Patent US3527906A successfully refreshed from Google Patents.
Patent US5019292A successfully refreshed from Google Patents.
← Back to Patent Explorer
US5019292A Expired / Lapsed US ⏱️ 0.0 years remaining

Detergent compositions

Assignee: Procter and Gamble Co
•
Filing: 1988-12-21
•
Granted: 1991-05-28
•
Expires: 2008-12-21
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract Detergent compositions are disclosed which comprise, as a fabric softening ingredient, a fabric softening clay. The fabric softening clay is a hectorite of natural origin, having a layer change distribution such that at least 50% is in the range 0.23-0.31. The clays preferably exhibit Relative Deposition values of at least 2.5.

Inventors

  • 👤 Andre C. Baeck
  • 👤 Young S. Oh

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 10:43
CPC Classifications
C; C11; C11D; C11D3/00; C11D3/0005; C11D3/001; C11D3/02; C11D3/12; C11D3/124; C11D3/1246; C11D3/1253

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 293 words
A granular detergent composition comprising: at least about 1% of a detersive surfactant; from about 5% to about 35% detergent builders; from about 1% to about 25% of a hectorite clay as a fabric softening ingredient, wherein said hectorite clay consists essentially of clay of natural origin having the general formula: ##EQU3## wherein Me III is Al, Fe, or B; or y=0; M n+ is a monovalent (n=1) or divalent (n=2) metal ion, said clay having a layer charge distribution (x+y) such that at least 50% of the layer charge is in the range of from about 0.23 to about 0.31; and in addition to said hectorite clay, from about 1% to about 10% of an additional fabric softening ingredient comprising: an amine of the formula R 1 R 2 R 3 N, wherein R 1 is selected from C 6 to C 20 hydrocarbyl groups, R 2 is selected from C 1 to C 20 hydrocarbyl groups and R 3 is selected from C 1 to C 20 hydrocarbyl or hydrogen groups; or an amide of the formula R 10 R 11 NCOR 12 , wherein R 10 and R 11 are independently selected from C 1 -C 22 alkyl, alkenyl, hydroxy alkyl, aryl, and alkyl-aryl groups, R 12 is hydrogen, a C 1 -C 22 alkyl or alkenyl, an aryl group, an alkyl-aryl group, or an O-R 13 group, wherein R 13 is selected from a C 1 -C 22 alkyl or alkenyl group, an aryl, or an alkyl-aryl group; or a 1-(higher alkyl) amide (lower alkyl)-2-(higher alkyl) imidazoline, wherein said higher alkyl is an alkyl having from about 12 to about 22 carbon atoms, and said lower alkyl is an alkyl having from about 1 to about 4 carbon atoms.
Claim 2
Dependent Claim 293 words
A granular detergent composition comprising: at least about 1% of a detersive surfactant; from about 5% to about 35% detergent builders; from about 1% to about 25% of a hectorite clay as a fabric softening ingredient, wherein said hectorite clay consists essentially of clay of natural origin having the general formula: ##EQU3## wherein Me III is Al, Fe, or B; or y=0; M n+ is a monovalent (n=1) or divalent (n=2) metal ion, said clay having a layer charge distribution (x+y) such that at least 50% of the layer charge is in the range of from about 0.23 to about 0.31; and in addition to said hectorite clay, from about 1% to about 10% of an additional fabric softening ingredient comprising: an amine of the formula R 1 R 2 R 3 N, wherein R 1 is selected from C 6 to C 20 hydrocarbyl groups, R 2 is selected from C 1 to C 20 hydrocarbyl groups and R 3 is selected from C 1 to C 20 hydrocarbyl or hydrogen groups; or an amide of the formula R 10 R 11 NCOR 12 , wherein R 10 and R 11 are independently selected from C 1 -C 22 alkyl, alkenyl, hydroxy alkyl, aryl, and alkyl-aryl groups, R 12 is hydrogen, a C 1 -C 22 alkyl or alkenyl, an aryl group, an alkyl-aryl group, or an O-R 13 group, wherein R 13 is selected from a C 1 -C 22 alkyl or alkenyl group, an aryl, or an alkyl-aryl group; or a 1-(higher alkyl) amide (lower alkyl)-2-(higher alkyl) imidazoline, wherein said higher alkyl is an alkyl having from about 12 to about 22 carbon atoms, and said lower alkyl is an alkyl having from about 1 to about 4 carbon atoms.
Claim 3
Dependent Claim 40 words
A granular detergent composition according to claim 1, wherein said hectorite clay has a distribution of layer charge (x+y) such that at least about 65% of the layer charge is in the range of from about 0.23 to about 0.31.
Claim 4
Dependent Claim 52 words
