Fluoroalkyl-functional organopolysiloxane-containing compositions based on water, a process for their preparation and their use

Claim 1

A process for the preparation of an organopolysiloxane containing composition comprising: organopolysiloxanes of formula I: HO{Si (A) (CH.sub.3).sub.z (OH).sub.1-z O}.sub.a {Si(B) (R.sup.2).sub.y (OH) .sub.1-y O}.sub.b {Si(C)(CH.sub.3)O}.sub.c {Si(D)(OH)O}.sub.4 H·(HX).sub.c (I) wherein A is an aminoalkyl group of formula II: H.sub.2 N(CH.sub.2).sub.f (NH).sub.g (CH.sub.2).sub.h Si(OR).sub.3-z (CH.sub.3).sub.z (II), in which 0≧f≧6, g=0 if f=0 and g=1 if f>0, 0≦h≧6 and 0≦z≧1; B is a fluoroakyl group of formula III; R.sup.1 -Y-(CH.sub.2).sub.2 Si(R.sup.2).sub.y (OR).sub.3-y (III) wherein R 1 is a mono-, oligo- or perfluorinated alkyl group having 1-9 C atoms or a mono-, oligo- or perfluorinated aryl group. Y is a CH 2 , O or S group. R 2 is a linear, branched or cyclic alkyl group having 1-8 C atoms or an aryl group and 0≦y≦1: C is an alkyl group of formula IV: R.sup.3 --Si(CH.sub.3)(OR).sub.2 (IV), and D is an alkyl group of formula V: R.sup.3 --Si(OR).sub.3 (V) wherein R 3 in each case is identical or different and is a linear, branched or cyclic alkyl group having 1-8 C atoms, and R in each case is identical or different and is a linear, branched or cyclic alkyl group having 1-8 C atoms or an aryl group; and wherein HX is an acid, wherein X is an inorganic or organic acid radical, and 0≦y≦1, 0≦z≦1, a>0, b>0, c≧0, d≧0, e≧0 and (a+b+c+d)≧2, the composition being essentially free from organic solvents, having a flash point of more than 70° C. and liberating essentially no alcohols by hydrolysis on dilution with water; which comprises: mixing a, b, c and d mols of organopolysiloxanes of formulas I, III, IV and V, respectively, in a molar ratio of 0.1≦(a/(b+c+d)) where a>0, b>0, c≧0, d≧0 to form an organosilane mixture; mixing the organosilane mixture with at least one selected from the group consisting of water; a water/acid mixture, and a water/acid/alcohol mixture and a mixture thereof, the amount of acid being selected such that the reaction mixture has a pH in the range of 1-8; and removing the alcohol already present or formed during the reaction.

Claim 12

A method of simultaneously hydrophobizing and oleophobizing surfaces, metals, plastics and mineral building materials, comprising: treating surfaces, metals, plastics, and mineral building material with an aqueous organopolysiloxane-containing composition comprising: organopolysiloxanes of formula I: HO{Si(A)(CH.sub.3).sub.z (OH).sub.1-z O}.sub.a {Si(B)(R.sup.2).sub.y (OH).sub.1-y O}.sub.b {Si(C)(CH.sub.3)O}.sub.c {Si(D)(OH)O}.sub.d H.(HX).sub.e (I), wherein A is an aminoalkyl group of formula II: H.sub.2 N(CH.sub.2).sub.f (NH).sub.g (CH.sub.2).sub.h Si(OR).sub.3-2 (CH.sub.3).sub.z (II), in which 0≦f≦6, g=0 if f=0 and g=1 if f>0, 0≦h≦6 and 0≦z≦1; B is a fluoroalkyl group of formula III: R.sup.1 --Y--(CH.sub.2).sub.2 Si(R.sup.2).sub.y (OR).sub.3-y(III), wherein R 1 is a mono-, oligo- or perfluorinated alkyl group having 1-9 C atoms or a mono-, oligo- or perfluorinated aryl group, Y is a CH 2 , O or S group, R 2 is a linear, branched or cyclic alkyl group having 1-8 C atoms or an aryl group and 0≦y≦1; C is an alkyl group of formula IV: R.sup.3 --Si(CH.sub.3)(OR).sub.2 (IV), and D is an alkyl group of formula V R.sup.3 --Si(OR).sub.3 (V): wherein R 3 in each case is identical or different and is a linear, branched or cyclic alkyl group having 1-8 C atoms, and R in each case is identical or different and is a linear, branched or cyclic alkyl group having 1-8 C atoms or an aryl group; and wherein HX is an acid, wherein X is an inorganic or organic acid radical, and 0≦y≦1, 0≦z≦1, a>0, b>0, c≧0, d≧0, e≧0 and (a+b+c+d)≧2, the composition being essentially free from organic solvents, having a flash point of more than 70° C. and liberating essentially no alcohols by hydrolysis on dilution with water; which provides a dirt and color repellent effect.

