Copolyamide containing tertiary amine linkage

Claim 2

A polyamide comprising: (a) from 60 to 99.9 mol % of terephthaloylalkylenediamine constituent units (a) of the general formula (I): ##STR5## (b) from 0 to 39.9 mol % of diacyloylalkylenediamine constituent units (b) of the general formula (II): ##STR6## and (c) from 0.1 to 5 mol % of trivalent diacyloylalkylenediamine constituent units (c) of the general formula (III) or (IV): ##STR7## wherein R 0 is an alkylene group having from 6 to 18 carbon atoms, Ar 0 is a divalent aromatic hydrocarbyl group having from 6 to 12 carbon atoms other than 1,4-phenylene, Ar 1 is a divalent aromatic hydrocarbon group selected from 1,4-phenylene or Ar 0 , X is a member selected from the group consisting of said constituent units (a), (b) and (c) attached to the tertiary nitrogen atom via a terminal carbonyl group, said constituent units (a), (b) and (c) being arranged at random to provide a branched linear structure, said polyamide being free from a gel-forming cross-linked structure and soluble in concentrated sulfuric acid and having: (i) an intrinsic viscosity [η] of from 0.5 to 3 dl/g, as measured in concentrated sulfuric acid at a temperature of 30° C., (ii) a melting point of from 280° C. to 370° C. and a glass transition temperature of from 100° to 160° C., as measured by means of a differential scanning calorimeter at a heating rate of 10° C./min., and (iii) a crystallinity of from 10 to 30%, as measured by X-ray diffractometry.

Claim 3

The polyamide according to claim 1 wherein said terephthaloylalkylenediamine constituent units are derived by a reaction of terephthalic acid with at least one aliphatic alkylenediamine having from 6 to 18 carbon atoms.

Claim 4

The polyamide according to claim 1 wherein said diacyloylalkylenediamine constituent units (b) are derived by a reaction of at least one aromatic dicarboxylic acid other than terephthalic acid with at least one aliphatic alkylenediamine having from 6 to 18 carbon atoms.

Claim 5

The polyamide according to claim 1 wherein said trivalent diacyloylalkylenediamine constitutent units (c) are derived by melt polycondensation of an oligomer comprising said constituent units (a) and (b).

Claim 6

A process for the production of a polyamide comprising: (a) from 60 to 99.9 mol % of terephthaloylalkylenediamine constituent units (a) of the general formula (I): ##STR8## (b) from 0 to 39.9 mol % of diacyloylalkylenediamine constituent units (b) of the general formula (II): ##STR9## and (c) from 0.1 to 5 mol % of trivalent diacyloylalkylenediamine constituent units (c) of the general formula (III) or (IV): ##STR10## wherein R 0 is an alkylene group having from 6 to 18 carbon atoms, Ar 0 is a divalent aromatic hydrocarbyl group having from 6 to 12 carbon atoms other than 1,4-phenylene, Ar 1 is a divalent aromatic hydrocarbon group selected from 1,4-phenylene or Ar 0 , X is a member selected from the group consisting of said constituent units (a), (b) and (c) attached to the tertiary nitrogen atom via a terminal carbonyl group, said constituent units (a), (b) and (c) being arranged at random to provide a branched linear structure, said polyamide being free from a gel-forming cross-linked structure and soluble in concentrated sulfuric acid and having: (i) an intrinsic viscosity [η] of from 0.5 to 3 dl/g, as measured in concentrated sulfuric acid at a temperature of 30° C., (ii) a melting point of from 280° C. to 370° C. and a glass transition temperature of from 100° C. to 160° C., as measured by means of a differential scanning calorimeter at a heating rate of 10° C./min., and (iii) a crystallinity of from 10 to 30%, as measured by X-ray diffractometry, which process comprises the steps of melt polycondensing terephthalic acid and at least one aromatic dicarboxylic acid other than terephthalic acid with at least one aliphatic alkylenediamine having from 6 to 18 carbon atoms at a temperature of from 210° C. to 300° C., and melt polycondensing the oligomer so produced while applying shear stress to the oligomer.

