← Back to Patent Explorer
US5159009A Expired / Lapsed US ⏱️ 0.0 years remaining

Carbon blacks modified with organosilicon compounds, method of their production and their use in rubber mixtures

Assignee: Evonik Operations GmbH
•
Filing: 1991-06-17
•
Granted: 1992-10-27
•
Expires: 2011-06-17
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract Carbon black is reacted with at least one organosilicon compound of the General Formula [R.sup.1.sub.n (RO).sub.3-n Si-(Alk).sub.m -(Ar).sub.p ]q [B](I) R.sup.1.sub.n (RO).sub.3-n Si-(Alkyl) (II) or R.sup.1.sub.n (RO).sub.3-n Si-(Alkenyl) (III), and any excess of said organosilicon compound is extracted with a solvent. The products are useful as active fillers in rubber mixtures, carbon black suspensions and plastic mixtures which can be cross-linked with sulfur or peroxide.

Inventors

  • 👤 Siegfried Wolff
  • 👤 Udo Gorl

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 06:34
CPC Classifications
C; C08; C08K; C08K9/00; C08K9/04; C08K9/06; C09; C09C; C09C1/00; C09C1/44; C09C1/48; C09C1/56; C09C3/00; C09C3/12; C01; C01P; C01P2006/00; C01P2006/12

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 206 words
Carbon blacks which are chemically modified with at least one organosilicon compound selected from the group consisting of [R.sup.1.sub.n (RO).sub.3-n Si-(Alk).sub.m -(Ar).sub.p ]q [B](I) R.sup.1.sub.n (RO).sub.3-n Si-(Alkyl) (II) R.sup.1.sub.n (RO).sub.3-n Si-(Alkenyl) (III) in which B represents --SCN, --SH, --Cl, --NH 2 (if q=1) or --Sx--(if q=2), R and R 1 , which may be the same or different, represent an alkyl group containing 1 to 4 carbon atoms or the phenyl group, q represents 1 or 2, n represents 0, 1 or 2, Alk represents a bivalent straight or branched hydrocarbon group containing 1 to 6 carbon atoms, m represents 0 or 1, Ar represents an arylene group containing 6 to 12 carbon atoms, p represents 0 or 1 provided that p and n do not simultaneously signify 0, x represents a number from 2 to 8, Alkyl represents a monovalent straight or branched unsaturated hydrocarbon group containing 1 to 20 carbon atoms, alkenyl represents a monovalent straight or branched unsaturated hydrocarbon group containing 2 to 20 carbon atoms, and on the surface of which blacks 0.1 to 15 % by weight of one or more of the named organosilicon compounds are bonded in such a manner that they can not be extracted with organic solvents.
Claim 2
Dependent Claim 206 words
Carbon blacks which are chemically modified with at least one organosilicon compound selected from the group consisting of [R.sup.1.sub.n (RO).sub.3-n Si-(Alk).sub.m -(Ar).sub.p ]q [B](I) R.sup.1.sub.n (RO).sub.3-n Si-(Alkyl) (II) R.sup.1.sub.n (RO).sub.3-n Si-(Alkenyl) (III) in which B represents --SCN, --SH, --Cl, --NH 2 (if q=1) or --Sx--(if q=2), R and R 1 , which may be the same or different, represent an alkyl group containing 1 to 4 carbon atoms or the phenyl group, q represents 1 or 2, n represents 0, 1 or 2, Alk represents a bivalent straight or branched hydrocarbon group containing 1 to 6 carbon atoms, m represents 0 or 1, Ar represents an arylene group containing 6 to 12 carbon atoms, p represents 0 or 1 provided that p and n do not simultaneously signify 0, x represents a number from 2 to 8, Alkyl represents a monovalent straight or branched unsaturated hydrocarbon group containing 1 to 20 carbon atoms, alkenyl represents a monovalent straight or branched unsaturated hydrocarbon group containing 2 to 20 carbon atoms, and on the surface of which blacks 0.1 to 15 % by weight of one or more of the named organosilicon compounds are bonded in such a manner that they can not be extracted with organic solvents.
Claim 3
Dependent Claim 20 words
Modified carbon blacks as set forth in claim 1 which exist in powder form, pellet form or as a granulate.
Claim 4
Dependent Claim 71 words
A method of producing the modified carbon blacks set forth in claim 1 or claim 2 which comprises forming a homogeneous mixture of at least one said organosilicon compound and the carbon black, then subsequently reacting said at least one organosilicon compound for 1 to 60 min. at 50° to 160° C. and then extracting any of said at least one organosilicon compound which is not reacted with an organic solvent.
Claim 5
Dependent Claim 18 words
A method according to claim 3 including pelletizing powdered modified carbon black or converting it into a granulate.
Claim 6
Dependent Claim 25 words
A method as set forth in claim 3 in which all of said organosilicon compound is reacted with said carbon black and none is extracted.
Claim 7
Dependent Claim 22 words
A vulcanizable rubber mixture comprising a vulcanizable rubber and a modified carbon black as set forth in claim 1 or claim 2.
Claim 8
Dependent Claim 27 words
Carbon blacks according to claim 1, wherein Ae contains 6 carbon atoms, Alkyl contains 2 to 8 carbon atoms and alkenyl contains 2 to 8 carbon atoms.

References Cited (Backward Citations)

US3227675A Cited
US4128438A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1995-10-27 1996-04-27 1996-10-27 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1999-10-27 2000-04-27 2000-10-27 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2003-10-27 2004-04-27 2004-10-27 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag