Patent US5118400A successfully refreshed from Google Patents.
US5118400A
Expired / Lapsed
US
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Method of making biocompatible electrodes
Assignee: Spire Corp
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Filing: 1990-01-29
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Granted: 1992-06-02
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Expires: 2010-01-29
Abstract
Abstract A process of improving the sensing function of biocompatible electrodes and the product so made are disclosed. The process is designed to alter the surfaces of the electrodes at their tips to provide increased surface area and therefore decreased contact resistance at the electrode-tissue interface for increased sensitivity and essentially includes rendering the tips atomically clean by exposing them to bombardment by ions of an inert gas, depositing an adhesion layer on the cleaned tips, forming a hillocked layer on the adhesion layer by increasing the temperature of the tips, and applying a biocompatible coating on the hillocked layer. The resultant biocompatible electrode is characterized by improved sensitivity, minimum voltage requirement for organ stimulation and a longer battery life for the device in which it is employed.
Inventors
- 👤 John S. Wollam
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-24 15:15
CPC Classifications
C; C23; C23C; C23C14/00; C23C14/06; C23C14/14; C23C14/16; C23C14/02; C23C14/021; C23C14/022; C23C14/0605
Claims Analysis
Total Claims: 12
Claim 1
Independent Claim
195 words
A process of making biocompatible electrode tips characterized by enhanced electrical properties comprising: (a) cleaning a plurality of electrode tips of contaminants; (b) introducing said tips cleaned of contaminants into a sputtering chamber; (c) evacuating said chamber to a vacuum of at least about 10 -7 torr; (d) introducing an inert gas into said chamber and generating a plasma discharge therein; (e) exposing said cleaned tips to bombardment by ions of said inert gas; (f) depositing an adhesion layer on said tips; (g) depositing a hillocked layer on said adhesion layer; and (h) depositing a biocompatible coating on said hillocked layer; (i) during said exposing said cleaned tips to said bombardment by ions of said inert gas, power to generate said plasma discharge at a first level is first applied to said electrode tips: (j) power is next applied to a sputtering electrode carrying a target comprised of a material designed to form said adhesion layer; (k) said depositing said hillocked layer on said adhesion layer is effected at a second power level in said plasma discharge so as to raise the temperature of said electrode tips, facilitating thereby the deposition of said hillocked layer.
Claim 2
Dependent Claim
195 words
A process of making biocompatible electrode tips characterized by enhanced electrical properties comprising: (a) cleaning a plurality of electrode tips of contaminants; (b) introducing said tips cleaned of contaminants into a sputtering chamber; (c) evacuating said chamber to a vacuum of at least about 10 -7 torr; (d) introducing an inert gas into said chamber and generating a plasma discharge therein; (e) exposing said cleaned tips to bombardment by ions of said inert gas; (f) depositing an adhesion layer on said tips; (g) depositing a hillocked layer on said adhesion layer; and (h) depositing a biocompatible coating on said hillocked layer; (i) during said exposing said cleaned tips to said bombardment by ions of said inert gas, power to generate said plasma discharge at a first level is first applied to said electrode tips: (j) power is next applied to a sputtering electrode carrying a target comprised of a material designed to form said adhesion layer; (k) said depositing said hillocked layer on said adhesion layer is effected at a second power level in said plasma discharge so as to raise the temperature of said electrode tips, facilitating thereby the deposition of said hillocked layer.
Claim 3
Dependent Claim
57 words
The process of claim 1 wherein said inert gas is one of a group consisting of argon, neon, krypton, and xenon; wherein said adhesion layer is formed of a group of materials consisting of titanium, zirconium, chromium, and nickel; and wherein said biocompatible coating is formed of a group of materials consisting of platinum, platinum-rhodium, and carbon.
Claim 4
Dependent Claim
42 words
The process of claim 1 further including a step of depositing a second adhesion layer on said hillocked layer before depositing said biocompatible coating thereon; and further including a step of depositing a second biocompatible coating on top of said biocompatible coating.
Claim 5
Dependent Claim
38 words
The process of claim 3 wherein said hillocked layer is formed of a group of materials consisting of aluminum, titanium, and zirconium, and wherein said second coating is formed of a group of materials consisting of elemental carbon.
