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Selective combustible sensor and method

Assignee: Ford Global Technologies LLC
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Filing: 1993-03-18
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Granted: 1994-01-25
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Expires: 2013-03-18
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Abstract

Abstract A method of operating a selective combustible sensor having a pump cell and a sensor cell includes the steps of immersing the sensor in a gaseous atmosphere having at least two combustible gases and oxygen gas and allowing the gaseous atmosphere to enter a region between the pump cell and the sensor cell, applying a pumping current to the pump cell, sensing an e.m.f. (V s ), across the sensor cell, varying at least either the V s or temperature to make the sensor insensitive to one of the combustible gases, and detecting the other combustible gases present in the gaseous atmosphere.

Inventors

  • 👤 Jacobus H. Visser
  • 👤 Eleftherios M. Logothetis
  • 👤 Lajos Rimai
  • 👤 Richard E. Soltis

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 20:18
CPC Classifications
G; G01; G01N; G01N27/00; G01N27/26; G01N27/416; G01N27/417; G01N27/419

Claims Analysis

Total Claims: 20
Claim 1
Independent Claim 109 words
A method of operating a selective combustible sensor, the sensor having a pump cell and a sensor cell, said method comprising the steps of: immersing the sensor in a gaseous atmosphere having at least two combustible gases and oxygen gas and allowing the atmosphere to enter a region between the pump cell and the sensor cell; applying a pumping current to the pump cell; sensing an electromotive force (V s ) across the sensor cell; varying at least either the V s or temperature of the sensor to make the sensor insensitive to one of the combustible gases; and detecting the other combustible gases present in the gaseous atmosphere.
Claim 2
Independent Claim 109 words
A method of operating a selective combustible sensor, the sensor having a pump cell and a sensor cell, said method comprising the steps of: immersing the sensor in a gaseous atmosphere having at least two combustible gases and oxygen gas and allowing the atmosphere to enter a region between the pump cell and the sensor cell; applying a pumping current to the pump cell; sensing an electromotive force (V s ) across the sensor cell; varying at least either the V s or temperature of the sensor to make the sensor insensitive to one of the combustible gases; and detecting the other combustible gases present in the gaseous atmosphere.
Claim 3
Dependent Claim 44 words
A method as set forth in claim 1 including the step of determining a V s for a zero change in pumping current with respect to a pumping current when no combustible is present for each combustible gas prior to said step of varying.
Claim 4
Dependent Claim 30 words
A method as set forth in claim 2 wherein said step of determining comprises either one of calculating or calibrating the sensor for the zero change of each combustible gas.
Claim 5
Dependent Claim 41 words
A method as set forth in claim 1 wherein said step of varying comprises adjusting the pumping current such that the sensor cell has a V s that corresponds to a zero differential pumping current for one of the combustible gases.
Claim 6
Dependent Claim 41 words
A method as set forth in claim 1 wherein said step of varying comprises adjusting the temperature of the sensor such that the sensor has a temperature that corresponds to a zero differential pumping current for one of the combustible gases.
Claim 7
Dependent Claim 38 words
A method as set forth in claim 1 wherein said step of detecting comprises measuring a pumping current of the pump cell, and calculating the concentration of various combustible gases from the measured values of the pumping current.
Claim 8
Dependent Claim 35 words
A method as set forth in claim 6 wherein said step of calculating comprises calculating the concentration of the combustible gases according to the following formula: I.sub.p =4eB(D.sub.02 /(kT))[{1-exp(-4eV.sub.s /(kT))}C.sub.02 -nC.sub.comb {D.sub.comb /D.sub.02 -exp(-4eV.sub.s /(kT))}]P.sub.T
Claim 9
Independent Claim 105 words
A method of operating a selective combustible sensor, the sensor having a pump cell and a sensor cell, said method comprising the steps of: immersing the sensor in a gaseous atmosphere having at least two combustible gases and oxygen gas and allowing the atmosphere to enter a region between the pump cell and the sensor cell; applying a pumping current to the pump cell; sensing an electromotive force (V s ) across the sensor cell; establishing a predetermined V s ; measuring a pumping current of the pump cell; and calculating the concentration of the combustible gases from the measured values of the pumping current.
