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Removal of sulfur oxides from flue gas

Assignee: Shell USA Inc
•
Filing: 1988-02-05
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Granted: 1989-07-18
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Expires: 2008-02-05
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Abstract

Abstract A method of removing sulfur oxides from flue gas produced by the combustion of a fuel to produce a flue gas containing sulfur oxides and water comprising contacting the moist flue gas with hydrated alkaline earth metal hydroxide particles having a temperature sufficiently low to condense the water vapor present in the flue gas onto the particles and recovering a flue gas reduced in sulfur oxides.

Inventors

  • 👤 Norman C. Samish

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 10:21
CPC Classifications
B; B01; B01D; B01D53/00; B01D53/34; B01D53/46; B01D53/48; B01D53/50; B01D53/501; Y; Y10; Y10S; Y10S62/00; Y10S62/922

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 106 words
A method of removing sulfur oxides from flue gas produced by the combustion of a fuel to produce a flue gas containing sulfur oxides and water vapor comprising contacting the moist flue gas with particles consisting essentially of hydrated alkaline earth metal hydroxide said particles having a temperature sufficiently low to condense the water vapor present in the flue gas onto the particles, the condensed water dissolving the surface oxides contained in the flue gas forming acid which subsequently reacts with the hydrate particles forming alkaline earth metal sulfur compounds, removing the sulfur compounds and excess particles and recovering a flue gas reduced in sulfur oxides.
Claim 2
Independent Claim 106 words
A method of removing sulfur oxides from flue gas produced by the combustion of a fuel to produce a flue gas containing sulfur oxides and water vapor comprising contacting the moist flue gas with particles consisting essentially of hydrated alkaline earth metal hydroxide said particles having a temperature sufficiently low to condense the water vapor present in the flue gas onto the particles, the condensed water dissolving the surface oxides contained in the flue gas forming acid which subsequently reacts with the hydrate particles forming alkaline earth metal sulfur compounds, removing the sulfur compounds and excess particles and recovering a flue gas reduced in sulfur oxides.
Claim 3
Dependent Claim 20 words
A process according to claim 1 wherein the alkaline earth metal hydroxide is calcium hydroxide, magnesium hydroxide or mixtures thereof.
Claim 4
Dependent Claim 15 words
A process according to claim 2 wherein the alkaline earth metal hydroxide is calcium hydroxide.
Claim 5
Dependent Claim 19 words
A process according to claim 1 wherein the hydrate is cooled prior to injection into the moist flue gases.
Claim 6
Dependent Claim 25 words
A process according to claim 1 wherein the hydrate is cooled by injecting hydrate particles and liquid nitrogen essentially simultaneously into the moist flue gases.
Claim 7
Dependent Claim 20 words
A process according to claim 1 wherein the moist flue gas has a temperature of 270° F. to 330° F.
Claim 8
Dependent Claim 16 words
A process according to claim 1 wherein the temperature of the particles is below 100° F.
Claim 9
Dependent Claim 28 words
A process according to claim 2 wherein the moist flue gas has a temperature of 260° F. to 400° F. and the particles temperature is below 100° F.
Claim 10
Dependent Claim 11 words
A process according to claim 8 wherein calcium hydroxide is used.
Claim 11
Dependent Claim 15 words
A process according to claim 9 wherein liquid nitrogen is used to cool the particles.

References Cited (Backward Citations)

US3837820A Cited
US4078390A Cited
US4509436A Cited
US4491461A Cited
US4590049A Cited
US4704972A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1992-07-17 1993-01-16 1993-07-18 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1996-07-17 1997-01-16 1997-07-18 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2000-07-17 2001-01-16 2001-07-18 $7700.00 Window Closed / Lapsed

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