Claim 6
Dependent Claim
15 words
The process of claim 1 wherein said electrode tips comprise assemblies of fine metal wires.
Claim 7
Dependent Claim
15 words
The process of claim 1 wherein said electrode tips comprise agglomerations of fine metal particles.
Claim 8
Dependent Claim
130 words
A process of making biocompatible electrode tips characterized by enhanced electrical properties comprising: (a) cleaning a plurality of electrode tips of contaminants; (b) introducing said tips cleaned of contaminants into a sputtering chamber; (c) evacuating said chamber to a vacuum of at least about 10 -7 torr; (d) introducing an inert gas into said chamber and generating a plasma discharge therein; (e) exposing said cleaned tips to bombardment by ions of said inert gas; (f) depositing an adhesion layer on said tips; (g) depositing a hillocked layer on said adhesion layer; and (h) depositing a biocompatible coating on said hillocked layer; (i) said cleaning of said plurality of electrode tips being effected by solvent rinsing, with ultrasonic agitation, in a beaker, followed by allowing said rinsed tips to drain dry.
Claim 9
Dependent Claim
130 words
A process of making biocompatible electrode tips characterized by enhanced electrical properties comprising: (a) cleaning a plurality of electrode tips of contaminants; (b) introducing said tips cleaned of contaminants into a sputtering chamber; (c) evacuating said chamber to a vacuum of at least about 10 -7 torr; (d) introducing an inert gas into said chamber and generating a plasma discharge therein; (e) exposing said cleaned tips to bombardment by ions of said inert gas; (f) depositing an adhesion layer on said tips; (g) depositing a hillocked layer on said adhesion layer; and (h) depositing a biocompatible coating on said hillocked layer; (i) said cleaning of said plurality of electrode tips being effected by solvent rinsing, with ultrasonic agitation, in a beaker, followed by allowing said rinsed tips to drain dry.
Claim 10
Dependent Claim
153 words
A process of making biocompatible electrode tips characterized by enhanced electrical properties comprising: (a) cleaning a plurality of electrode tips of contaminants; (b) introducing said tips cleaned of contaminants into a sputtering chamber; (c) evacuating said chamber to a vacuum of at least about 10 -7 torr; (d) introducing an inert gas and oxygen into said chamber, and positioning a seed target therein; (e) exposing said cleaned tips and seed target to bombardment by ions of said inert gas, and to partial pressure of said oxygen; (f) depositing an adhesion layer on said tips; (g) depositing a hillocked layer on said adhesion layer; and (h) depositing a biocompatible coating on said hillocked layer; (i) said seed target being in the form of a mesh of wires or filaments interposed between an ion source and the electrode tips; (j) said oxygen being present therein at a partial pressure of about 2 to 5 percent.
Claim 11
Dependent Claim
153 words
A process of making biocompatible electrode tips characterized by enhanced electrical properties comprising: (a) cleaning a plurality of electrode tips of contaminants; (b) introducing said tips cleaned of contaminants into a sputtering chamber; (c) evacuating said chamber to a vacuum of at least about 10 -7 torr; (d) introducing an inert gas and oxygen into said chamber, and positioning a seed target therein; (e) exposing said cleaned tips and seed target to bombardment by ions of said inert gas, and to partial pressure of said oxygen; (f) depositing an adhesion layer on said tips; (g) depositing a hillocked layer on said adhesion layer; and (h) depositing a biocompatible coating on said hillocked layer; (i) said seed target being in the form of a mesh of wires or filaments interposed between an ion source and the electrode tips; (j) said oxygen being present therein at a partial pressure of about 2 to 5 percent.
Claim 12
Dependent Claim
37 words
The process of claim 8 wherein said inert gas is one of a group consisting of argon, neon, krypton, and xenon; and wherein said seed target is one of a group consisting of tantalum, titanium, and carbon.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1995-06-02 | 1995-12-02 | 1996-06-02 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1999-06-02 | 1999-12-02 | 2000-06-02 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2003-06-02 | 2003-12-02 | 2004-06-02 | $7700.00 | Window Closed / Lapsed |