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Patent US5244599A successfully refreshed from Google Patents.
US5244599A
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Defoamer compositions
Assignee: Shin-Etsu Chemical Co Ltd
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Filing: 1990-11-16
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Granted: 1993-09-14
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Expires: 2010-11-16
Abstract
Abstract A defoamer composition comprising (A) an organopolysiloxane containing an oxyalkylene group having an appropriate hydrophilic-hydrophobic balance, (B) another organopolysiloxane containing an oxyalkylene group serving as a surface active agent for component (C), (C) a dimethylpolysiloxane for retaining defoaming power, and (D) a silica filler can maintain defoaming power for a long time, for example, when it is added to a developer for exposed photosensitive resin which is subject to shearing stresses in the wash-out step.
Inventors
- 👤 Nobuyuki Terae
- 👤 Tadashi Domae
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 16:40
CPC Classifications
B; B01; B01D; B01D19/00; B01D19/02; B01D19/04; B01D19/0404; B01D19/0409
Claims Analysis
Total Claims: 9
Claim 1
Independent Claim
308 words
A defoamer composition comprising (A) 5 to 50 parts by weight of an organopolysiloxane containing an oxyalkylene group having formula (1): ##STR13## wherein Y is a monovalent hydrocarbon group having 6 to 30 carbon atoms or an alkoxy group having 6 to 30 carbon atoms, G is an oxyalkylene group of the formula: --R--O--(C.sub.2 H.sub.4 O).sub.d (C.sub.3 H.sub.6 O).sub.e --A wherein R is a divalent hydrocarbon group having 2 to 6 carbon atoms, A is a group selected from the class consisting of a hydrogen atom, an acetyl group, an alkyl group having 1 to 8 carbon atoms, and an isocyanate group, d=6 to 60, e=2 to 60, d+e=8 to 75, and e/(d+e)=0.2 to 0.8, said oxyalkylene group having an average molecular weight of 500 to 5,000, a and b are independently equal to 0, 1 or 2, c is equal to 1, 2 or 3, a+b+c=3, l is an integer of from 10 to 200, m is a number such that m+2a is equal to 1 to 50, n is a number such that n+2b is equal to 1 to 30, and (n+2b)/l=0.01 to l, (B) 100 parts by weight of an organopolysiloxane containing an oxyalkylene group having formula (2): ##STR14## wherein G' is an oxyalkylene group of the formula: --R--O--(C.sub.2 H.sub.4 O).sub.h (C.sub.3 H.sub.6 O).sub.i --A wherein R and A are as defined above, h=6 to 60, i=2 to 60, h+i=8 to 75, and i/(h+i)=0.2 to 0.8, said oxyalkylene group having an average molecular weight of 500 to 5,000, f is equal to 1, 2 or 3, g is equal to 0, 1 or 2, f+g=3, p and q are independently integers of at least 1, and (q+2g)/p=0.02 to 1, (C) 20 to 200 parts by weight of a dimethylpolysiloxane having a viscosity of 100 to 1,000,000 centistokes at 25° C. and (D) a silica filler.
