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US4801573A Expired / Lapsed US ⏱️ 0.0 years remaining

Catalyst for production of hydrocarbons

Assignee: Equinor ASA
•
Filing: 1987-10-23
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Granted: 1989-01-31
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Expires: 2007-10-23
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Abstract

Abstract A catalyst for converting synthesis gas composed of hydrogen and carbon monoxide to hydrocarbons. The catalyst includes cobalt in catalytically active amounts up to about 60 wt % of the catalyst and rhenium in catalytically active amounts of about 0.5 to 50 wt % of the cobalt content of the catalyst supported on alumina. A metal oxide promoter may be added.

Inventors

  • 👤 Sigrid Eri
  • 👤 James G. Goodwin, Jr.
  • 👤 George Marcelin
  • 👤 Trygve Riis

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 23:49
CPC Classifications
C; C07; C07C; C07C1/00; C07C1/02; C07C1/04; C07C1/0425; C07C1/043; C07C1/0435; B; B01; B01J; B01J23/00; B01J23/70; B01J23/76; B01J23/84; B01J23/889; B01J23/8896; C07C2521/00; C07C2521/02; C07C2521/04; C07C2523/00; C07C2523/16; C07C2523/32; C07C2523/36; C07C2523/70; C07C2523/74; C07C2523/75; C07C2523/76; C07C2523/84; C07C2523/889

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 33 words
A catalyst for converting synthesis gas to hydrocarbons comprising amounts of cobalt catalytically active in a Fischer-Tropsch synthesis and relatively lesser amounts of rhenium than the cobalt content composited on an alumina support.
Claim 2
Dependent Claim 33 words
A catalyst for converting synthesis gas to hydrocarbons comprising amounts of cobalt catalytically active in a Fischer-Tropsch synthesis and relatively lesser amounts of rhenium than the cobalt content composited on an alumina support.
Claim 3
Dependent Claim 23 words
The catalyst recited in claim 1 wherein cobalt is present in amounts ranging from 5 to about 60 wt % of the catalyst.
Claim 4
Dependent Claim 24 words
The catalyst recited in claim 1 wherein cobalt is present in amounts ranging from about 10 to about 40 wt % of the catalyst.
Claim 5
Dependent Claim 27 words
The catalyst recited in claim 1 wherein rhenium is present in amounts ranging from about 0.5 to 50 wt % of the cobalt content of the catalyst.
Claim 6
Dependent Claim 27 words
The catalyst recited in claim 1 wherein rhenium is present in amounts ranging from about 1 to 30 wt % of the cobalt content of the catalyst.
Claim 7
Dependent Claim 12 words
The catalyst recited in claim 1 wherein said support is gamma alumina.
Claim 8
Dependent Claim 33 words
The catalyst recited in claim 1 wherein said support has a surface area of at least about 100 m 2 /g and a pore volume of at least about 0.3 cm 3 /g.
Claim 9
Dependent Claim 49 words
The catalyst recited in claim 1 further comprising an effective amount of a promoter selected from the group consisting of oxides of the elements chosen from grous III B, IV B and V B of the periodic table, the lanthanides and the actinides, MgO and MnO, and mixtures thereof.
Claim 10
Dependent Claim 25 words
The catalyst recited in claim 8 wherein said promoter is present in an amount ranging from about 0.1 to 5 wt % of the catalyst.
Claim 11
Dependent Claim 57 words
A catalyst for converting synthesis gas to hydrocarbons comprising cobalt and rhenium composited on an alumina support wherein cobalt is present in catalytically active amounts up to about 60 wt % of the catalyst and rhenium is present in catalytically active amounts from about 0.5 to about 50 wt % of the cobalt content of the catalyst.
Claim 12
Dependent Claim 57 words
A catalyst for converting synthesis gas to hydrocarbons comprising cobalt and rhenium composited on an alumina support wherein cobalt is present in catalytically active amounts up to about 60 wt % of the catalyst and rhenium is present in catalytically active amounts from about 0.5 to about 50 wt % of the cobalt content of the catalyst.
Claim 13
Dependent Claim 50 words
The catalyst recited in claim 10 further comprising an effective amount of a promoter selected from the group consisting of oxides of the elements chosen from the groups III B, IV B and V B of the periodic table, the lanthanides and the actinides, MgO and MnO, and mixtures thereof.
Claim 14
Dependent Claim 33 words
The catalyst recited in claim 10 wherein said support has a surface area of at least about 150 m 2 /g and a pore volume of at least about 0.3 cm 3 /g.
Claim 15
Dependent Claim 25 words
The catalyst recited in claim 10 wherein the sulfur content of the alumina support is kept to levels below about one hundred parts per million.

References Cited (Backward Citations)

US3389965A Cited
JPS4866086A Cited
SU468649A1 Cited
SU610558A1 Cited
US4613624A Cited
US4568663A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1992-01-31 1992-08-01 1993-01-31 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1996-01-31 1996-08-01 1997-01-31 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2000-01-31 2000-08-01 2001-01-31 $7700.00 Window Closed / Lapsed

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