Claim 10
Independent Claim 105 words
A method of operating a selective combustible sensor, the sensor having a pump cell and a sensor cell, said method comprising the steps of: immersing the sensor in a gaseous atmosphere having at least two combustible gases and oxygen gas and allowing the atmosphere to enter a region between the pump cell and the sensor cell; applying a pumping current to the pump cell; sensing an electromotive force (V s ) across the sensor cell; establishing a predetermined V s ; measuring a pumping current of the pump cell; and calculating the concentration of the combustible gases from the measured values of the pumping current.
Claim 11
Dependent Claim 44 words
A method as set forth in claim 8 including the step of determining a V s for a zero change in pumping current with respect to a pumping current when no combustible is present for each combustible gas prior to said step of establishing.
Claim 12
Dependent Claim 30 words
A method as set forth in claim 9 wherein said step of determining comprises either one of calculating or calibrating the sensor for the zero change of each combustible gas.
Claim 13
Dependent Claim 42 words
A method as set forth in claim 8 wherein said step of establishing comprises adjusting the pumping current cell such that the sensor cell has a V s that corresponds to a zero differential pumping current for one of the combustible gases.
Claim 14
Dependent Claim 46 words
A method as set forth in claim 8 including the step of varying the temperature (T) of the sensor such that the sensor has a T that corresponds to a zero differential pumping current for one of the combustible gases prior to said step of measuring.
Claim 15
Dependent Claim 35 words
A method as set forth in claim 8 wherein said step of calculating comprises calculating the concentration of the combustible gases according to the following formula: I.sub.p =4eB(D.sub.02 /(kT))[{1-exp(-4eV.sub.s /(kT))}C.sub.02 -nC.sub.comb {D.sub.comb /D.sub.02 -exp(-4eV.sub.s /(kT))}]P.sub.T
Claim 16
Independent Claim 129 words
A method of operating a selective combustible sensor, the sensor having a pump cell and a sensor cell, said method comprising the steps of: immersing the sensor in a gaseous atmosphere having at least two combustible gases and oxygen gas and allowing the atmosphere to enter a region between the pump cell and the sensor cell; applying a pumping current to the pump cell; sensing an electromotive force (V s ) across the sensor cell; varying the pumping current and temperature (T) such that the sensor has a V s /T that corresponds to a zero differential pumping current for one of the combustible gases; measuring a pumping current of the pump cell; and calculating the concentration of the combustible gases from the measured values of the pumping current.
Claim 17
Independent Claim 129 words
A method of operating a selective combustible sensor, the sensor having a pump cell and a sensor cell, said method comprising the steps of: immersing the sensor in a gaseous atmosphere having at least two combustible gases and oxygen gas and allowing the atmosphere to enter a region between the pump cell and the sensor cell; applying a pumping current to the pump cell; sensing an electromotive force (V s ) across the sensor cell; varying the pumping current and temperature (T) such that the sensor has a V s /T that corresponds to a zero differential pumping current for one of the combustible gases; measuring a pumping current of the pump cell; and calculating the concentration of the combustible gases from the measured values of the pumping current.
Claim 18
Dependent Claim 44 words
A method as set forth in claim 14 including the step of determining a V s for a zero change in pumping current with respect to a pumping current when no combustible is present for each combustible gas prior to said step of varying.
Claim 19
Dependent Claim 30 words
A method as set forth in claim 15 wherein said step of determining comprises either one of calculating or calibrating the sensor for the zero change of each combustible gas.
Claim 20
Dependent Claim 35 words
A method as set forth in claim 14 wherein said step of calculating comprising calculating the concentration of the combustible gases according to the following formula: I.sub.p =4eB(D.sub.02 /(kT))[{1-exp(-4eV.sub.s /(kT))}C.sub.02 -nC.sub.comb {D.sub.comb /D.sub.02 -exp(-4eV.sub.s /(kT))}]P.sub.T

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1997-01-24 1997-07-26 1998-01-25 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2001-01-24 2001-07-26 2002-01-25 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2005-01-24 2005-07-26 2006-01-25 $7700.00 Window Closed / Lapsed

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