Claim 2
Dependent Claim
308 words
A defoamer composition comprising (A) 5 to 50 parts by weight of an organopolysiloxane containing an oxyalkylene group having formula (1): ##STR13## wherein Y is a monovalent hydrocarbon group having 6 to 30 carbon atoms or an alkoxy group having 6 to 30 carbon atoms, G is an oxyalkylene group of the formula: --R--O--(C.sub.2 H.sub.4 O).sub.d (C.sub.3 H.sub.6 O).sub.e --A wherein R is a divalent hydrocarbon group having 2 to 6 carbon atoms, A is a group selected from the class consisting of a hydrogen atom, an acetyl group, an alkyl group having 1 to 8 carbon atoms, and an isocyanate group, d=6 to 60, e=2 to 60, d+e=8 to 75, and e/(d+e)=0.2 to 0.8, said oxyalkylene group having an average molecular weight of 500 to 5,000, a and b are independently equal to 0, 1 or 2, c is equal to 1, 2 or 3, a+b+c=3, l is an integer of from 10 to 200, m is a number such that m+2a is equal to 1 to 50, n is a number such that n+2b is equal to 1 to 30, and (n+2b)/l=0.01 to l, (B) 100 parts by weight of an organopolysiloxane containing an oxyalkylene group having formula (2): ##STR14## wherein G' is an oxyalkylene group of the formula: --R--O--(C.sub.2 H.sub.4 O).sub.h (C.sub.3 H.sub.6 O).sub.i --A wherein R and A are as defined above, h=6 to 60, i=2 to 60, h+i=8 to 75, and i/(h+i)=0.2 to 0.8, said oxyalkylene group having an average molecular weight of 500 to 5,000, f is equal to 1, 2 or 3, g is equal to 0, 1 or 2, f+g=3, p and q are independently integers of at least 1, and (q+2g)/p=0.02 to 1, (C) 20 to 200 parts by weight of a dimethylpolysiloxane having a viscosity of 100 to 1,000,000 centistokes at 25° C. and (D) a silica filler.
Claim 3
Dependent Claim
17 words
The composition of claim 1, which comprises 0.1 to 30 parts by weight of silica filler (D).
Claim 4
Dependent Claim
49 words
The composition of claim 1, wherein formula (1): Y has 8 to 20 carbon atoms; d=10 to 30, e=4 to 30, d+e=15 to 60; m+2a is equal to 2 to 30, n is a number such that n+2b is equal to 2 to 20 n and (n+2b)/l=0.05 to 0.4.
Claim 5
Dependent Claim
22 words
The composition of claim 1, wherein in formula (2): h is 10 to 30, i is=4 to 30 and h+i=15 to 60.
Claim 6
Dependent Claim
29 words
The composition of claim 1, which contains 1-20 parts of a silica filler having a specific surface area of 50 to 500 m 2 /g as measured by BET.
Claim 7
Dependent Claim
40 words
The composition of claim 3, wherein in formula (2): h=10 to 30, i=4 to 30 and h+i=15 to 60; and wherein the silica filler has a specific surface area of 50 to 500 m 2 /g as measured by BET.
Claim 8
Dependent Claim
92 words
The composition of claim 1, wherein component (A) is a compound of one of the formulae ##STR15## wherein G 1 : --(CH 2 ) 3 --O--(C 2 H 4 O) 25 (C 3 H 6 O) 25 --C 4 H 9 and Y 1 : --C 14 H 29 ; ##STR16## wherein G 2 :--(CH 2 ) 3 --O--(C 2 H 4 O) 6 --(C 3 H 6 O) 24 --H and Y 2 : ##STR17## and; ##STR18## wherein G 3 : ##STR19## and Y 3 : --OC 16 H 33 .
Claim 9
Dependent Claim
64 words
The composition of claim 1, wherein component (B) is a compound of one of the formulae ##STR20## wherein G 1 : --(CH 2 ) 3 --O--(C 2 H 4 O) 25 --(C 2 H 4 O) 25 --C 4 H 9 and ##STR21## wherein G 2 : --(CH 2 ) 3 --O--(C 2 H 4 O) 6 --(C 3 H 6 O) 24 --H.
References Cited (Backward Citations)
US3233986A
Cited
US4076648A
Cited
US4395352A
Cited
JPS56129013A
Cited
US4514319A
Cited
US4597894A
Cited
US4690713A
Cited
JPS60173068A
Cited
US5004559A
Cited
US4912157A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
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| 3.5 Years (Year 4) | 1996-09-13 | 1997-03-15 | 1997-09-14 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2000-09-13 | 2001-03-15 | 2001-09-14 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2004-09-13 | 2005-03-15 | 2005-09-14 | $7700.00 | Window Closed / Lapsed |