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US5808256A
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Method of controlling a photoreaction with a laser beam
Assignee: RIKEN
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Filing: 1997-01-22
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Granted: 1998-09-15
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Expires: 2017-01-22
Abstract
Abstract A target is irradiated with a laser beam having an energy of hν/n, where n is an integer, instead of the photon energy hν required for a reaction to proceed using a conventional single-photon excitation method. A desired reaction is selectively induced by the absorption of multiple photons instead of single photons. It is thus possible to induce a photoreaction in which an absorption is carried out in accordance with a selection theory different from that of single-photon absorption, and which is quite different from a photoreaction induced by a single-photon excitation. Namely, a target or reactant is irradiated with a photon energy hν 2 having a wavelength integral times longer than that of the photon energy hν 1 necessary for a photoreaction to proceed. Photon energy hν 2 is either used in place of the photon energy hν 1 necessary for a photoreaction, or together with the photon energy hν 1 , to thereby make the reactant absorb the energy equal to the photon energy hν 1 . The method is capable of selectively and preferentially inducing a specific photoreaction among various possible, concurrent photoreactions.
Inventors
- 👤 Mitsuo Kira
- 👤 Shinya Koshihara
- 👤 Takashi Miyazawa
- 👤 Yusaburo Segawa
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-02 17:38
CPC Classifications
G; G11; G11C; G11C13/00; G11C13/04; B; B01; B01J; B01J19/00; B01J19/08; B01J19/12; B01J19/121; C; C07; C07C; C07C5/00; C07C5/22; C07F; C07F7/00; C07F7/02; C07F7/08; C07F7/0803; C07F7/0825; C07F7/0827; C07F7/18; C07F7/1804; C07F7/1872; C07F7/188; G11B; G11B7/00; G11B7/004; G11B7/0045; G11B7/00455
Claims Analysis
Total Claims: 18
Claim 1
Independent Claim
78 words
A method of controlling a desired photoreaction, comprising the steps of: irradiating a target with a laser beam having a photon energy hν 1 /n, wherein n is 2 or greater, and hν 1 is an energy necessary to excite the target to a higher electronic state to make the desired reaction proceed to thereby induce an electronic state by multiple photon excitation by the simultaneous absorption of two or more photons, and selectively inducing the desired reaction.
Claim 2
Independent Claim
78 words
A method of controlling a desired photoreaction, comprising the steps of: irradiating a target with a laser beam having a photon energy hν 1 /n, wherein n is 2 or greater, and hν 1 is an energy necessary to excite the target to a higher electronic state to make the desired reaction proceed to thereby induce an electronic state by multiple photon excitation by the simultaneous absorption of two or more photons, and selectively inducing the desired reaction.
Claim 3
Independent Claim
87 words
A method of controlling a desired photoreaction comprising the steps of concurrently irradiating a target with a first laser beam having a photon energy hν 1 necessary to excite the target to a higher electronic state for a desired photoreaction to proceed, and a second laser beam having photon energy hν 1 /n, wherein n is an integer 2 or greater to thereby induce an excited electronic state by multiple photon excitation by the simultaneous absorption of one or more photons, and selectively inducing the desired reaction.
Claim 4
Independent Claim
87 words
A method of controlling a desired photoreaction comprising the steps of concurrently irradiating a target with a first laser beam having a photon energy hν 1 necessary to excite the target to a higher electronic state for a desired photoreaction to proceed, and a second laser beam having photon energy hν 1 /n, wherein n is an integer 2 or greater to thereby induce an excited electronic state by multiple photon excitation by the simultaneous absorption of one or more photons, and selectively inducing the desired reaction.
Claim 5
Dependent Claim
53 words
The method as recited in claim 1, wherein said photon energy hν 1 is that generated by a Nd:YAG laser which emits coherent light having a wavelength of 266 nm, and said photon energy hν 1 /n is that generated by a Nd:YAG laser which emits light having a wavelength of 532 nm.
Claim 6
Dependent Claim
53 words
The method as recited in claim 2, wherein said photon energy hν 1 is that generated by a Nd:YAG laser which emits coherent light having a wavelength of 266 nm, and said photon energy hν 1 /n is that generated by a Nd:YAG laser which emits light having a wavelength of 532 nm.
Claim 7
Dependent Claim
12 words
The method as recited in claim 1, wherein said target is 2,2-diphenyl-1,1,1,3,3,3-hexamethyltrisilane.
Claim 8
Dependent Claim
12 words
The method as recited in claim 1, wherein said target is cis-stilbene.
Claim 9
Dependent Claim
12 words
The method as recited in claim 1, wherein said target is trans-stilbene.
Claim 10
Dependent Claim
12 words
The method as recited in claim 2, wherein said target is 2,2-diphenyl-1,1,1,3,3,3-hexamethyltrisilane.
Claim 11
Dependent Claim
12 words
The method as recited in claim 2, wherein said target is cis-stilbene.
Claim 12
Dependent Claim
12 words
The method as recited in claim 2, wherein said target is trans-stilbene.
Claim 13
Dependent Claim
10 words
A method according to claim 1, wherein n is 2.
Claim 14
Dependent Claim
10 words
A method according to claim 1, wherein n is 3.
Claim 15
Dependent Claim
10 words
A method according to claim 1, wherein n is 4.
Claim 16
Dependent Claim
10 words
A method according to claim 1, wherein n is 2.
Claim 17
Dependent Claim
10 words
A method according to claim 1, wherein n is 3.
Claim 18
Dependent Claim
10 words
A method according to claim 1, wherein n is 4.
References Cited (Backward Citations)
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