Claim 13

A method of simultaneously hydrophobizing and oleophobizing surfaces, metals, plastics and mineral building materials, comprising: treating surfaces, metals, plastics, and mineral building material with an aqueous organopolysiloxane-containing composition comprising: organopolysiloxanes of formula I: HO{Si(A)(CH.sub.3).sub.z (OH).sub.1-z O}.sub.a {Si(B)(R.sup.2).sub.y (OH).sub.1-y O}.sub.b {Si(C)(CH.sub.3)O}.sub.c {Si(D)(OH)O}.sub.d H.(HX).sub.e (I), wherein A is an aminoalkyl group of formula II: H.sub.2 N(CH.sub.2).sub.f (NH).sub.g (CH.sub.2).sub.h Si(OR).sub.3-2 (CH.sub.3).sub.z (II), in which 0≦f≦6, g=0 if f=0 and g=1 if f>0, 0≦h≦6 and 0≦z≦1; B is a fluoroalkyl group of formula III: R.sup.1 --Y--(CH.sub.2).sub.2 Si(R.sup.2).sub.y (OR).sub.3-y(III), wherein R 1 is a mono-, oligo- or perfluorinated alkyl group having 1-9 C atoms or a mono-, oligo- or perfluorinated aryl group, Y is a CH 2 , O or S group, R 2 is a linear, branched or cyclic alkyl group having 1-8 C atoms or an aryl group and 0≦y≦1; C is an alkyl group of formula IV: R.sup.3 --Si(CH.sub.3)(OR).sub.2 (IV), and D is an alkyl group of formula V R.sup.3 --Si(OR).sub.3 (V): wherein R 3 in each case is identical or different and is a linear, branched or cyclic alkyl group having 1-8 C atoms, and R in each case is identical or different and is a linear, branched or cyclic alkyl group having 1-8 C atoms or an aryl group; and wherein HX is an acid, wherein X is an inorganic or organic acid radical, and 0≦y≦1, 0≦z≦1, a>0, b>0, c≧0, d≧0, e≧0 and (a+b+c+d)≧2, the composition being essentially free from organic solvents, having a flash point of more than 70° C. and liberating essentially no alcohols by hydrolysis on dilution with water; which provides a dirt and color repellent effect.

