Coating composition and coated product

Claim 2

A coating composition comprising a fluorine-containing copolymer containing at least 10% by weight of fluorine based on fluoroolefin units, being soluble in a solvent and having curable reactive sites, and a polyfunctional organic silicon compound having at least one isocyanate group directly bonded to a silicon atom, said curable reactive sites being capable of reacting with an isocyanate group and the functional groups other than the isocyanate groups of the polyfunctional organic silicon compound being groups capable of reacting with the curable reactive sites of the fluorine-containing copolymer or being hydrolyzable groups each convertible to a silanol group by hydrolysis, any groups attached to silicon of the polyfunctional organic silicon compound other than the isocyanate groups and the hydrolyzable groups being organic groups attached to silicon through a carbon bonded to silicon atom, the solvent being one capable of dissolving both the fluorine-containing copolymer and the polyfunctional organic silicon compound.

Claim 3

The composition according to claim 1, wherein the fluorine-containing copolymer is a copolymer which comprises a fluoroolefin and a vinyl ether as copolymer components and which has an intrinsic viscosity of from 0.05 to 2 dl/g as measured in tetrahydrofuran at 30° C. and is soluble in a solvent.

Claim 4

The composition according to claim 1, wherein the curable reactive sites are hydroxyl groups, amino groups, carboxyl groups or epoxy groups.

Claim 5

The composition according to claim 1, wherein the polyfunctional organic silicon compound is a compound of the formula R 4-p Si(--N═C═O) p wherein p is an integer of from 1 to 4 and R is an organic group, provided that when p is 1, at least one the three R groups is a hydrolyzable organic group.

Claim 6

The composition according to claim 1, which comprises 100 parts by weight of the fluorine-containing copolymer and from 2 to 60 parts by weight of the polyfunctional organic silicon compound.

Claim 7

The composition according to claim 1, which contains the polyfunctional organic silicon compound in an amount of more than a N/n mol per mol of the fluorine-containing copolymer, where N is the number of the curable reactive sites of the fluorine-containing copolymer and n is the number of the functional groups of the polyfunctional organic silicon compound.

Claim 8

A coated product comprising a substrate and a cured coating layer thereon, wherein the coating layer is formed by a coating composition comprising a fluorine-containing copolymer containing at least 10% by weight of fluorine based on fluoroolefin units, being soluble in a solvent and having curable reactive sites, and a polyfunctional organic silicon compound having at least one isocyanate group directly bonded to a silicon atom, said curable reactive sites being capable of reacting with an isocyanate group and the functional groups other than the isocyanate groups of the polyfunctional organic silicon compound being groups capable of reacting with the curable reactive sites of the fluorine-containing copolymer or being hydrolyzable groups each convertible to a silanol group by hydrolysis, any groups attached to silicon of the polyfunctional organic silicon compound other than the isocyanate groups and the hydrolyzable groups being organic groups attached to silicon through a carbon bonded to silicon atom, the solvent being one capable of dissolving both the fluorine-containing copolymer and the polyfunctional organic silicon compound, and the coating layer being cured by a reaction between the curable reactive sites of the fluorine-containing copolymer and the functional groups of the polyfunctional silicon compound.

Claim 9

A coated product comprising a substrate and a cured coating layer thereon, wherein the coating layer is formed by a coating composition comprising a fluorine-containing copolymer containing at least 10% by weight of fluorine based on fluoroolefin units, being soluble in a solvent and having curable reactive sites, and a polyfunctional organic silicon compound having at least one isocyanate group directly bonded to a silicon atom, said curable reactive sites being capable of reacting with an isocyanate group and the functional groups other than the isocyanate groups of the polyfunctional organic silicon compound being groups capable of reacting with the curable reactive sites of the fluorine-containing copolymer or being hydrolyzable groups each convertible to a silanol group by hydrolysis, any groups attached to silicon of the polyfunctional organic silicon compound other than the isocyanate groups and the hydrolyzable groups being organic groups attached to silicon through a carbon bonded to silicon atom, the solvent being one capable of dissolving both the fluorine-containing copolymer and the polyfunctional organic silicon compound, and the coating layer being cured by a reaction between the curable reactive sites of the fluorine-containing copolymer and the functional groups of the polyfunctional silicon compound.

Claim 10

The coated product according to claim 7, wherein the substrate is made of glass.

Claim 11

The coated product according to claim 7, wherein the substrate is made of a metal.

Claim 12

The composition according to claim 3, wherein the polyfunctional organic silicon compound is a compound of the formula R 4-p Si(--N═C═O) p wherein p is an integer of from 1 to 4 and R is an organic group, provided that when p is 1, at least one of the three R groups is a hydrolyzable organic group.

Claim 13

The composition according to claim 10, which comprises 100 parts by weight of the fluorine containing copolymer and from 2 to 60 parts by weight of the polyfunctional organic silicon compound.

Claim 14

The composition according to claim 10, which contains the polyfunctional organic silicon compound in an amount of more than a N/n mol per mol of the fluorine-containing copolymer, where N is the number of the curable reactive sites of the fluorine-containing copolymer and n is the number of the functional groups of the polyfunctional organic silicon compound.

Claim 15

The composition according to claim 12 wherein a non-hydrolyzable R group is an alkyl group, an alkenyl group, a cycloalkyl group and a hydrolyzable R group is an alkoxy group or an acyloxy group.

Claim 16

A coating composition comprising a fluorine-containing copolymer containing at least 10% by weight of fluorine based on fluoroolefin units, being soluble in a solvent and having curable reactive sites, and a polyfunctional organic silicon compound having at least one isocyanate group directly bonded to a silicon atom, the curable reactive sites of the fluorine-containing copolymer being sites each having an active hydrogen atom, an epoxy group, an ester group or a halogen atom in each site, the functional groups other than one or more isocyanate groups of the polyfunctional organic silicon compound being hydrolyzable groups which are convertible to a silanol group by reaction with water, any other group attached to silicon of the polyfunctional organic silicon compound being organic groups attached to silicon through a carbon bonded to the silicon atom, the solvent being one capable of dissolving both the fluorine containing copolymer and the polyfunctional organic silicon compound.

Claim 17

A coating composition comprising a fluorine-containing copolymer containing at least 10% by weight of fluorine based on fluoroolefin units, being soluble in a solvent and having curable reactive sites, and a polyfunctional organic silicon compound having at least one isocyanate group directly bonded to a silicon atom, the curable reactive sites of the fluorine-containing copolymer being sites each having an active hydrogen atom, an epoxy group, an ester group or a halogen atom in each site, the functional groups other than one or more isocyanate groups of the polyfunctional organic silicon compound being hydrolyzable groups which are convertible to a silanol group by reaction with water, any other group attached to silicon of the polyfunctional organic silicon compound being organic groups attached to silicon through a carbon bonded to the silicon atom, the solvent being one capable of dissolving both the fluorine containing copolymer and the polyfunctional organic silicon compound.