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US5264491A Expired / Lapsed US ⏱️ 0.0 years remaining

Compatibilization of polymer blends

Assignee: Edison Polymer Innovation Corp
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Filing: 1992-08-26
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Granted: 1993-11-23
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Expires: 2012-08-26
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Abstract

Abstract Compatibilizing agents suitable for blending otherwise immiscible polymers comprise a block or graft copolymer in which at least one of the block segments is formed by a living anionic polymerization and thereafter chemically converted to provide a polymer having at least one functional end group. The functional groups of the polymer blocks thus formed are reacted with a functionalized monomer, or an oligomer to provide a second block polymer segment. Compatibilizing agents containing more than two blocks may be formed in similar fashion. The compatibilizing agents are used to provide uniform blends of polar and non-polar polymers having superior uniformity and other physical properties.

Inventors

  • 👤 Roderic P. Quirk

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 06:03
CPC Classifications
C; C08; C08G; C08G63/00

Claims Analysis

Total Claims: 5
Claim 1
Independent Claim 81 words
A linear diblock compatibilizing agent for polymer blends whose block segments have an M n of about 21,000 to 30,000 comprising a copolymer selected from a member of the group of a polystyrene-block-aromatic polyester and a polyisoprene-block-aromatic polyester, said polystyrene and said polyisoprene being prepared by living anionic polymerization using an alkyllithium initiator, and said aromatic polyester being selected from a member of the group consisting of polyethylene isophthalate, polyethylene terephthalate, polybutylene isophthalate, polybutylene terephthalate, and copolymers formed between the preceding.
Claim 2
Dependent Claim 81 words
A linear diblock compatibilizing agent for polymer blends whose block segments have an M n of about 21,000 to 30,000 comprising a copolymer selected from a member of the group of a polystyrene-block-aromatic polyester and a polyisoprene-block-aromatic polyester, said polystyrene and said polyisoprene being prepared by living anionic polymerization using an alkyllithium initiator, and said aromatic polyester being selected from a member of the group consisting of polyethylene isophthalate, polyethylene terephthalate, polybutylene isophthalate, polybutylene terephthalate, and copolymers formed between the preceding.
Claim 3
Dependent Claim 144 words
A process for preparing a linear diblock compatibilizing agent for polymer blends whose block segments have an M n of about 21,000 to 30,000 comprising: (1) polymerizing a member selected from the group consisting of styrene and isoprene in a living anionic polymerization in the presence of an alkyllithium initiator to form a first polymer having a stable anionic chain end; (2) converting the anionic chain end into a functional end group by reacting said first polymer with an electrophilic compound (3) converting said functional end group into an active polymerization-initiating site; and (4) converting said first polymer into a linear diblock copolymer by using said site to initiate a condensation polymerization to produce a second polymer, said second polymer being an aromatic polyester selected from the group consisting of polyethylene isophthalate, polyethylene terephthalate, polybutylene isophthalate, polybutylene terephthalate, and copolymers formed between the preceding.
Claim 4
Dependent Claim 144 words
A process for preparing a linear diblock compatibilizing agent for polymer blends whose block segments have an M n of about 21,000 to 30,000 comprising: (1) polymerizing a member selected from the group consisting of styrene and isoprene in a living anionic polymerization in the presence of an alkyllithium initiator to form a first polymer having a stable anionic chain end; (2) converting the anionic chain end into a functional end group by reacting said first polymer with an electrophilic compound (3) converting said functional end group into an active polymerization-initiating site; and (4) converting said first polymer into a linear diblock copolymer by using said site to initiate a condensation polymerization to produce a second polymer, said second polymer being an aromatic polyester selected from the group consisting of polyethylene isophthalate, polyethylene terephthalate, polybutylene isophthalate, polybutylene terephthalate, and copolymers formed between the preceding.
Claim 5
Dependent Claim 44 words
A process according to claim 2 wherein said functional end groups are selected from a carboxy group, an amine group, a thiol group, a hydroxyl group, and a phenol group, and wherein said groups are converted into said active site in a subsequent reaction.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1996-11-22 1997-05-24 1997-11-23 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2000-11-22 2001-05-24 2001-11-23 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2004-11-22 2005-05-24 2005-11-23 $7700.00 Window Closed / Lapsed

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