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US5286552A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for the production of propylene polymer films and laminates and products thus obtained

Assignee: Himont Inc
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Filing: 1991-02-25
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Granted: 1994-02-15
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Expires: 2011-02-25
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Abstract

Abstract Disclosed are films and laminates which are prepared by known filming or calendering processes using heterophasic propylene polymer compositions comprising: A) 10-60 parts by weight of homopolymer polypropylene having an isotactic index greater than 90, or crystalline copolymer of propylene with ethylene and/or other alphaolefins containing more than 85% by weight of propylene and having an isotactic index greater than 85; B) 10-40 parts by weight of a semi-crystalline essentially linear copolymer containing prevailingly ethylene, which is insoluble in xylene at room temperature; C) 30-60 parts by weight of an amorphous ethylene-propylene copolymer, soluble in xylene at room temperature and containing 40-70% by weight of ethylene; said propylene polymer compositions having a ratio between the intrinsic viscosities, in tetrahydronaphthalene at 135° C., of the portion soluble in xylene and of the portion insoluble in xylene at room temperature of from 0.8 to 1.2.

Inventors

  • 👤 Giuseppe Lesca
  • 👤 Vincenzo Giannella
  • 👤 Serafino Ongari
  • 👤 Annibale Vezzoli

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 11:04
CPC Classifications
B; B32; B32B; B32B27/00; B32B27/06; B32B27/08; B32B27/32; C; C08; C08F; C08F297/00; C08F297/06; C08F297/08; C08F297/083; C08F297/086; B32B2323/00; B32B2323/10

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 188 words
A process for the production of a propylene polymer film comprising forming a film from a heterophasic propylene polymer composition obtained by sequential polymerization in at least two stages wherein components (B) and (C) are polymerized in the presence of component (A) polymerized in the first stage comprising: (A) 10-60 parts by weight of homopolymer polypropylene having an isotactic index greater than 90, or of a crystalline copolymer of propylene with ethylene, other alpha-olefins or combinations thereof, containing more than 85% by weight of propylene and having an isotactic index greater than 85; (B) 10-40 parts by weight of a semi-crystalline, essentially linear ethylene-propylene copolymer containing prevailingly ethylene, which is insoluble in xylene at room temperature; (C) 30-60 parts by weight of an amorphous ethylene-propylene copolymer, which is soluble in xylene at room temperature and contains 40-70% by weight of ethylene; said propylene polymer composition having a ratio between the intrinsic viscosities, in tetrahydronaphthalene at 135° C., of the portion soluble in xylene and of the portion insoluble in xylene at room temperature of from 0.8 to 1.2, and containing great than 40% by weight of component (C).
Claim 2
Dependent Claim 188 words
A process for the production of a propylene polymer film comprising forming a film from a heterophasic propylene polymer composition obtained by sequential polymerization in at least two stages wherein components (B) and (C) are polymerized in the presence of component (A) polymerized in the first stage comprising: (A) 10-60 parts by weight of homopolymer polypropylene having an isotactic index greater than 90, or of a crystalline copolymer of propylene with ethylene, other alpha-olefins or combinations thereof, containing more than 85% by weight of propylene and having an isotactic index greater than 85; (B) 10-40 parts by weight of a semi-crystalline, essentially linear ethylene-propylene copolymer containing prevailingly ethylene, which is insoluble in xylene at room temperature; (C) 30-60 parts by weight of an amorphous ethylene-propylene copolymer, which is soluble in xylene at room temperature and contains 40-70% by weight of ethylene; said propylene polymer composition having a ratio between the intrinsic viscosities, in tetrahydronaphthalene at 135° C., of the portion soluble in xylene and of the portion insoluble in xylene at room temperature of from 0.8 to 1.2, and containing great than 40% by weight of component (C).
Claim 3
Dependent Claim 19 words
The process of to claim 1, wherein component (A) is a crystalline copolymer of propylene with butene or 4-methyl-1-pentene.
Claim 4
Dependent Claim 15 words
The process of claim 1, wherein component (C) further contains minor amounts of a diene.
Claim 5
Dependent Claim 185 words
A thermoweldable film, having high elastomeric properties comprising a heterophasic propylene polymer composition obtained by sequential polymerization in at least two stages wherein components (B) and (C) are polymerized in the presence of component (A) polymerized in the first stage which is comprised of: (A) 10-60 parts by weight of homopolymer polypropylene having an isotactic index greater than 90, or of a crystalline copolymer of propylene with ethylene, other alpha-olefins or combinations thereof, containing more than 85% by weight of propylene and having an isotactic index greater than 85; (B) 10-40 parts by weight of a semi-crystalline, essentially linear ethylene-propylene copolymer containing prevailingly ethylene, which is insoluble in xylene at room temperature; (C) 30-60 parts by weight of an amorphous ethylene-propylene copolymer, which is soluble in xylene at room temperature and contains 40-70% by weight of ethylene; wherein said propylene polymer composition having a ratio between the intrinsic viscosities, in tetrahydronaphthalene at 135° C., of the portion soluble in xylene and of the portion insoluble in xylene at room temperature of from 0.8 to 1.2, and containing greater than 40% by weight of component (C).
Claim 6
Dependent Claim 185 words
A thermoweldable film, having high elastomeric properties comprising a heterophasic propylene polymer composition obtained by sequential polymerization in at least two stages wherein components (B) and (C) are polymerized in the presence of component (A) polymerized in the first stage which is comprised of: (A) 10-60 parts by weight of homopolymer polypropylene having an isotactic index greater than 90, or of a crystalline copolymer of propylene with ethylene, other alpha-olefins or combinations thereof, containing more than 85% by weight of propylene and having an isotactic index greater than 85; (B) 10-40 parts by weight of a semi-crystalline, essentially linear ethylene-propylene copolymer containing prevailingly ethylene, which is insoluble in xylene at room temperature; (C) 30-60 parts by weight of an amorphous ethylene-propylene copolymer, which is soluble in xylene at room temperature and contains 40-70% by weight of ethylene; wherein said propylene polymer composition having a ratio between the intrinsic viscosities, in tetrahydronaphthalene at 135° C., of the portion soluble in xylene and of the portion insoluble in xylene at room temperature of from 0.8 to 1.2, and containing greater than 40% by weight of component (C).
Claim 7
Dependent Claim 18 words
The film of claim 4, wherein component (A) is a crystalline copolymer of propylene with butene or 4-methyl-1-pentene.
Claim 8
Dependent Claim 15 words
The film of claim 4, wherein component (C) further contains minor amounts of a diene.
Claim 9
Dependent Claim 12 words
The film of claim 4, having a thickness smaller than 100 μm.

References Cited (Backward Citations)

EP0077532A2 Cited
EP0086300A1 Cited
EP0145368A2 Cited
EP0170255A1 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1997-02-14 1997-08-16 1998-02-15 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2001-02-14 2001-08-16 2002-02-15 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2005-02-14 2005-08-16 2006-02-15 $7700.00 Window Closed / Lapsed

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