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US5569619A Expired / Lapsed US ⏱️ 0.0 years remaining

Method for forming a capacitor of a semiconductor memory cell

Assignee: SK Hynix Inc
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Filing: 1995-02-28
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Granted: 1996-10-29
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Expires: 2015-02-28
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Abstract

Abstract A method for forming a capacitor of a memory cell is disclosed. Steps of the present invention may include: forming a first conductive layer on a substrate; forming a tantalum oxide layer on the first conductive layer; forming a silicon nitride layer on the tantalum oxide layer; carrying out a titanium ion implantation into the tantalum oxide layer; carrying out a heat treatment, which may form a silicon oxide layer between the first conductive layer and the tantalum oxide layer, and which may include titanium oxide in the tantalum oxide layer, and which may change the silicon nitride to an oxynitride layer; and forming a second conductive layer on the oxynitride layer. During the titanium ion implantation process, Ti(OCH 3 ) 4 may be used as a titanium ion source. The titanium ion implantation process may be carried out using the Si 3 N 4 layer as a buffer layer, and with an energy of about 5 KeV-15 KeV, and a dosage of about 10 13 -10 16 .

Inventors

  • 👤 Jae-sung Roh

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 05:51
CPC Classifications
H; H10; H10D; H10D1/00; H10D1/60; H10D1/68

Claims Analysis

Total Claims: 18
Claim 1
Independent Claim 112 words
A method of making a capacitor in a semiconductor device comprising the steps of: (a) forming a first conductive layer on a substrate; (b) forming a tantalum oxide layer on the first conductive layer; (c) forming a silicon nitride layer on the tantalum oxide layer; (d) implanting titanium ions into the tantalum oxide layer; (e) carrying out a heat treatment, wherein a silicon oxide layer is formed between the first conductive layer and the tantalum oxide layer, wherein an oxide of titanium is formed in the tantalum oxide layer, and wherein the silicon nitride is converted to comprise an oxynitride layer; and (f) forming a second conductive layer on the oxynitride layer.
Claim 2
Independent Claim 112 words
A method of making a capacitor in a semiconductor device comprising the steps of: (a) forming a first conductive layer on a substrate; (b) forming a tantalum oxide layer on the first conductive layer; (c) forming a silicon nitride layer on the tantalum oxide layer; (d) implanting titanium ions into the tantalum oxide layer; (e) carrying out a heat treatment, wherein a silicon oxide layer is formed between the first conductive layer and the tantalum oxide layer, wherein an oxide of titanium is formed in the tantalum oxide layer, and wherein the silicon nitride is converted to comprise an oxynitride layer; and (f) forming a second conductive layer on the oxynitride layer.
Claim 3
Dependent Claim 24 words
The method of claim 1, wherein the titanium ion implantation is carried out using Ti (OCH 3 ) 4 as a titanium ion source.
Claim 4
Dependent Claim 46 words
The method of claim 1, wherein the titanium ion implantation is carried out using the silicon nitride layer as a buffer layer, and the implantation is carried out with an energy of about 5 KeV and at a dosage of about 10 13 -10 16 .
Claim 5
Dependent Claim 27 words
The method of claim 1, wherein the heat treatment is carried out in an oxygen atmosphere at a temperature of about 700°-900° C. for about 10-30 minutes.
Claim 6
Dependent Claim 19 words
The method of claim 1, wherein the silicon nitride layer is deposited to a thickness of about 10-30 Å.
Claim 7
Dependent Claim 15 words
The method of claim 1, wherein the first and second conductive layers comprise doped polysilicon.
Claim 8
Independent Claim 102 words
A method of forming a capacitor in a semiconductor device comprising the steps of: (a) forming a first conductive layer on a substrate; (b) forming a tantalum oxide layer on the first conductive layer; (c) forming a silicon oxide layer on the tantalum oxide layer; (d) introducing titanium ions into the tantalum oxide layer using the silicon nitride layer as a buffer layer; (e) forming a silicon oxide layer between the first conductive layer and the tantalum oxide layer wherein the silicon nitride layer is converted to comprise an oxinitride layer; and (f) forming a second conductive layer on the oxynitride layer.
Claim 9
Independent Claim 102 words
A method of forming a capacitor in a semiconductor device comprising the steps of: (a) forming a first conductive layer on a substrate; (b) forming a tantalum oxide layer on the first conductive layer; (c) forming a silicon oxide layer on the tantalum oxide layer; (d) introducing titanium ions into the tantalum oxide layer using the silicon nitride layer as a buffer layer; (e) forming a silicon oxide layer between the first conductive layer and the tantalum oxide layer wherein the silicon nitride layer is converted to comprise an oxinitride layer; and (f) forming a second conductive layer on the oxynitride layer.
Claim 10
Dependent Claim 20 words
The method of claim 7, further comprising the step of forming an oxide of titanium in the tantalum oxide layer.
Claim 11
Dependent Claim 53 words
The method of claim 7, wherein the step of forming a silicon oxide layer between the first conductive layer and the tantalum oxide layer comprises a heat treatment, and wherein an oxide of titanium is formed in the tantalum oxide layer, and wherein the silicon nitride is converted to comprise an oxynitride layer.
Claim 12
Dependent Claim 16 words
The method of claim 7, wherein the step of introducing titanium ions comprises an ion implantation.
Claim 13
Dependent Claim 28 words
The method of claim 7, wherein the step of introducing titanium ions comprises an ion, implantation carried out using Ti(OCH 3 ) 4 as a titanium ion source.
Claim 14
Dependent Claim 50 words
The method of claim 7, wherein the step of introducing titanium ions comprises an ion implantation carried out using the silicon nitride layer as a buffer layer, and the implantation is carried out with an energy of about 5 KeV, at a dosage of about 10 13 -10 16 .
Claim 15
Dependent Claim 27 words
The method of claim 9, wherein the heat treatment is carried out in an oxygen atmosphere at a temperature of about 700°-900° C. for about 10-30 minutes.
Claim 16
Dependent Claim 19 words
The method of claim 7, wherein the silicon nitride layer is deposited to a thickness of about 10-30 Å.
Claim 17
Dependent Claim 15 words
The method of claim 7, wherein the first and second conductive layers comprise doped polysilicon.
Claim 18
Dependent Claim 17 words
The method of claim 1, wherein the oxynitride layer comprises SiON and Si 3 N 4 .

References Cited (Backward Citations)

US4495219A Cited
US4734340A Cited
US5079191A Cited
US4891684A Cited
US5202280A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1999-10-29 2000-04-29 2000-10-29 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2003-10-29 2004-04-29 2004-10-29 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2007-10-29 2008-04-29 2008-10-29 $7700.00 Window Closed / Lapsed

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