Claim 14

A method of protecting buildings and facades, comprising: treating buildings or facades with an aqueous organopolysiloxane-containing composition comprising: organopolysiloxanes of formula I HO{Si(A)(CH.sub.3).sub.z (OH).sub.1-z O}.sub.3 {Si(B)(R.sup.2).sub.y (OH).sub.1-y O}.sub.b {Si(C)(CH.sub.3)O}.sub.c {Si(D)(OH)O}.sub.d H.(HX).sub.c (I), wherein A is an aminoalkyl group of formula II; H.sub.2 N(CH.sub.2).sub.f (NH).sub.g (CH.sub.2).sub.h Si(OR).sub.3-z (CH.sub.3).sub.z (II), in which 0≦f≦6, g=0 if f=0 and g=1 if f>0, 0≦h≦6 and 0≦z≦1; B is a fluoroalkyl group of formula III: R.sup.1 --Y--(CH.sub.2).sub.2 Si(R.sup.2).sub.y (OR).sub.3-y(III), wherein R 1 is a mono- oligo- or perfluorinated alkyl group having 1-9 C atoms or a mono-, oligo- or perfluorinated aryl group, Y is a CH 2 , O or S group, R 2 is a linear, branched or cyclic alkyl group having 1-8 C atoms or an aryl group and 0≦y≦1; C is an alkyl group of formula IV: R.sup.3 --Si(CH.sub.3)(OR).sub.2 (IV), and D is an alkyl group of formula V: R.sup.3 --Si(OR).sub.3 (V) wherein R 3 in each case is identical or different and is a linear, branched or cyclic alkyl group having 1-8 C atoms, and R in each case is identical or different and is a linear, branched or cyclic alkyl group having 1-8 C atoms or an aryl group; and wherein HX is an acid, wherein X is an inorganic or organic acid radical, and 0≦y≦1, 0≦z≦1, a>0, b>0, c≧0, d≧0, e≧0, and (a+b+c+d)≧2, the composition being essentially free from organic solvents, having a flash point of more than 70° C. and liberating essentially no alcohols by hydrolysis on dilution with water.

Claim 15

A method of protecting buildings and facades, comprising: treating buildings or facades with an aqueous organopolysiloxane-containing composition comprising: organopolysiloxanes of formula I HO{Si(A)(CH.sub.3).sub.z (OH).sub.1-z O}.sub.3 {Si(B)(R.sup.2).sub.y (OH).sub.1-y O}.sub.b {Si(C)(CH.sub.3)O}.sub.c {Si(D)(OH)O}.sub.d H.(HX).sub.c (I), wherein A is an aminoalkyl group of formula II; H.sub.2 N(CH.sub.2).sub.f (NH).sub.g (CH.sub.2).sub.h Si(OR).sub.3-z (CH.sub.3).sub.z (II), in which 0≦f≦6, g=0 if f=0 and g=1 if f>0, 0≦h≦6 and 0≦z≦1; B is a fluoroalkyl group of formula III: R.sup.1 --Y--(CH.sub.2).sub.2 Si(R.sup.2).sub.y (OR).sub.3-y(III), wherein R 1 is a mono- oligo- or perfluorinated alkyl group having 1-9 C atoms or a mono-, oligo- or perfluorinated aryl group, Y is a CH 2 , O or S group, R 2 is a linear, branched or cyclic alkyl group having 1-8 C atoms or an aryl group and 0≦y≦1; C is an alkyl group of formula IV: R.sup.3 --Si(CH.sub.3)(OR).sub.2 (IV), and D is an alkyl group of formula V: R.sup.3 --Si(OR).sub.3 (V) wherein R 3 in each case is identical or different and is a linear, branched or cyclic alkyl group having 1-8 C atoms, and R in each case is identical or different and is a linear, branched or cyclic alkyl group having 1-8 C atoms or an aryl group; and wherein HX is an acid, wherein X is an inorganic or organic acid radical, and 0≦y≦1, 0≦z≦1, a>0, b>0, c≧0, d≧0, e≧0, and (a+b+c+d)≧2, the composition being essentially free from organic solvents, having a flash point of more than 70° C. and liberating essentially no alcohols by hydrolysis on dilution with water.

