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US5159009A
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Carbon blacks modified with organosilicon compounds, method of their production and their use in rubber mixtures
Assignee: Evonik Operations GmbH
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Filing: 1991-06-17
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Granted: 1992-10-27
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Expires: 2011-06-17
Abstract
Abstract Carbon black is reacted with at least one organosilicon compound of the General Formula [R.sup.1.sub.n (RO).sub.3-n Si-(Alk).sub.m -(Ar).sub.p ]q [B](I) R.sup.1.sub.n (RO).sub.3-n Si-(Alkyl) (II) or R.sup.1.sub.n (RO).sub.3-n Si-(Alkenyl) (III), and any excess of said organosilicon compound is extracted with a solvent. The products are useful as active fillers in rubber mixtures, carbon black suspensions and plastic mixtures which can be cross-linked with sulfur or peroxide.
Inventors
- 👤 Siegfried Wolff
- 👤 Udo Gorl
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-08 21:59
CPC Classifications
C; C08; C08K; C08K9/00; C08K9/04; C08K9/06; C09; C09C; C09C1/00; C09C1/44; C09C1/48; C09C1/56; C09C3/00; C09C3/12; C01; C01P; C01P2006/00; C01P2006/12
Claims Analysis
Total Claims: 8
Claim 1
Independent Claim
206 words
Carbon blacks which are chemically modified with at least one organosilicon compound selected from the group consisting of [R.sup.1.sub.n (RO).sub.3-n Si-(Alk).sub.m -(Ar).sub.p ]q [B](I) R.sup.1.sub.n (RO).sub.3-n Si-(Alkyl) (II) R.sup.1.sub.n (RO).sub.3-n Si-(Alkenyl) (III) in which B represents --SCN, --SH, --Cl, --NH 2 (if q=1) or --Sx--(if q=2), R and R 1 , which may be the same or different, represent an alkyl group containing 1 to 4 carbon atoms or the phenyl group, q represents 1 or 2, n represents 0, 1 or 2, Alk represents a bivalent straight or branched hydrocarbon group containing 1 to 6 carbon atoms, m represents 0 or 1, Ar represents an arylene group containing 6 to 12 carbon atoms, p represents 0 or 1 provided that p and n do not simultaneously signify 0, x represents a number from 2 to 8, Alkyl represents a monovalent straight or branched unsaturated hydrocarbon group containing 1 to 20 carbon atoms, alkenyl represents a monovalent straight or branched unsaturated hydrocarbon group containing 2 to 20 carbon atoms, and on the surface of which blacks 0.1 to 15 % by weight of one or more of the named organosilicon compounds are bonded in such a manner that they can not be extracted with organic solvents.
Claim 2
Dependent Claim
206 words
Carbon blacks which are chemically modified with at least one organosilicon compound selected from the group consisting of [R.sup.1.sub.n (RO).sub.3-n Si-(Alk).sub.m -(Ar).sub.p ]q [B](I) R.sup.1.sub.n (RO).sub.3-n Si-(Alkyl) (II) R.sup.1.sub.n (RO).sub.3-n Si-(Alkenyl) (III) in which B represents --SCN, --SH, --Cl, --NH 2 (if q=1) or --Sx--(if q=2), R and R 1 , which may be the same or different, represent an alkyl group containing 1 to 4 carbon atoms or the phenyl group, q represents 1 or 2, n represents 0, 1 or 2, Alk represents a bivalent straight or branched hydrocarbon group containing 1 to 6 carbon atoms, m represents 0 or 1, Ar represents an arylene group containing 6 to 12 carbon atoms, p represents 0 or 1 provided that p and n do not simultaneously signify 0, x represents a number from 2 to 8, Alkyl represents a monovalent straight or branched unsaturated hydrocarbon group containing 1 to 20 carbon atoms, alkenyl represents a monovalent straight or branched unsaturated hydrocarbon group containing 2 to 20 carbon atoms, and on the surface of which blacks 0.1 to 15 % by weight of one or more of the named organosilicon compounds are bonded in such a manner that they can not be extracted with organic solvents.
Claim 3
Dependent Claim
20 words
Modified carbon blacks as set forth in claim 1 which exist in powder form, pellet form or as a granulate.
Claim 4
Dependent Claim
71 words
A method of producing the modified carbon blacks set forth in claim 1 or claim 2 which comprises forming a homogeneous mixture of at least one said organosilicon compound and the carbon black, then subsequently reacting said at least one organosilicon compound for 1 to 60 min. at 50° to 160° C. and then extracting any of said at least one organosilicon compound which is not reacted with an organic solvent.
Claim 5
Dependent Claim
18 words
A method according to claim 3 including pelletizing powdered modified carbon black or converting it into a granulate.
Claim 6
Dependent Claim
25 words
A method as set forth in claim 3 in which all of said organosilicon compound is reacted with said carbon black and none is extracted.
Claim 7
Dependent Claim
22 words
A vulcanizable rubber mixture comprising a vulcanizable rubber and a modified carbon black as set forth in claim 1 or claim 2.
Claim 8
Dependent Claim
27 words
Carbon blacks according to claim 1, wherein Ae contains 6 carbon atoms, Alkyl contains 2 to 8 carbon atoms and alkenyl contains 2 to 8 carbon atoms.
References Cited (Backward Citations)
US3227675A
Cited
US4128438A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1995-10-27 | 1996-04-27 | 1996-10-27 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1999-10-27 | 2000-04-27 | 2000-10-27 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2003-10-27 | 2004-04-27 | 2004-10-27 | $7700.00 | Window Closed / Lapsed |