Organic electroluminescence device with oligomers

Claim 2

An organic electroluminescence device having a high brightness of 50 cd/m 2 or more and a luminous efficiency of 0.02 lm/W or more, comprising an organic semiconductor zone and an organic insulator zone which are sandwiched between electrodes, the organic insulator zone comprising an organic light emitting area, and the organic semiconductor zone comprising an electroconducting oligomer.

Claim 3

The organic electroluminescence device according to claim 1 wherein the organic insulator zone comprises an electron barrier area.

Claim 4

The organic electroluminescence device according to claim 1 wherein the organic insulator zone comprises a hole barrier area.

Claim 5

The organic electroluminescence device according to any one of claims 1 to 3 having a diode function with a rectification ratio of 10 2 or more in the working of light emission.

Claim 6

The organic electroluminescence device according to claim 1, wherein the electroconducting oligomer is a thiophene-containing oligomer in the form of a thin film having a thickness of 10 nm to 100 nm; the organic light emitting zone comprises an organic compound in the form of a thin film having a thickness of 5 nm to 5 μm, having an ionization energy of 6 eV or less and having an electron affinity of 2.5 eV or more.

Claim 7

The organic electroluminescence device according to claim 5, wherein the electroconducting oligomer is selected from the group consisting of α-quinquethiophene and α-sexithiophene.

Claim 8

The organic electroluminescence device according to claim 5, wherein the electroconducting oligomer is selected from the group consisting of ##STR23## the organic light emitting zone comprises an organic compound selected from the group consisting of

Claim 9

5-bis(5,7-di-t-pentyl-2-benzooaxazolyl)-1,3,4-thiadiazole, 4,4'-bis(5,7-t-pentyl-2-benzooxazolyl)stilbene, 4,4'-bis(5,7-di-(2-methyl-2-butyl)-2-benzooxazolyl)stilbene, 2,5-bis(5,7-di-t-pentyl-2-benzooxazolyl)thiophene, 2,5-bis(5-(α,α-dimethylbenzyl)-2-benzooxazolyl)thiophene, 2,5-bis(5,7-di-(2-methyl-2-butyl)-2-benzooxazolyl)-3,4-diphenylthiophene, 2,5-bis(5-methyl-2-benzooxazolyl)thiophene, 4,4'-bis(2-benzooxazolyl)biphenyl, 5-methyl-2-(2-(4-(5-methyl-2-benzooxazolyl)phenyl)vinyl)benzooxazole, 2-(2-(4-chlorophenyl)vinyl)naptho(1,2-d)oxazole, 2,2'-(p-penylenedivinylene)-bisbenzothiazole, 2-(2-(4-(2-benzoimidazolyl)phenyl)vinyl)benzoimidazole, 2-(2-(4-carboxyphenyl)vinyl)benzoimidazole, tris(8-quinolinol)aluminum, bis(8-quinolinol)magnesium, bis(benzo(f)-8-quinolinol)zinc, bis(2-methyl-8-quinolinolate)aluminumoxide, tris(8-quinolinol)indium, tris(5-methyl-8-quinolinol)aluminum, 8-quinolinol lithium, tris(5-chloro-8-quinolinol)gallium, bis(5-chloro-8-quinolinol)calcium, poly(zinc(II)-bis(8-hydroxy-5-quinolinolyl)methane), dilithiumepindridion, distyryl benzene compounds and a polycyclic condensation aromatic compound comprising a condensed ring luminous substance comprising anthracene, naphthalene, phenanthrene, pyrene, chrysene and a perylene skeleton.