Claim 16

A method of coating glass fibers, comprising: coating glass fibers with an aqueous organopolysiloxane-containing composition comprising: organopolysiloxanes of formula I: HO{Si(A)(CH.sub.3).sub.z (OH).sub.1-z O}.sub.3 {Si(B)(R.sup.2).sub.y (OH).sub.1-y O}.sub.b {Si(C)(CH.sub.3)O}.sub.c {Si(D)(OH)O}.sub.d H.(HX).sub.c (I), wherein A is an aminoalkyl group of formula II: H.sub.2 N(CH.sub.2).sub.f (NH).sub.g (CH.sub.2).sub.h Si(OR).sub.3-z (CH.sub.3).sub.z (II), in which 0≦f≦6, g=0 if f=0 and g=1 if f>0, 0≦h≦6 and 0≦z≦1; B is a fluoroalkyl group of formula III: R.sup.1 --Y--(CH.sub.2).sub.2 Si(R.sup.2).sub.y (OR).sub.3-y(III), wherein R 1 is a mono-, oligo- or perfluorinated alkyl group having 1-9 C atoms or a mono-, oligo- or pentfluorinated aryl group, Y is a CH 2 , O or S group, R 2 is a linear, branched or cyclic alkyl group having 1-8 C atoms or an aryl group and 0≦y≦1; C is an alkyl group of formula IV: R.sup.3 --Si(CH.sub.3)(OR).sub.2 (IV), and D is an alkyl group of formula V: R.sup.3 --Si(OR).sub.3 (V) wherein R 3 in each case is identical or different and is a linear, branched or cyclic alkyl group having 1-8 C atoms, and R in each case is identical or different and is a linear, branched or cyclic alkyl group having 1-8 C atoms or an aryl group; and wherein HX is an acid, wherein X is an inorganic or organic acid radical, and 0≦y≦1, 0≦z≦1, a>0, b>0, c≧0, d≧0, e≧0 and (a+b+c+d)≧2, the composition being essentially free from organic solvents, having a flash point of more than 70° C. and liberating essentially no alcohols by hydrolysis on dilution with water.

Claim 17

A method of coating glass fibers, comprising: coating glass fibers with an aqueous organopolysiloxane-containing composition comprising: organopolysiloxanes of formula I: HO{Si(A)(CH.sub.3).sub.z (OH).sub.1-z O}.sub.3 {Si(B)(R.sup.2).sub.y (OH).sub.1-y O}.sub.b {Si(C)(CH.sub.3)O}.sub.c {Si(D)(OH)O}.sub.d H.(HX).sub.c (I), wherein A is an aminoalkyl group of formula II: H.sub.2 N(CH.sub.2).sub.f (NH).sub.g (CH.sub.2).sub.h Si(OR).sub.3-z (CH.sub.3).sub.z (II), in which 0≦f≦6, g=0 if f=0 and g=1 if f>0, 0≦h≦6 and 0≦z≦1; B is a fluoroalkyl group of formula III: R.sup.1 --Y--(CH.sub.2).sub.2 Si(R.sup.2).sub.y (OR).sub.3-y(III), wherein R 1 is a mono-, oligo- or perfluorinated alkyl group having 1-9 C atoms or a mono-, oligo- or pentfluorinated aryl group, Y is a CH 2 , O or S group, R 2 is a linear, branched or cyclic alkyl group having 1-8 C atoms or an aryl group and 0≦y≦1; C is an alkyl group of formula IV: R.sup.3 --Si(CH.sub.3)(OR).sub.2 (IV), and D is an alkyl group of formula V: R.sup.3 --Si(OR).sub.3 (V) wherein R 3 in each case is identical or different and is a linear, branched or cyclic alkyl group having 1-8 C atoms, and R in each case is identical or different and is a linear, branched or cyclic alkyl group having 1-8 C atoms or an aryl group; and wherein HX is an acid, wherein X is an inorganic or organic acid radical, and 0≦y≦1, 0≦z≦1, a>0, b>0, c≧0, d≧0, e≧0 and (a+b+c+d)≧2, the composition being essentially free from organic solvents, having a flash point of more than 70° C. and liberating essentially no alcohols by hydrolysis on dilution with water.

