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Patent US4655890A successfully refreshed from Google Patents.
US4655890A
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Laser isotope separation by multiple photon absorption
Assignee: United States Department of Energy
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Filing: 1985-02-08
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Granted: 1987-04-07
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Expires: 2005-02-08
Abstract
Abstract Multiple photon absorption from an intense beam of infrared laser light may be used to induce selective chemical reactions in molecular species which result in isotope separation or enrichment. The molecular species must have a sufficient density of vibrational states in its vibrational manifold that, is the presence of sufficiently intense infrared laser light tuned to selectively excite only those molecules containing a particular isotope, multiple photon absorption can occur. By this technique, for example, intense CO2 laser light may be used to highly enrich 34S in natural SF6 and 11B in natural BCl3.
Inventors
- 👤 C. Paul Robinson
- 👤 Stephen D. Rockwood
- 👤 Reed J. Jensen
- 👤 John L. Lyman
- 👤 Jack P. Aldridge, III
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-03 23:46
CPC Classifications
B; B01; B01D; B01D59/00; B01D59/34
Claims Analysis
Total Claims: 6
Claim 1
Independent Claim
246 words
A method for separating isotopes of an element, said method comprising the steps of: a. irradiating a mixture of molecules containing the element, and a scavenger species of fewer than five times the number of said molecules containing the element, with a first infrared laser radiation having a first wavelength which lies in close coincidence with the transition from the ground rotation-vibrational level of those of said molecules which contain the isotopic variant of the element which is to be separated and the next highest rotation-vibration level having vibrational excitation, said first infrared laser radiation having an intensity sufficient to selectively induce multiple photon absorption of said first wavelength laser radiation by those of said molecules which contain the isotopic variant of the element which is to be separated; b. simultaneously irradiating said molecules containing the element with a second infrared laser radiation having a second wavelength chosen to selectively excite said molecules which have selectively absorbed said first electromagnetic radiation by the absorption of at least one photon of said second wavelength laser radiation, whereby said molecules which have selectively absorbed said first wavelength laser radiation are excited to sufficiently high rotation-vibration levels of the ground electronic state such that said selectively excited molecules undergo chemical reaction while molecules containing other isotopic variants of the element remain substantially in their lower rotation-vibration levels and consequently substantially unreactive; and c. separating the product of said chemical reaction of said selectively excited molecules from said unreacted molecules.
Claim 2
Independent Claim
246 words
A method for separating isotopes of an element, said method comprising the steps of: a. irradiating a mixture of molecules containing the element, and a scavenger species of fewer than five times the number of said molecules containing the element, with a first infrared laser radiation having a first wavelength which lies in close coincidence with the transition from the ground rotation-vibrational level of those of said molecules which contain the isotopic variant of the element which is to be separated and the next highest rotation-vibration level having vibrational excitation, said first infrared laser radiation having an intensity sufficient to selectively induce multiple photon absorption of said first wavelength laser radiation by those of said molecules which contain the isotopic variant of the element which is to be separated; b. simultaneously irradiating said molecules containing the element with a second infrared laser radiation having a second wavelength chosen to selectively excite said molecules which have selectively absorbed said first electromagnetic radiation by the absorption of at least one photon of said second wavelength laser radiation, whereby said molecules which have selectively absorbed said first wavelength laser radiation are excited to sufficiently high rotation-vibration levels of the ground electronic state such that said selectively excited molecules undergo chemical reaction while molecules containing other isotopic variants of the element remain substantially in their lower rotation-vibration levels and consequently substantially unreactive; and c. separating the product of said chemical reaction of said selectively excited molecules from said unreacted molecules.
Claim 3
Dependent Claim
13 words
The method as described in claim 1, wherein said chemical reaction include photodissociation.
Claim 4
Dependent Claim
22 words
The method as described in claim 1, wherein said chemical reaction includes reaction of said vibrationally excited molecules with said scavenger species.
Claim 5
Dependent Claim
35 words
The method as described in claim 2, wherein the products of said photodissociation are reacted with said scavenger species before said step of separation of said products of said chemical reaction from said unreacted molecules.
Claim 6
Dependent Claim
46 words
The method as described in claim 4, wherein said molecules containing the element for which isotope separation is to be performed are in the gaseous state and wherein said molecules containing the element for which isotope separation is to be performed have at least four atoms.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1990-04-06 | 1990-10-06 | 1991-04-07 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1994-04-06 | 1994-10-06 | 1995-04-07 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1998-04-06 | 1998-10-06 | 1999-04-07 | $7700.00 | Window Closed / Lapsed |