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US4985471A
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Radiation curable pressure sensitive adhesive composition
Assignee: Resonac Corp
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Filing: 1988-04-19
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Granted: 1991-01-15
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Expires: 2008-04-19
Abstract
Abstract A radiation curable pressure sensitive adhesive composition comprising: (A) 100 parts by weight of a hydrogenated polybutadiene liquid oligomer which has one or more ethylenically unsaturated terminal radicals in its molecule and in which 70% or more of intramolecular carbon-carbon double bonds has been hydrogenated; (B) from 0.2 to 20 parts by weight of a chain transfer agent; and (C) from 0.001 to 1.0 parts by weight of a thermal polymerization inhibitor selected from metal complexes of N-nitrosophenylhydroxylamine; has an excellent storage stability and curing property and can provide pressure sensitive adhesive tapes which have excellent heat resistance and weatherability and are suitably used as surface protecting films.
Inventors
- 👤 Tomohisa Ohta
- 👤 Hiroyuki Hagiwara
- 👤 Hisashige Kanbara
- 👤 Akihiko Dobashi
- 👤 Yasuyuki Seki
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-06 15:57
CPC Classifications
C; C08; C08J; C08J3/00; C08K; C08K5/00; C08K5/16; C08K5/32; C09; C09J; C09J7/00; C09J7/30; C09J7/38; C09J7/381; C09J7/383; C08J2315/00
Claims Analysis
Total Claims: 9
Claim 1
Independent Claim
135 words
A radiation curable pressure sensitive adhesive composition comprising: (A) 100 parts by weight of a hydrogenated 1,2-polybutadiene liquid oligomer which has one or more ethylenically unsaturated terminal radicals in its molecule and in which 70% or more of intramolecular carbon-carbon double bonds has been hydrogenated, said one or more ethylenically unsaturated terminal radicals being attached at both terminals of a main chain of the hydrogenated 1,2-polybutadiene liquid oligomer and the main chain of the hydrogenated 1,2-polybutadiene liquid oligomer being prepared by living anionic polymerization; (B) from 0.2 to 20 parts by weight of a chain transfer agent selected from the group consisting of ethylene glycol bis(thioglycolate), 1,4-butanediol bis(thiopropionate), trimethylolpropane tris(thioglycolate), trimethylolpropane tris(β-thiopropionate), and pentaerythritol tetrakis(β-thiopropionate); and (C) from 0.001 to 1.0 parts by weight of a thermal polymerization inhibitor selected from metal complexes of N-nitrosophenylhydroxylamine.
Claim 2
Dependent Claim
135 words
A radiation curable pressure sensitive adhesive composition comprising: (A) 100 parts by weight of a hydrogenated 1,2-polybutadiene liquid oligomer which has one or more ethylenically unsaturated terminal radicals in its molecule and in which 70% or more of intramolecular carbon-carbon double bonds has been hydrogenated, said one or more ethylenically unsaturated terminal radicals being attached at both terminals of a main chain of the hydrogenated 1,2-polybutadiene liquid oligomer and the main chain of the hydrogenated 1,2-polybutadiene liquid oligomer being prepared by living anionic polymerization; (B) from 0.2 to 20 parts by weight of a chain transfer agent selected from the group consisting of ethylene glycol bis(thioglycolate), 1,4-butanediol bis(thiopropionate), trimethylolpropane tris(thioglycolate), trimethylolpropane tris(β-thiopropionate), and pentaerythritol tetrakis(β-thiopropionate); and (C) from 0.001 to 1.0 parts by weight of a thermal polymerization inhibitor selected from metal complexes of N-nitrosophenylhydroxylamine.
Claim 3
Dependent Claim
45 words
The radiation curable pressure sensitive adhesive composition according to claim 1, wherein said ethylenically unsaturated terminal radical is selected from the group consisting of vinyloxy radical, vinyloxycarbonyl radical, acryloyl radical, methacryloyl radical, acrylamido radical, methacryloylamido radical allyl, radical, allyloxy radical, allylthio radical, and vinylthio radical.
Claim 4
Dependent Claim
40 words
The radiation curable pressure sensitive adhesive composition according to claim 1, wherein said hydrogenated 1,2-polybutadiene oligomer has a weight average molecular weight of 2,000 to 10,000 and has a viscosity of not more than 5×10 5 cps at 50° C.
Claim 5
Dependent Claim
19 words
The radiation curable pressure sensitive adhesive composition according to claim 1, wherein said chain transfer agent is trimethylolpropane tris(β-thiopropionate).
Claim 6
Dependent Claim
21 words
The radiation curable pressure sensitive adhesive composition according to claim 1, wherein said thermal polymerization inhibitor is aluminum complex of N-nitrosophenylhydroxylamine.
Claim 7
Dependent Claim
71 words
The radiation curabole pressure sensitive adhesive composition according to claim 1, wherein said oligomer is obtained by 1,2-polymerization of CH 2 ═CHR 1 --CR 2 ═CH 2 wherein each R 1 and R 2 independently represent a hydrogen atom, a C 1 -C 10 alkyl radical, a C 6 -C 10 cycloalkyl radical, a C 6 -C 10 aryl radical, a C 7 -C 10 alaryl radical or a halogen radical.
Claim 8
Dependent Claim
32 words
The radiation curable pressure sensitive adhesive composition according to claim 6, wherein R 1 and R 2 represent a hydrogen atom, a C 1 -C 10 alkyl radical or a chlorine radical.
Claim 9
Dependent Claim
29 words
The radiation curable pressure sensitive adhesive composition according to claim 6, wherein R 1 and R 2 independently represent a halogen atom, a methyl radical or a chlorine radical.
References Cited (Backward Citations)
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