Oxidation resistant compositions for use with rare earth magnets

Claim 2

An oxidation resistant composition for a rare earth magnet or magnet material, comprising: an oxidation resistant coating composition cured in the presence of a rare earth magnet or magnet material, said coating composition comprising; (1) an amino containing silane, (2) an epoxy silane, and (3) an epoxy resin, said amino containing silane being an aminosilane or a polyaminosilane having the formula ##STR3## wherein said R 1 group has from 1 to 30 carbon atoms, wherein said R 1 group is an aliphatic, an aromatic, or combinations thereof, wherein n is 1 or 0, wherein R 2 and R 3 , independently, is an aliphatic, an aromatic, or combinations thereof having from 1 to 20 carbon atoms, wherein Y and Z independently is a hydrogen atom, an aminoalkyl group, a polyaminoalkyl group, an aryl group, an alkylalkoxysilane group, or an aminoalkylalkoxysilane group wherein said alkyl group has from 1 to 12 carbon atoms and said alkoxy group has from 1 to 6 carbon atoms, wherein said epoxy silane compound has the formula ##STR4## wherein said R 1 group has from 1 to 30 carbon atoms, wherein said R 1 group is an aliphatic, an aromatic, or combinations thereof, wherein n is 1 or 0, wherein R 2 and R 3 , independently, is an aliphatic, an aromatic, or combinations thereof having from 1 to 20 carbon atoms, and wherein T is an epoxycyclohexyl group, a glycidoxy group, or an alkyl derivative thereof, and the amount of said amino containing silane and said epoxy silane in said coating composition each being from about 5 to about 70 parts by weight per 100 parts by weight of said coating composition, and the amount of said epoxy compound being from about 5 parts to about 90 parts by weight per every 100 parts by weight of said coating composition.

Claim 3

An oxidation resistant composition according to claim 1, wherein said R 1 of said amino containing silane compound and said epoxy silane compound independently is an aliphatic having from 1 to 20 carbon atoms, an aromatic or an alkyl substituted aromatic having from 6 to 30 carbon atoms, and wherein R 2 and R 3 of said amino containing silane and said epoxy silane compound independently is an aliphatic having from 1 to 11 carbon atoms.

Claim 4

An oxidation resistant composition according to claim 2, wherein R 1 of said amino containing silane and said epoxy silane independently is an aliphatic containing from 1 to 11 carbon atoms, an aromatic or an alkyl substituted aromatic containing from 7 to 16 carbon atoms, wherein the amount of said amino containing silane is from about 20 to about 60 parts by weight, wherein the amount of said epoxy silane is from about 10 to about 55 parts by weight, and wherein said epoxy resin is from about 10 to about 50 parts by weight.

Claim 5

An oxidation resistant composition according to claim 3, wherein said R 1 of said amino containing silane compound and said epoxy silane compound independently is an alkyl containing 3 or 4 carbon atoms, an aromatic or an alkyl substituted aromatic containing from 7 to 9 carbon atoms, wherein R 2 and R 3 is an alkyl having from 1 to 2 carbon atoms, wherein said Y aminoalkyl group contains at least one secondary or primary amine moiety, wherein the amount of said amino containing silane is from about 35 to about 50 parts by weight, wherein the amount of said epoxy silane is from about 10 parts to about 40 parts by weight, and wherein the amount of said epoxy resin is from about 20 parts to about 40 parts by weight.

Claim 6

An oxidation resistant composition according to claim 1, wherein said amino containing silane compound is 4-aminobutyltriethoxysilane, (aminoethylaminomethyl)phenethyltrimethoxysilane, N-(2-aminoethyl)-3-aminopropylmethyldimethoxysilane, 3-aminopropyltriethoxysilane, 3-aminopropyltrimethoxysilane, N-2-aminoethyl-3-aminopropyltrimethoxysilane, N-2-aminoethyl-3-aminopropyltris(2-ethylhexoxy)silane, 6-(aminohexylaminopropyl)trimethoxysilane, 3-aminophenyltrimethoxysilane, 3-aminopropylmethyldiethoxysilane, bis[3-(trimethoxysilyl)propyl]ethylenediamine, n-phenylaminopropyltrimethoxysilane, trimethoxysilylpropyldiethylenetramine, ω-aminoundecyltrimethoxysilane, bis[3-(triethoxysilyl)propyl]amine, dimethoxymethylsilylpropyl(polyethyleneimine), trimethoxysilylpropyl(polyethylenimine), and wherein said epoxy silane is (3-glycidoxypropyl)methyldiethoxysilane, (3-glycidoxypropyl)trimethoxysilane, 2-(3,4-epoxycyclohexyl)ethylmethyldimethoxysilane, 2-(3,4-epoxycyclohexyl)ethyltrimethoxysilane and [2-(3,4-epoxy-4-methylcyclohexyl)propyl]methyldiethoxy silane.

