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US5674752A Expired / Lapsed US ⏱️ 0.0 years remaining

Conductive polymer coated fabrics for chemical sensing

Assignee: NAVY DEPARTMENT OF United States,
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Filing: 1995-10-16
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Granted: 1997-10-07
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Expires: 2015-10-16
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Abstract

Abstract A fabric chemical sensor, a process and an apparatus is disclosed. The sensor, process and apparatus are for the detection, classification, identification and/or quantitation of one or more component chemicals of a chemical vapor via a resistance measurment made across sensor in response to exposure of the sensor to the chemical vapor.

Inventors

  • 👤 Leonard J. Buckley
  • 👤 Greg Collins

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 17:06
CPC Classifications
G; G01; G01N; G01N27/00; G01N27/02; G01N27/04; G01N27/12; G01N27/125; G01N27/126; G01N33/00; G01N33/0004; G01N33/0009; G01N33/0027; G01N33/0031; G01N33/0036; G01N33/0047; Y; Y10; Y10S; Y10S436/00; Y10S436/902

Claims Analysis

Total Claims: 24
Claim 1
Independent Claim 170 words
A process for the detection of one or more component chemicals of a chemical vapor, said process comprising the steps of: (i) electrically connecting one or more fabric chemical sensors to a power source, said one or more fabric chemical sensors comprising one or more sensor elements, said sensor elements woven into a fabric of insulating fibers, said fibers being coated with one or more conductive polymers, each of said fabric chemical sensors having a baseline resistance; (ii) exposing at time=t 0 over said one or more fabric chemical sensors a chemical vapor, said chemical vapor comprising one or more component chemicals; (iii) detecting and quantifying a change in said baseline resistance of said one or more fabric chemical sensors at a later time=t 1 in response to exposure of said one or more fabric chemical sensors to said chemical vapor; and (iv) resolving and classifying from said change in said baseline resistance the identity of at least one of said one or more component chemicals of said chemical vapor.
Claim 2
Dependent Claim 170 words
A process for the detection of one or more component chemicals of a chemical vapor, said process comprising the steps of: (i) electrically connecting one or more fabric chemical sensors to a power source, said one or more fabric chemical sensors comprising one or more sensor elements, said sensor elements woven into a fabric of insulating fibers, said fibers being coated with one or more conductive polymers, each of said fabric chemical sensors having a baseline resistance; (ii) exposing at time=t 0 over said one or more fabric chemical sensors a chemical vapor, said chemical vapor comprising one or more component chemicals; (iii) detecting and quantifying a change in said baseline resistance of said one or more fabric chemical sensors at a later time=t 1 in response to exposure of said one or more fabric chemical sensors to said chemical vapor; and (iv) resolving and classifying from said change in said baseline resistance the identity of at least one of said one or more component chemicals of said chemical vapor.
Claim 3
Dependent Claim 47 words
The process of claim 1 wherein said power source is a direct current battery, wherein said insulating fiber is selected from the group consisting of PET, nylon and mixtures thereof, and wherein said conductive polymer is selected from the group consisting of poly(pyrrole), poly(aniline) and mixtures thereof.
Claim 4
Dependent Claim 29 words
The process of claim 1 wherein said detecting and quantifying is accomplished using an electrometer and wherein said resolving and classifying is accomplished using a means for data acquisition.
Claim 5
Dependent Claim 16 words
The process of claim 3 wherein said means for data acquisition is a data acquisition algorithm.
Claim 6
Dependent Claim 19 words
The process of claim 1 wherein said one or more conductive polymers are doped with one or more dopants.
Claim 7
Dependent Claim 27 words
The process of claim 5 wherein said one or more dopants are selected from the group consisting of PTSA, NDSA, N2SA, AQSA, chloride ion and mixtures thereof.
Claim 8
Dependent Claim 20 words
The process of claim 5 wherein said one or more conductive polymers are coated with one or more bilayer polymers.
Claim 9
Dependent Claim 26 words
The process of claim 7 wherein said one or more bilayer polymers are selected from the group consisting of PEI, PIB, SXFA, FPOL and mixtures thereof.
Claim 10
