US4912934A
Expired / Lapsed
US
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Hermetically closed circulation type, vapor absorption refrigerator
Assignee: Hitachi Ltd
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Filing: 1988-10-05
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Granted: 1990-04-03
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Expires: 2008-10-05
Abstract
Abstract A hermetically closed circulation type, vapor absorption refrigerator which comprises a high temperature regenerator, a low temperature regenerator a condenser, an evaporator, an absorber and heat exchangers in a hermetically closed circulation system as essential constituent members composed of iron-based materials, where refrigeration is produced by repetitions of concentration of an absorbing solution sealed into the circulation system, dilution with a cooling medium and heat exchange, the inside wall of the high temperature regenerator being provided with a composite film of molybdenum oxides and iron oxide can be operated stably with a high reliability or corrosion resistance.
Inventors
- 👤 Masahiko Itoh
- 👤 Heihatiro Midorikawa
- 👤 Kazutoshi Itoh
- 👤 Yasumasa Furutani
- 👤 Michihiko Aizawa
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-23 22:57
CPC Classifications
C; C09; C09K; C09K5/00; C09K5/02; C09K5/04; C09K5/047; C23; C23C; C23C22/00; C23C22/05; C23C22/60; C23C22/62; C23F; C23F11/00; C23F11/08; F; F25; F25B; F25B15/00; F25B15/008; F25B15/02; F25B15/06; F25B47/00; F25B47/003; Y; Y10; Y10S; Y10S62/00; Y10S62/20
Claims Analysis
Total Claims: 20
Claim 1
Independent Claim
202 words
A process for forming an anti-corrosive film on the inside wall of a high temperature regenerator of a hermetically closed circulation type, vapor absorption refrigerator comprising a high temperature regenerator, a low temperature regenerator, a condenser, an evaporator, an absorber and heat exchangers in a hermetically closed circulation system as essential constituent members composed of iron-based materials, which comprises providing a solution recycle line and a cooling medium supply line to the high temperature regenerator, sealing an aqueous solution containing molybdate ions and having a pH of 7.5 to 11 as a film-forming solution into the high temperature regenerator in advance to a refrigerating operation, recycling the film-forming solution in the high temperature regenerator through the solution recycle line while heating the high temperature refrigerator and supplying a cooling medium to the high temperature regenerator in an amount to balance the amount of water vapor evaporated from the film-making solution through the cooling medium supply line, thereby subjecting the high temperature regenerator to a film-forming operation and forming an anti-corrosive film on the inside wall of the high temperature regenerator, then closing the solution recycle line and the cooling medium supply line and withdrawing the film-forming solution from the high temperature regenerator.
Claim 2
Dependent Claim
202 words
A process for forming an anti-corrosive film on the inside wall of a high temperature regenerator of a hermetically closed circulation type, vapor absorption refrigerator comprising a high temperature regenerator, a low temperature regenerator, a condenser, an evaporator, an absorber and heat exchangers in a hermetically closed circulation system as essential constituent members composed of iron-based materials, which comprises providing a solution recycle line and a cooling medium supply line to the high temperature regenerator, sealing an aqueous solution containing molybdate ions and having a pH of 7.5 to 11 as a film-forming solution into the high temperature regenerator in advance to a refrigerating operation, recycling the film-forming solution in the high temperature regenerator through the solution recycle line while heating the high temperature refrigerator and supplying a cooling medium to the high temperature regenerator in an amount to balance the amount of water vapor evaporated from the film-making solution through the cooling medium supply line, thereby subjecting the high temperature regenerator to a film-forming operation and forming an anti-corrosive film on the inside wall of the high temperature regenerator, then closing the solution recycle line and the cooling medium supply line and withdrawing the film-forming solution from the high temperature regenerator.
Claim 3
Dependent Claim
27 words
A process according to claim 1, wherein the heating of the high temperature regenerator is carried out at the boiling point or higher of the film-forming solution.
Claim 4
Dependent Claim
21 words
A process according to claim 1, wherein the anti-corrosive film is a composite oxide film of molybdenum oxides and iron oxide.
Claim 5
Dependent Claim
25 words
A process according to claim 3, wherein the composite oxide film is richer in the molybdenum oxides outwardly from the inside wall in the film.
Claim 6
Dependent Claim
25 words
A process according to claim 3, wherein the composite oxide film is richer in the iron oxide inwardly toward the inside wall in the film.
Claim 7
Dependent Claim
95 words
A process for forming an anti-corrosive film on the inside wall of a high temperature regenerator of a hermetically closed circulation type, vapor absorption refrigerator comprising a high temperature regenerator, a low temperature regenerator, a condenser, an evaporator, an absorber and heat exchangers in a hermetically closed circulation system as essential constituent members composed of iron-based materials, which comprises introducing a film-making solution into the high temperature regenerator and heating the high temperature regenerator in the presence of the film-making solution, thereby forming an anti-corrosive film on the inside wall of the high temperature regenerator.