Claim 7

An oxidation resistant composition according to claim 1, wherein said amino containing silane is 3-aminopropyltriethoxysilane, 3-aminopropyltrimethoxysilane, or N-2-aminoethyl-3-aminopropyltrimethoxysilane, wherein said epoxy silane compound is (3-glycidoxypropyl)-trimethoxysilane, wherein said epoxy is the reaction product of bisphenol A and epichlorohydrin, wherein the amount of said amino containing silane is from about 20 to about 60 parts by weight, wherein the amount of said epoxy silane is from about 10 to about 55 parts by weight, and wherein the amount of said epoxy resin is from about 10 to about 50 parts by weight.

Claim 8

An oxidation resistant composition according to claim 1, including from about 0.1 to about 10 parts by weight of an oxymetallate inhibitor for every 100 parts by weight of said coating composition.

Claim 9

An oxidation resistant composition according to claim 3, including from about 0.1 to about 10 parts by weight of an oxymetallate inhibitor for every 100 parts by weight of said coating composition, wherein said oxymetallate compound is K 3 PO 4 , Na 2 MoO 4 , K 2 Cr 2 O 7 , MCr 2 O 7 , or MCrO 4 , or combinations thereof, and wherein M is H, Li, Na, or K.

Claim 10

An oxidation resistant composition according to claim 6, including from about 0.1 to about 10 parts by weight of an oxymetallate inhibitor for every 100 parts by weight of said coating composition, wherein said oxymetallate compound is MCr 2 O 7 , MCrO 4 , or combinations thereof, and where M is H, Li, Na, or K.

Claim 11

An oxidation resistant composition for a rare earth magnet or magnet material, comprising: an oxidation resistant coating composition cured in the presence of a rare earth magnet or magnetic material, said coating composition comprising; (1) an amino containing silane; and (2) an epoxy silane or an epoxy resin, said amino containing silane being an aminosilane or a polyaminosilane having the formula ##STR5## wherein said R 1 group has from 1 to 30 carbon atoms, wherein said R 1 group is an aliphatic, an aromatic, or combinations thereof, wherein n is 1 or 0, wherein R 2 and R 3 , independently, is an aliphatic, an aromatic, or combinations thereof having from 1 to 20 carbon atoms, wherein Y and Z independently is a hydrogen atoms, an aminoalkyl group, a polyaminoalkyl group, an aryl group, an alkylalkoxysilane group, or an aminoalkylalkoxysilane group wherein said alkyl group has from 1 to 12 carbon atoms and said alkoxy group has from 1 to 6 carbon atoms, wherein said epoxy silane compound has the formula ##STR6## wherein said R 1 group has from 1 to 30 carbon atoms, wherein said R 1 group is an aliphatic, an aromatic, or combinations thereof, wherein n is 1 or 0, wherein R 2 and R 3 , independently, is an aliphatic, an aromatic, or combinations thereof having from 1 to 20 carbon atoms, and wherein T is an epoxycyclohexyl group, a glycidoxy group, or an alkyl derivative thereof, the amount of said amino containing silane being from about 20 parts to about 80 parts by weight based upon the total weight of said amino containing silane and said remaining compound, or said epoxy resin, and the amount of said epoxy silane or said epoxy resin being from about 80 parts to about 20 parts by weight based upon the total weight of said epoxy silane or said epoxy resin and said amino containing silane.

Claim 12

An oxidation resistant composition for a rare earth magnet or magnet material, comprising: an oxidation resistant coating composition cured in the presence of a rare earth magnet or magnetic material, said coating composition comprising; (1) an amino containing silane; and (2) an epoxy silane or an epoxy resin, said amino containing silane being an aminosilane or a polyaminosilane having the formula ##STR5## wherein said R 1 group has from 1 to 30 carbon atoms, wherein said R 1 group is an aliphatic, an aromatic, or combinations thereof, wherein n is 1 or 0, wherein R 2 and R 3 , independently, is an aliphatic, an aromatic, or combinations thereof having from 1 to 20 carbon atoms, wherein Y and Z independently is a hydrogen atoms, an aminoalkyl group, a polyaminoalkyl group, an aryl group, an alkylalkoxysilane group, or an aminoalkylalkoxysilane group wherein said alkyl group has from 1 to 12 carbon atoms and said alkoxy group has from 1 to 6 carbon atoms, wherein said epoxy silane compound has the formula ##STR6## wherein said R 1 group has from 1 to 30 carbon atoms, wherein said R 1 group is an aliphatic, an aromatic, or combinations thereof, wherein n is 1 or 0, wherein R 2 and R 3 , independently, is an aliphatic, an aromatic, or combinations thereof having from 1 to 20 carbon atoms, and wherein T is an epoxycyclohexyl group, a glycidoxy group, or an alkyl derivative thereof, the amount of said amino containing silane being from about 20 parts to about 80 parts by weight based upon the total weight of said amino containing silane and said remaining compound, or said epoxy resin, and the amount of said epoxy silane or said epoxy resin being from about 80 parts to about 20 parts by weight based upon the total weight of said epoxy silane or said epoxy resin and said amino containing silane.