Independent Claim 181 words
An apparatus for the detection of one or more component chemicals of a chemical vapor, said apparatus comprising: (i) one or more fabric chemical sensors comprising one or more sensor elements, said one or more sensor elements being woven into a fabric of insulating fibers, said fibers being coated with one or more conductive polymers; (ii) a power supply being electrically connected to said one or more fabric chemical sensors, said one or more fabric chemical sensors having a measurable baseline resistance; (iii) a means for exposing a chemical vapor over said one or more fabric chemical sensors sufficient to measure a reproducible change in said baseline resistance, said chemical vapor further comprising one or more component chemicals; (iv) a means for detecting and quantifying said change in said baseline resistance in response to said exposure of said one or more fabric chemical sensors to said chemical vapor; and (v) a means for resolving from said change in said baseline resistance a classification of the identity of at least one of said one or more component chemicals of said chemical vapor.
Claim 11
Independent Claim 181 words
An apparatus for the detection of one or more component chemicals of a chemical vapor, said apparatus comprising: (i) one or more fabric chemical sensors comprising one or more sensor elements, said one or more sensor elements being woven into a fabric of insulating fibers, said fibers being coated with one or more conductive polymers; (ii) a power supply being electrically connected to said one or more fabric chemical sensors, said one or more fabric chemical sensors having a measurable baseline resistance; (iii) a means for exposing a chemical vapor over said one or more fabric chemical sensors sufficient to measure a reproducible change in said baseline resistance, said chemical vapor further comprising one or more component chemicals; (iv) a means for detecting and quantifying said change in said baseline resistance in response to said exposure of said one or more fabric chemical sensors to said chemical vapor; and (v) a means for resolving from said change in said baseline resistance a classification of the identity of at least one of said one or more component chemicals of said chemical vapor.
Claim 12
Dependent Claim 19 words
The apparatus of claim 9 wherein said one or more conductive polymers are doped with one or more dopants.
Claim 13
Dependent Claim 27 words
The apparatus of claim 10 wherein said one or more dopants are selected from the group consisting of PTSA, NDSA, N2SA, AQSA, chloride ion and mixtures thereof.
Claim 14
Dependent Claim 20 words
The apparatus of claim 10 wherein said one or more conductive polymers are coated with one or more bilayer polymers.
Claim 15
Dependent Claim 26 words
The apparatus of claim 12 wherein said one or more bilayer polymers are selected from the group consisting of PEI, PIB, SXFA, FPOL and mixtures thereof.
Claim 16
Dependent Claim 21 words
The apparatus of claim 9 wherein said insulating fibers are selected from the group consisting of PET, nylon and mixtures thereof.
Claim 17
Dependent Claim 21 words
The apparatus of claim 14 wherein said conductive polymers are selected from the group consisting of poly(pyrrole), poly(aniline) and mixtures thereof.
Claim 18
Dependent Claim 14 words
The apparatus of claim 15 wherein said power supply is a direct current battery.
Claim 19
Dependent Claim 21 words
The apparatus of claim 16 wherein said means for exposing is one or more fabric chemical sensors exposed to ambient atmosphere.
Claim 20
Dependent Claim 15 words
The apparatus of claim 17 wherein said means for detecting and quantifying is an electrometer.
Claim 21
Dependent Claim 15 words
The apparatus of claim 18 wherein said means for resolving is an artificial neural network.
Claim 22
Dependent Claim 15 words
The apparatus of claim 18 wherein said means for resolving is a pattern selectivity algorithm.
Claim 23
Dependent Claim 16 words
The apparatus of claim 18 wherein said means for resolving is a means for data acquisition.
Claim 24
Dependent Claim 16 words
The apparatus of claim 21 wherein said means for data acquisition is a data acquisition algorithm.

References Cited (Backward Citations)

US4794365A Cited
US5060527A Cited
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US5528155A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 2000-10-06 2001-04-07 2001-10-07 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2004-10-06 2005-04-07 2005-10-07 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2008-10-06 2009-04-07 2009-10-07 $7700.00 Window Closed / Lapsed

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