Claim 8
Dependent Claim
95 words
A process for forming an anti-corrosive film on the inside wall of a high temperature regenerator of a hermetically closed circulation type, vapor absorption refrigerator comprising a high temperature regenerator, a low temperature regenerator, a condenser, an evaporator, an absorber and heat exchangers in a hermetically closed circulation system as essential constituent members composed of iron-based materials, which comprises introducing a film-making solution into the high temperature regenerator and heating the high temperature regenerator in the presence of the film-making solution, thereby forming an anti-corrosive film on the inside wall of the high temperature regenerator.
Claim 9
Dependent Claim
27 words
A process according to claim 6, wherein the heating of the high temperature regenerator is carried out at the boiling point or higher of the film-forming solution.
Claim 10
Dependent Claim
21 words
A process according to claim 6, wherein the anti-corrosive film is a composite oxide film of molybdenum oxides and iron oxide.
Claim 11
Dependent Claim
25 words
A process according to claim 8, wherein the composite oxide film is richer in the molybdenum oxides outwardly from the inside wall in the film.
Claim 12
Dependent Claim
25 words
A process according to claim 8, wherein the composite oxide film is richer in the iron oxide inwardly toward the inside wall in the film.
Claim 13
Dependent Claim
104 words
A hermetically closed circulation type, vapor absorption refrigerator which comprises a high temperature regenerator, a low temperature regenerator, a condenser, an evaporator, an absorber and heat exchangers in a hermetically closed circulation system as essential constituent members composed of iron-based materials, where refrigeration is produced by repetitions of concentration of an absorbing solution sealed into the circulation system, dilution with a cooling medium and heat exchange, and recycle piping being provided at the high temperature regenerator, thereby passing a film-making solution in a liquid state through the high temperature regenerator and forming an anti-corrosive film on an inside wall of the high temperature regenerator.
Claim 14
Dependent Claim
104 words
A hermetically closed circulation type, vapor absorption refrigerator which comprises a high temperature regenerator, a low temperature regenerator, a condenser, an evaporator, an absorber and heat exchangers in a hermetically closed circulation system as essential constituent members composed of iron-based materials, where refrigeration is produced by repetitions of concentration of an absorbing solution sealed into the circulation system, dilution with a cooling medium and heat exchange, and recycle piping being provided at the high temperature regenerator, thereby passing a film-making solution in a liquid state through the high temperature regenerator and forming an anti-corrosive film on an inside wall of the high temperature regenerator.
Claim 15
Dependent Claim
37 words
A hermetically closed circulation type vapor absorption refrigerator according to claim 11 wherein the anti-corrosive film is a composite oxide film richer in molybdenum oxides than in other oxides outwardly from the inside wall in the film.
Claim 16
Dependent Claim
37 words
A hermetically closed circulation type vapor absorption refrigerator according to claim 11, wherein the anti-corrosive film is a composite oxide film richer in iron oxide than in other oxides inwardly toward the inside wall of the film.
Claim 17
Dependent Claim
50 words
A hermetically closed circulation type vapor absorption refrigerator according to claim 11, wherein the absorbing solution is an aqueous lithium bromide solution containing a small amount of an alkali hydroxide and at least one of very small amounts of molybdate and nitrate and a small amount of a higher alcohol.
Claim 18
Dependent Claim
67 words
A hermetically closed circulation type, vapor absorption refrigerator according to claim 11, wherein the absorbing solution is an aqueous absorbing solution containing 50 to 70% by weight of LiBr, 0.05 to 1.0% by weight of LiOH, 10 to 150 ppm of Li 2 MoO 4 as MoO 4 2- , and 5 to 350 ppm of LiNO 3 as NO 3 - , the balance being water.
Claim 19
Dependent Claim
63 words
A hermetically closed circulation type, vapor absorption refrigerator according to claim 11, wherein the absorbing solution is an aqueous absorbing solution containing 50 to 70% by weight of LiBr, 0.05 to 1.0% by weight of LiOH, 10 to 400 ppm of Li 2 MoO 4 as MoO 4 2- , and 0.2 to 3% by weight of sec-octyl alcohol, the balance being water.
Claim 20
Dependent Claim
51 words
A hermetically closed circulation type, vapor absorption refrigerator according to claim 11, wherein the absorbing solution is an aqueous absorbing solution containing 50 to 70% by weight of LiBr, 0.05-0.5% by weight of LiOH and 50 to 350 ppm of LiNO 3 as NO 3 - , the balance being water.
References Cited (Backward Citations)
US3101277A
Cited
US2476345A
Cited
US2755170A
Cited
US4311024A
Cited
US4487036A
Cited
JPS6029872A
Cited
JPS6211550A
Cited
US4795662A
Cited
US4644907A
Cited
US4760878A
Cited
JPH04226917A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
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| 3.5 Years (Year 4) | 1993-04-02 | 1993-10-02 | 1994-04-03 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1997-04-02 | 1997-10-02 | 1998-04-03 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2001-04-02 | 2001-10-02 | 2002-04-03 | $7700.00 | Window Closed / Lapsed |