Claim 13

An oxidation resistant composition according to claim 10, wherein said R 1 of said amino containing silane compound and said epoxy silane compound independently is an aliphatic having from 1 to 20 carbon atoms, or an aromatic or an alkyl substituted aromatic having from 6 to 30 carbon atoms, and wherein R 2 and R 3 of said amino containing silane and said epoxy silane compound independently is an aliphatic having from 1 to 11 carbon atoms.

Claim 14

An oxidation resistant composition according to claim 11, wherein R 1 of said amino containing silane and said epoxy silane independently is an aliphatic containing from 1 to 11 carbon atoms, or an aromatic or an alkyl substituted aromatic containing from 7 to 16 carbon atoms, wherein the amount of said amino containing silane is from about 30 to about 70 parts by weight, and wherein the amount of said epoxy silane or said epoxy resin is from about 70 parts to about 30 parts by weight.

Claim 15

An oxidation resistant composition according to claim 12, wherein said R 1 of said amino containing silane compound and said epoxy silane compound independently is an alkyl containing 3 or 4 carbon atoms, or an aromatic or an alkyl substituted aromatic containing from 7 to 9 carbon atoms, wherein R 2 and R 3 is an alkyl having from 1 to 2 carbon atoms, and wherein said Y aminoalkyl group contains at least one secondary or primary amine moiety.

Claim 16

An oxidation resistant composition according to claim 10, wherein said amino containing silane compound is 4-aminobutyltriethoxysilane, (aminoethylaminomethyl)phenethyltrimethoxysilane, N-(2-aminoethyl)-3-aminopropylmethyldimethoxysilane, 3-aminopropyltriethoxysilane, 3-aminopropyltrimethoxysilane, N-2-aminoethyl-3-aminopropyltrimethoxysilane, N-2-aminoethyl-3-aminopropyltris(2-ethylhexoxy)silane, 6-(aminohexylaminopropyl)trimethoxysilane, 3-aminophenyltrimethoxysilane, 3-aminopropylmethyldiethoxysilane, bis[3-(trimethoxysilyl)propyl]ethylenediamine, n-phenylaminopropyltrimethoxysilane, trimethoxysilylpropyldiethylenetriamine, ω-aminoundecyltrimethoxysilane, bis[3-(triethoxysilyl)propyl]amine, dimethoxymethylsilylpropyl(polyethyleneimine), trimethoxysilylpropyl(polyethylenimine), and wherein said epoxy silane is (3-glycidoxypropyl)methyldiethoxysilane, (3-glycidoxypropyl)trimethoxysilane, 2-(3,4-epoxycyclohexyl)ethylmethyldimethoxysilane, 2-(3,4-epoxycyclohexyl)ethyltrimethoxysilane and [2-(3,4-epoxy-4-methylcyclohexyl)propyl]methyldiethoxy silane.

Claim 17

An oxidation resistant composition according to claim 10, wherein said amino containing silane is 3-aminopropyltriethoxysilane, 3-aminopropyltrimethoxysilane, or N-2-aminoethyl-3-aminopropyltrimethoxysilane, wherein said epoxy silane compound is (3-glycidoxypropyl)-trimethoxysilane, and wherein said epoxy is the reaction product of bisphenol A and epichlorohydrin.

Claim 18

An oxidation resistant composition according to claim 10, including from about 0.1 to about 10 parts by weight of an oxymetallate inhibitor for every 100 parts by weight of said coating composition.

Claim 19

An oxidation resistant composition according to claim 12, including from about 0.1 to about 10 parts by weight of an oxymetallate inhibitor for every 100 parts by weight of said coating composition, wherein said oxymetallate compound is K 3 PO 4 , Na 2 MoO 4 , K 2 Cr 2 O 7 , MCr 2 O 7 , or MCrO 4 , or combinations thereof, and wherein M is H, Li, Na, or K.

Claim 20

An oxidation resistant composition according to claim 15, including from about 0.1 to about 10 parts by weight of an oxymetallate inhibitor for every 100 parts by weight of said coating composition, wherein said oxymetallate compound is MCr 2 O 7 , MCrO 4 , or combinations thereof, and where M is H, Li, Na, or K.