Claim 10

5-bis(5,7-di-t-pentyl-2-benzooaxazolyl)-1,3,4-thiadiazole, 4,4'-bis(5,7-t-pentyl-2-benzooxazolyl)stilbene, 4,4'-bis(5,7-di-(2-methyl-2-butyl)-2-benzooxazolyl)stilbene, 2,5-bis(5,7-di-t-pentyl-2-benzooxazolyl)thiophene, 2,5-bis(5-(α,α-dimethylbenzyl)-2-benzooxazolyl)thiophene, 2,5-bis(5,7-di-(2-methyl-2-butyl)-2-benzooxazolyl)-3,4-diphenylthiophene, 2,5-bis(5-methyl-2-benzooxazolyl)thiophene, 4,4'-bis(2-benzooxazolyl)biphenyl, 5-methyl-2-(2-(4-(5-methyl-2-benzooxazolyl)phenyl)vinyl)benzooxazole, 2-(2-(4-chlorophenyl)vinyl)naptho(1,2-d)oxazole, 2,2'-(p-penylenedivinylene)-bisbenzothiazole, 2-(2-(4-(2-benzoimidazolyl)phenyl)vinyl)benzoimidazole, 2-(2-(4-carboxyphenyl)vinyl)benzoimidazole, tris(8-quinolinol)aluminum, bis(8-quinolinol)magnesium, bis(benzo(f)-8-quinolinol)zinc, bis(2-methyl-8-quinolinolate)aluminumoxide, tris(8-quinolinol)indium, tris(5-methyl-8-quinolinol)aluminum, 8-quinolinol lithium, tris(5-chloro-8-quinolinol)gallium, bis(5-chloro-8-quinolinol)calcium, poly(zinc(II)-bis(8-hydroxy-5-quinolinolyl)methane), dilithiumepindridion, distyryl benzene compounds and a polycyclic condensation aromatic compound comprising a condensed ring luminous substance comprising anthracene, naphthalene, phenanthrene, pyrene, chrysene and a perylene skeleton.

Claim 11

The organic electroluminescence device according to claim 7, wherein the organic insulator zone comprises an electron barrier area comprising a compound of the formula ##STR24## wherein X is at least one of the following (I), (II) and (III) in any of the following combinations of (I), (II) and (III): --(I)--(II)--(I)--, --(II)--(II)--(I)--, 13 (III)--(I)--(II)--, --(III)--(II)--(II)-- and --(III)--(III)--(III)--, ##STR25## Y and Y' are --N═ or --CR'═, Z is --O--, --S-- or --NR'--, R' is a hydrogen atom, an alkyl group or an aryl group, R 1 and R 2 are independently at least one of a hydrogen atom, Ar, an alkyl group and a cyclohexyl group, and Ar is at least one of a phenyl group and a naphthyl group.

Claim 12

The organic electroluminescence device according to claim 7, wherein the organic insulator zone comprises an electron barrier area comprising a compound selected from the group consisting of ##STR26## wherein t-Bu is a tert-butyl group.

Claim 13

The organic electroluminescence device according to claim 7, wherein the organic insulator zone comprises a hole barrier area comprising an organic compound having an absolute ionization energy of at least 5.9 eV and having the formula ##STR27## wherein Q is at least one of --(A)--, --(B)--, --(C)--, --(A)--(B)--, --(A)--(C)--, --(A)--(D)--(A)--, --(A)--(D)--, --(B)--(C)--, --(C)--(D)--, --(D)--(D)-- and --(D)--(C)--(A)--, wherein ##STR28##

Claim 14

The organic electroluminescence device according to claim 10, wherein the hole barrier area comprises an organic compound selected from the group consisting of ##STR29## wherein t-Bu is a tert-butyl group.

Claim 15

The organic electroluminescence device according to claim 2, wherein the organic semiconductor zone comprises a compound selected from the group consisting of α-sexithiophene, 5,5'-bis-2-(5-cyclohexyl)thienyl bithiophene and 4,4'-bis(5-(2,2-dithienyl))biphenyl; the electron barrier area comprises a compound selected from the group consisting of ##STR30## and the organic light emitting area comprises a compound selected from the group consisting of ##STR31## wherein t-Bu is a tert-butyl group.

Claim 16

The organic electroluminescence device according to claim 1, wherein the electroconducting oligomer is selected from the group consisting of ##STR32##