Claim 7

A process for the production of a polyamide comprising: (a) from 60 to 99.9 mol % of terephthaloylalkylenediamine constituent units (a) of the general formula (I): ##STR8## (b) from 0 to 39.9 mol % of diacyloylalkylenediamine constituent units (b) of the general formula (II): ##STR9## and (c) from 0.1 to 5 mol % of trivalent diacyloylalkylenediamine constituent units (c) of the general formula (III) or (IV): ##STR10## wherein R 0 is an alkylene group having from 6 to 18 carbon atoms, Ar 0 is a divalent aromatic hydrocarbyl group having from 6 to 12 carbon atoms other than 1,4-phenylene, Ar 1 is a divalent aromatic hydrocarbon group selected from 1,4-phenylene or Ar 0 , X is a member selected from the group consisting of said constituent units (a), (b) and (c) attached to the tertiary nitrogen atom via a terminal carbonyl group, said constituent units (a), (b) and (c) being arranged at random to provide a branched linear structure, said polyamide being free from a gel-forming cross-linked structure and soluble in concentrated sulfuric acid and having: (i) an intrinsic viscosity [η] of from 0.5 to 3 dl/g, as measured in concentrated sulfuric acid at a temperature of 30° C., (ii) a melting point of from 280° C. to 370° C. and a glass transition temperature of from 100° C. to 160° C., as measured by means of a differential scanning calorimeter at a heating rate of 10° C./min., and (iii) a crystallinity of from 10 to 30%, as measured by X-ray diffractometry, which process comprises the steps of melt polycondensing terephthalic acid and at least one aromatic dicarboxylic acid other than terephthalic acid with at least one aliphatic alkylenediamine having from 6 to 18 carbon atoms at a temperature of from 210° C. to 300° C., and melt polycondensing the oligomer so produced while applying shear stress to the oligomer.

Claim 8

The process according to claim 5 wherein said oligomer has a molecular weight of from 300 to 2,000.

Claim 9

An agent for imparting a gas-barrier property which comprises a polyamide comprising: (a) from 60 to 99.9 mol % of terephthaloylalkylenediamine constituent units (a) of the general formula (I): ##STR11## (b) from 0 to 39.9 mol % of diacyloylalkylenediamine constituent units (b) of the general formula (II): ##STR12## and (c) from 0.1 to 5 mol % of trivalent diacyloylalkylenediamine constituent units (c) of the general formula (III) or (IV): ##STR13## wherein R 0 is an alkylene group having from 6 to 18 carbon atoms, Ar 0 is a divalent aromatic hydrocarbyl group having from 6 to 12 carbon atoms other than 1,4-phenylene, Ar 1 is a divalent aromatic hydrocarbon group selected from 1,4-phenylene or Ar 0 , X is a member selected from the group consisting of said constituent units (a), (b) and (c) attached to the tertiary nitrogen atom via a terminal carbonyl group, said constituent units (a), (b) and (c) being arranged at random to provide a branched linear structure, said polyamide being free from a gel-forming cross-linked structure and soluble in concentrated sulfuric acid and having: (i) an intrinsic viscosity [η] of from 0.5 to 3 dl/g, as measured in concentrated sulfuric acid at a temperature of 30° C., (ii) a melting point of from 280° C. to 370° C. and a glass transition temperature of from 100° C. to 160° C., as measured by means of a differential scanning calorimeter at a heating rate of 10° C./min., and (iii) a crystallinity of from 10 to 30%, as measured by X-ray diffractometry.

Claim 10

An agent for imparting a gas-barrier property which comprises a polyamide comprising: (a) from 60 to 99.9 mol % of terephthaloylalkylenediamine constituent units (a) of the general formula (I): ##STR11## (b) from 0 to 39.9 mol % of diacyloylalkylenediamine constituent units (b) of the general formula (II): ##STR12## and (c) from 0.1 to 5 mol % of trivalent diacyloylalkylenediamine constituent units (c) of the general formula (III) or (IV): ##STR13## wherein R 0 is an alkylene group having from 6 to 18 carbon atoms, Ar 0 is a divalent aromatic hydrocarbyl group having from 6 to 12 carbon atoms other than 1,4-phenylene, Ar 1 is a divalent aromatic hydrocarbon group selected from 1,4-phenylene or Ar 0 , X is a member selected from the group consisting of said constituent units (a), (b) and (c) attached to the tertiary nitrogen atom via a terminal carbonyl group, said constituent units (a), (b) and (c) being arranged at random to provide a branched linear structure, said polyamide being free from a gel-forming cross-linked structure and soluble in concentrated sulfuric acid and having: (i) an intrinsic viscosity [η] of from 0.5 to 3 dl/g, as measured in concentrated sulfuric acid at a temperature of 30° C., (ii) a melting point of from 280° C. to 370° C. and a glass transition temperature of from 100° C. to 160° C., as measured by means of a differential scanning calorimeter at a heating rate of 10° C./min., and (iii) a crystallinity of from 10 to 30%, as measured by X-ray diffractometry.