A granular detergent composition according to claim 2, comprising from about 1% to about 25% of a hectorite clay of natural origin, wherein cotton terry towels laundered with a detergent composition containing about 10% (weight) of the hectorite clay show a reduction of the shear hysteresis, 2HG5, of at least about 32%.
Claim 5
Dependent Claim 20 words
A granular detergent composition according to claim 3, wherein the reduction of the shear hysteresis is at least about 35%.
Claim 6
Independent Claim 128 words
A method for washing and softening fabrics with a detergent composition containing a fabric softening clay, wherein said detergent comprises at least about 1% of a detersive surfactant, from about 5% to about 35% detergent builders, and from about 1% to about 25% of a hectorite clay of natural origin, said hectorite clay having the general formula: ##EQU4## wherein Me III is Al, Fe, or B; or y=0; M n+ is a monovalent (n=1) or divalent (n=2) metal ion, said clay having a layer charge distribution (x+y) such that at least 50% of the layer charge is in the range of from about 0.23 to about 0.31, and wherein said detergent composition is used at a concentration of at least about 500 ppm in an aqueous laundry bath.
Claim 7
Independent Claim 128 words
A method for washing and softening fabrics with a detergent composition containing a fabric softening clay, wherein said detergent comprises at least about 1% of a detersive surfactant, from about 5% to about 35% detergent builders, and from about 1% to about 25% of a hectorite clay of natural origin, said hectorite clay having the general formula: ##EQU4## wherein Me III is Al, Fe, or B; or y=0; M n+ is a monovalent (n=1) or divalent (n=2) metal ion, said clay having a layer charge distribution (x+y) such that at least 50% of the layer charge is in the range of from about 0.23 to about 0.31, and wherein said detergent composition is used at a concentration of at least about 500 ppm in an aqueous laundry bath.
Claim 8
Dependent Claim 34 words
A granular detergent composition according to claim 1 wherein R 1 and R 2 of said amine are each alkyl having from about 12 to about 18 carbon atoms, and R 3 is methyl.
Claim 9
Dependent Claim 39 words
A granular detergent composition according to claim 6 wherein the amine is present in the form of a complex with a fatty acid of the formula RCOOH, wherein R is a C 9 to C 20 alkyl or alkenyl.
Claim 10
Dependent Claim 72 words
A granular detergent composition according to claim 7 wherein the amine is present in form of a complex with a phosphate ester of the formula: ##STR4## wherein R 8 and R 9 are C 1 -C 20 alkyl, or ethoxylated alkyl groups of the general formula alkyl-(OCH 2 CH 2 ) y , wherein the alkyl substituent is C 1 -C 20 , and y is an integer of 1 to 15.
Claim 11
Dependent Claim 39 words
A granular detergent composition according to claim 4 wherein the amide is present in the form of a composite with the fatty acid of the formula RCOOH, wherein R is a C 9 to C 20 alkyl or alkenyl.
Claim 12
Dependent Claim 77 words
A granular detergent composition according to claim 4 further comprising from about 5% to about 35% of a builder system, said builder system comprising: (a) from about 1% to about 99% by weight of a tartrate monosuccinate component of the structure: ##STR5## wherein X is H or a salt-forming cation; and (b) from about 1% to about 99% by weight of a tartrate disuccinate component of the structure: ##STR6## wherein X is H or a salt-forming cation.
Claim 13
Dependent Claim 34 words
A granular detergent composition according to claim 4 comprising from about 1% to about 25% of a hectorite clay of natural origin, wherein the relative deposition of the clay is at least about 2.5.
Claim 14
Dependent Claim 20 words
A granular detergent composition according to claim 11, wherein the Relative Deposition of the clay is at least about 2.7.
Claim 15
Dependent Claim 20 words
A granular detergent composition according to claim 12, wherein the Relative Deposition of the clay is at least about 2.9.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1994-05-27 1994-11-26 1995-05-28 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1998-05-27 1998-11-26 1999-05-28 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2002-05-27 2002-11-26 2003-05-28 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag