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US5310828A Expired / Lapsed US ⏱️ 0.0 years remaining

Superior stain resistant compositions

Assignee: Peach State Labs Inc
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Filing: 1991-10-28
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Granted: 1994-05-10
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Expires: 2011-10-28
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Abstract

Abstract Novel polymeric compositions are provided for polyamide fibers or fibers having terminal amino groups that impart stain resistance and are resistant to discoloration.

Inventors

  • 👤 Michael S. Williams
  • 👤 Thomas H. Moss, III

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 02:11
CPC Classifications
D; D06; D06M; D06M15/00; D06M15/19; D06M15/21; D06M15/263; C; C08; C08F; C08F290/00; C08F290/08; C08F290/14; C08F299/00; D06M15/37; D06M15/39; D06M15/41; D06M15/412; D06M15/564; D06M2101/00; D06M2101/16; D06M2101/30; D06M2101/34; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31942; Y10T442/00; Y10T442/20; Y10T442/2279; Y10T442/2861; Y10T442/2893; Y10T442/2902

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 144 words
An aromatic polymeric stain resistant composition wherein at least some of the aromatic moieties in the polymer are sulfonated and at least some of the aromatic moieties in the polymer contain free hydroxyl groups, prepared by: (i) allowing a hydroxyaromatic compound to react with a compound selected from the group consisting of an unsaturated carboxylic acid, unsaturated carboxylic acid anhydride, unsaturated carboxylic acid chloride, unsaturated carboxylic acid precursor, saturated carboxylic acid, saturated carboxylic acid anhydride, saturated carboxylic acid chloride, saturated carboxylic acid precursor, saturated isocyanate and an unsaturated isocyanate; (ii) homopolymerizing or copolymerizing the ester formed in step (i) with an aldehyde in an aldehyde condensation reaction to form an aromatic condensation polymer; and then (iii) allowing the product of step (ii) to react with an acrylic acid, or α-substituted acrylic acid, or a mixture thereof in the presence of a free radical agent.
Claim 2
Dependent Claim 144 words
An aromatic polymeric stain resistant composition wherein at least some of the aromatic moieties in the polymer are sulfonated and at least some of the aromatic moieties in the polymer contain free hydroxyl groups, prepared by: (i) allowing a hydroxyaromatic compound to react with a compound selected from the group consisting of an unsaturated carboxylic acid, unsaturated carboxylic acid anhydride, unsaturated carboxylic acid chloride, unsaturated carboxylic acid precursor, saturated carboxylic acid, saturated carboxylic acid anhydride, saturated carboxylic acid chloride, saturated carboxylic acid precursor, saturated isocyanate and an unsaturated isocyanate; (ii) homopolymerizing or copolymerizing the ester formed in step (i) with an aldehyde in an aldehyde condensation reaction to form an aromatic condensation polymer; and then (iii) allowing the product of step (ii) to react with an acrylic acid, or α-substituted acrylic acid, or a mixture thereof in the presence of a free radical agent.
Claim 3
Dependent Claim 39 words
The stain resistant composition of claim 1, wherein a ratio by weight of solids of approximately 1 part by weight sulfated hydroxyaromatic compound to between 0.5 and 2.5 parts acid, anhydride, or acid chloride is used in step (i).
Claim 4
Dependent Claim 35 words
The stain resistant composition of claim 1, wherein a ratio of approximately 1 part by weight of hydroxyaromatic compound to between 0.5 and 2 parts by weight of an aldehyde is used in step (ii).
Claim 5
Dependent Claim 41 words
The stain resistant composition of claim 1, wherein a ratio of 1 part by weight of condensation polymer to between 1 and 30 parts by weight of acrylic acid, α-substituted acrylic acid, or a mixture thereof, is used in step (iii).
Claim 6
Dependent Claim 39 words
The stain resistant composition of claim 1, wherein a ratio of 1 part of condensation polymer to between 1 and 5 parts by weight of acrylic acid, α-substituted acrylic acid, or a mixture thereof, is used in step (iii).
Claim 7
Dependent Claim 13 words
The stain resistant composition of claim 1, wherein the hydroxyaromatic is dihydroxydiphenyl sulfone.
Claim 8
Dependent Claim 17 words
The stain resistant composition of claim 1, wherein the hydroxyaromatic is allowed to react with acetic anhydride.
Claim 9
Dependent Claim 15 words
The stain resistant composition of claim 1, wherein the α-substituted acrylic acid is methacrylic acid.
Claim 10
Dependent Claim 17 words
The stain resistant composition of claim 1, wherein mixtures of hydroxyaromatic compounds are reacted with the aldehyde.
Claim 11
Dependent Claim 21 words
The stain resistant composition of claim 1, wherein an aromatic compound without hydroxyl groups is included in the aldehyde condensation reaction.
Claim 12
Dependent Claim 17 words
The stain resistant composition of claim 1, wherein the hydroxyaromatic is reacted with a saturated carboxylic acid.
Claim 13
Dependent Claim 17 words
The stain resistant composition of claim 1, wherein the hydroxyaromatic is reacted with an unsaturated carboxylic acid.
Claim 14
Dependent Claim 18 words
The stain resistant composition of claim 1, wherein mixtures of α-substituted acrylic acids are used in step (iii).
Claim 15
Dependent Claim 22 words
The stain resistant composition of claim 1, wherein acrylic acid is used in combination with an α-substituted acrylic acids in step (iii).

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1997-05-09 1997-11-08 1998-05-10 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2001-05-09 2001-11-08 2002-05-10 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2005-05-09 2005-11-08 2006-05-10 $7700.00 Window Closed / Lapsed

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