Patent US4533640A successfully refreshed from Google Patents.
US4533640A
Expired / Lapsed
US
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Accumulated thermal exposure responder and method of use
Assignee: CONTROLLED CHEMICALS Inc A MI CORP
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Filing: 1984-02-21
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Granted: 1985-08-06
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Expires: 2004-02-21
Abstract
Abstract An adjustable accumulated thermal exposure indicator device, and method of use, for affixing to and indicating deterioration of perishable goods and the like, comprising (1) a reactant yielding material that reacts via one or more steps at a rate depending on time, temperature, and pH to provide an amine and (2) an indicator that reacts at a time, temperature, concentration and pH dependent rate with the amine to produce a visible reaction that is indicative of the expiration of a predetermined time-temperature history related to the useful life of the goods to which the device is affixed. Also provided is a device or article that is responsive to accumulated thermal exposure for the controlled release of immobilized alcohols and amines.
Inventors
- 👤 Jules A. Shafer
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 14:12
CPC Classifications
G; G01; G01N; G01N31/00; G01N31/22; G01N31/229; G01K; G01K3/00; G01K3/02; G01K3/04
Claims Analysis
Total Claims: 14
Claim 1
Independent Claim
107 words
A device for monitoring accumulated thermal exposure and for affixing to perishable goods having a given shelf-life and for signaling the expiration of the given self-life by producing a visible indicator reaction after a predetermined accumulated thermal exposure corresponding to the given shelf-life comprising a sealed container and reagents in said container, wherein the reagents in said container are viewable and include (1) a reactant yielding reagent that is capable of producing an amine reactant during thermal exposure and (2) an indicator yielding reagent that, during thermal exposure, is capable of reacting with the amine to produce a visible indicator reaction after a predetermined accumulated thermal exposure.
Claim 2
Independent Claim
107 words
A device for monitoring accumulated thermal exposure and for affixing to perishable goods having a given shelf-life and for signaling the expiration of the given self-life by producing a visible indicator reaction after a predetermined accumulated thermal exposure corresponding to the given shelf-life comprising a sealed container and reagents in said container, wherein the reagents in said container are viewable and include (1) a reactant yielding reagent that is capable of producing an amine reactant during thermal exposure and (2) an indicator yielding reagent that, during thermal exposure, is capable of reacting with the amine to produce a visible indicator reaction after a predetermined accumulated thermal exposure.
Claim 3
Dependent Claim
13 words
A device according to claim 1 where the reactant yielding reagent comprises N-2'-carboxyphenylphthalimide.
Claim 4
Dependent Claim
14 words
A device according to claim 1 where the reactant yielding reagent comprises N-2'-carboxyphenylphthalamic acid.
Claim 5
Dependent Claim
18 words
A device according to claim 1 where the reactant yielding reagent comprises a substituted or unsubstituted cyclic imide.
Claim 6
Dependent Claim
27 words
A device according to claim 1 where the indicator yielding reagent comprises 2-chloro-3,5-dinitrobenzoic acid and is capable of reacting with the amine to produce a yellow color.
Claim 7
Dependent Claim
33 words
A device according to claim 1 where the indicator yielding reagent comprises an ionic metal or a metal containing compound that is capable of forming an insoluble visible precipitate complex with the amine.
Claim 8
Dependent Claim
43 words
A device according to claim 1 where the reactant yielding reagent comprises an N-2'-carboxyphenylphthalamic acid ester of formula ##STR9## where R is a benzyl, menthyl or alkyl group and wherein the reactant yielding reagent also controllably releases an alcohol having a formula ROH.
Claim 9
Dependent Claim
22 words
A device according to claim 1 where the reagents are included in an aqueous reaction medium at controlled pH and reagent concentration.
Claim 10
Dependent Claim
56 words
A device according to claim 1 wherein the container comprises a non-frangible common container and a separate frangible container located and visible within the common container, wherein the reagents are kept separate within respective containers prior to activating the device by mixing the reagents and wherein the device can be activated by breaking the frangible container.
Claim 11
Dependent Claim
116 words
A device according to claim 1 wherein the container includes; a first closure for sealing the container and having opposed faces with one face open to the container and the other closure face having a recess with a bottom, and wherein the bottom of said recess defines a membrane, and a second closure having puncture means and insertable in the recess in two positions, one position for telescopically matching and sealing engagement with the recess, and the second position wherein the puncture means is advanced telescopically in the recess and in piercing relation through the membrane so that liquid contents in the container can be mixed with liquid contents in the recess of the first closure.
Claim 12
Dependent Claim
50 words
A method of indicating an accumulated thermal exposure of a device according to claim 1 comprising the steps of subjecting the reactant yielding reagent to said exposure to produce the amine reactant and further reacting the amine reactant thus produced with the indicator yielding reagent to produce a visible reaction.
Claim 13
Dependent Claim
75 words
A process of monitoring accumulated thermal exposure of perishable goods having a given shelf-life, employing a device according to claim 1, comprising the steps of selecting the device for its indicator reaction corresponding to the given shelf-life, affixing the selected device to said perishable goods, activating the device by mixing the reagents in the container contemporaneously with the step of affixing the device to said perishable goods and monitoring the device for its indicator reaction.
Claim 14
Dependent Claim
29 words
A process according to claim 12 where the device produces a visible yellow color reaction after a predetermined accumulated thermal exposure corresponding to the shelf-life of the perishable goods.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1988-08-05 | 1989-02-04 | 1989-08-06 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1992-08-05 | 1993-02-04 | 1993-08-06 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1996-08-05 | 1997-02-04 | 1997-08-06 | $7700.00 | Window Closed / Lapsed |