a separate branch outlet line connecting each said reactor to said main outlet line; I. a separate second pump for pumping decontaminated dielectric fluid from each said reactor through said branch outlet and main outlet lines during separate batch discharging cycles, said batch charging and batch discharging cycles for each said reactor being separated in time by an intervening reaction cycle during which PCBs in the dielectric fluid are chemically decomposed; J. a heat exchanger included in both said main inlet and main outlet lines for coupling the dielectric fluids pumped therethrough in heat exchanging relation; and K. a controller for controlling said pumps, heater and reagent introducing means such that dielectric fluid is normally processed through said reactors on a repetitive, sequential batch basis with said charging, reaction and discharging cycles of the respective reactor batches being respectively phased 120° apart in time.

Claim 18

The apparatus defined in claim 15, wherein said charging, reaction, and discharging cycles of each said reactor batch are all of substantially equal time duration as controlled by said controller duration.

Claim 19

The apparatus defined in claim 16, wherein each said charging cycle for anyone of said reactors, each said reaction cycle for any second one of said reactors, and each said discharging cycle for any third one of said reactors all are substantially coincident in time.

Claim 20

The apparatus defined in claim 15, which further includes separate valves in said main inlet and main outlet lines, and said branch inlet, and branch outlet lines whose valve positions are automatically controlled by said controller.

Claim 21

The apparatus defined in claim 15, which further includes means connected with said main outlet line for separating the decontaminated dielectric fluid from the non-PCB byproducts of the reaction of PCBs with said reagent in each said reactor.

Claim 22

The apparatus defined in claim 19, which further includes means controlled by said controller for introducing into each said reactor during each said batch reaction cycle therefor a metered quantity of water.

Claim 23

The apparatus defined in claim 20, wherein said reagent introducing means separately introduces an alkali metal hydroxide and a glycol into said reactors during each said charging cycle therefor.

Claim 24

The apparatus defined in claim 18, which further includes a common recirculating line connecting each said branch oulet line to said main inlet line through separate recirculating valves controlled by said controller, whereby, during a startup routine, said controller interrupts said charging cycles to temporarily establish a recirculating loop through said common recirculating line for each said reactor to permit reheating of contaminated fluid by said heater.

Claim 25

The apparatus defined in claim 18, which further includes a separate recirculating line connected between an inlet of each said reactor and the associated one of said outlet branch lines by a separate recirculating valve controlled by said controller, whereby said controller establishes a separate recirculating loop for the dielectric fluid in each said reactor during each said batch reaction cycle therefor.

Claim 26

The apparatus defined in claim 23, wherein each said reactor is equipped with an agitator controlled by said controller for stirring the dielectric fluid therein during each said batch reaction cycle therfor.

Claim 27

The apparatus defined in claim 18, which further includes separate liquid level detectors for monitoring the dielectric fluid level in said reactors, said controller controlling said batch charging and discharging cycles in response to signals from said liquid level detectors.

Claim 28

The apparatus defined in claim 25, which further includes separate sensors for sensing the temperature of the dielectric fluid in said reactors, said controller controlling the energization of said heater in response to temperature signals received from said sensors.