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Method of reducing the degradation of the red phosphor, Y203:EU, in water base lamp suspensions

Assignee: Osram Sylvania Inc
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Filing: 1990-12-21
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Granted: 1992-06-30
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Expires: 2010-12-21
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Abstract

Abstract A method has been found which reduces substantially the degradation of the red phosphor, Y 2 O 3 :Eu, in water base fluorescent lamp suspension, thereby prolonging the shelf life of triphosphor suspensions. The method of the invention comprises forming a protective coating around individual particles of europium-doped yttrium oxide phosphor to inhibit degradation of europium-doped yttrium oxide phosphor in a water base phosphor coating suspension, the protective coating comprising an inorganic material and being of sufficient thickness to prevent the europium-doped yttrium oxide phosphor from reacting with the coating suspension. A preferred coating material is gamma-alumina.

Inventors

  • 👤 Arunava Dutta
  • 👤 Ernest A. Dale
  • 👤 Leonard V. Dullea

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 12:25
CPC Classifications
C; C09; C09K; C09K11/00; C09K11/02; C09K11/025; C09K11/08; C09K11/77; C09K11/7783; C09K11/7784; C09K11/7787; H; H01; H01J; H01J61/00; H01J61/02; H01J61/38; H01J61/42; H01J61/46

Claims Analysis

Total Claims: 4
Claim 1
Independent Claim 99 words
A method of reducing the degradation of Y 2 O 3 :Eu phosphor in water base fluorescent lamp coating suspensions comprising: forming a protective coating around individual particles of europium-doped yttrium oxide phosphor to inhibit degradation of europium-doped yttrium oxide phosphor in a water base phosphor coating suspension, the protective coating comprising silicon oxynitride of sufficient thickness to prevent the europium-doped yttrium oxide phosphor from reacting with said water base phosphor coating suspension, said silicon oxynitride protective coating having a solubility in water of less than 0.0001 grams/cc at 25° C. at pH from about 6 to about 10.
Claim 2
Independent Claim 99 words
A method of reducing the degradation of Y 2 O 3 :Eu phosphor in water base fluorescent lamp coating suspensions comprising: forming a protective coating around individual particles of europium-doped yttrium oxide phosphor to inhibit degradation of europium-doped yttrium oxide phosphor in a water base phosphor coating suspension, the protective coating comprising silicon oxynitride of sufficient thickness to prevent the europium-doped yttrium oxide phosphor from reacting with said water base phosphor coating suspension, said silicon oxynitride protective coating having a solubility in water of less than 0.0001 grams/cc at 25° C. at pH from about 6 to about 10.
Claim 3
Independent Claim 87 words
A method of reducing the degradation of Y 2 O 3 :Eu phosphor in water base fluorescent lamp coating suspensions comprising: forming a protective coating around individual particles of europium-doped yttrium oxide phosphor to inhibit degradation of europium-doped yttrium oxide phosphor in a water base phosphor coating suspension, the protective coating comprising silicon oxynitride of sufficient thickness to prevent the europium-doped yttrium oxide suspension wherein said silicon oxynitride protective coating has a lower aqueous solubility than yttrium hydroxide over a range of pH from 6 to 10.
Claim 4
Independent Claim 87 words
A method of reducing the degradation of Y 2 O 3 :Eu phosphor in water base fluorescent lamp coating suspensions comprising: forming a protective coating around individual particles of europium-doped yttrium oxide phosphor to inhibit degradation of europium-doped yttrium oxide phosphor in a water base phosphor coating suspension, the protective coating comprising silicon oxynitride of sufficient thickness to prevent the europium-doped yttrium oxide suspension wherein said silicon oxynitride protective coating has a lower aqueous solubility than yttrium hydroxide over a range of pH from 6 to 10.

References Cited (Backward Citations)

US4287229A Cited
US4585673A Cited
US4952422A Cited
US4803400A Cited
US5049408A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1995-06-30 1995-12-30 1996-06-30 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1999-06-30 1999-12-30 2000-06-30 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2003-06-30 2003-12-30 2004-06-30 $7700.00 Window Closed / Lapsed

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