Claim 18

A method of silanizing fillers and pigments, comprising: treating fillers or pigments with an aqueous organopolysiloxane-containing composition comprising: organopolysiloxanes of formula I: HO{Si(A)(CH.sub.3).sub.z (OH).sub.1-z O}.sub.a {Si(B)(R.sup.2).sub.y (OH).sub.1-y O}.sub.b {Si(C)(CH.sub.3 O}.sub.c {Si(D)(OH)O}.sub.d H.(HX).sub.c (I), wherein A is an aminoalkyl group of formula II: H.sub.2 N(CH.sub.2).sub.f (NH).sub.g (CH.sub.2).sub.h Si(OR).sub.3-z (CH.sub.3).sub.z (II), in which 0≦f≦6, g=0 if f=0 and g=1 if f>0, 0≦h≦6 and 0≦z≦1; B is a fluoroalkyl group of formula III: R.sup.1 --Y--(CH.sub.2).sub.2 Si(R.sup.2).sub.y (OR).sub.3-y(III), wherein R 1 is a mono-i, oligo- or perfluorinated alkyl group having 1-9 C atoms or a mono-, oligo- or perfluorinated aryl group, Y is a CH 2 , O or S group, R 2 is a linear, branched or cyclic alkyl group having 1-8 C atoms or an aryl group and 0≦y≦1; C is an alkyl group of formula IV: R.sup.3 --Si(CH.sub.3 (OR).sub.2 (IV), and D is an alkyl group of formula V: R.sup.3 --SI(OR).sub.3 (V) wherein R 3 in each case is identical or different and is a linear, branched or cyclic alkyl group having 1-8 C atoms, and R in each case is identical or different and is a linear, branched or cyclic alkyl group having 1-8 C atoms or an aryl group; and wherein HX is an acid, wherein X is an inorganic or organic acid radical, and 0≦y≦1, 0≦z≦1, a>0, b>0, c≧0, d≧0, e≧0 and (a+b+c+d)≧2, the composition being essentially free from organic solvents, having a flash point of more than 70° C. and liberating essentially no alcohols by hydrolysis on dilution with water.

Claim 19

A method of silanizing fillers and pigments, comprising: treating fillers or pigments with an aqueous organopolysiloxane-containing composition comprising: organopolysiloxanes of formula I: HO{Si(A)(CH.sub.3).sub.z (OH).sub.1-z O}.sub.a {Si(B)(R.sup.2).sub.y (OH).sub.1-y O}.sub.b {Si(C)(CH.sub.3 O}.sub.c {Si(D)(OH)O}.sub.d H.(HX).sub.c (I), wherein A is an aminoalkyl group of formula II: H.sub.2 N(CH.sub.2).sub.f (NH).sub.g (CH.sub.2).sub.h Si(OR).sub.3-z (CH.sub.3).sub.z (II), in which 0≦f≦6, g=0 if f=0 and g=1 if f>0, 0≦h≦6 and 0≦z≦1; B is a fluoroalkyl group of formula III: R.sup.1 --Y--(CH.sub.2).sub.2 Si(R.sup.2).sub.y (OR).sub.3-y(III), wherein R 1 is a mono-i, oligo- or perfluorinated alkyl group having 1-9 C atoms or a mono-, oligo- or perfluorinated aryl group, Y is a CH 2 , O or S group, R 2 is a linear, branched or cyclic alkyl group having 1-8 C atoms or an aryl group and 0≦y≦1; C is an alkyl group of formula IV: R.sup.3 --Si(CH.sub.3 (OR).sub.2 (IV), and D is an alkyl group of formula V: R.sup.3 --SI(OR).sub.3 (V) wherein R 3 in each case is identical or different and is a linear, branched or cyclic alkyl group having 1-8 C atoms, and R in each case is identical or different and is a linear, branched or cyclic alkyl group having 1-8 C atoms or an aryl group; and wherein HX is an acid, wherein X is an inorganic or organic acid radical, and 0≦y≦1, 0≦z≦1, a>0, b>0, c≧0, d≧0, e≧0 and (a+b+c+d)≧2, the composition being essentially free from organic solvents, having a flash point of more than 70° C. and liberating essentially no alcohols by hydrolysis on dilution with water.

Claim 20

A method of improving the rheological properties of polymer dispersions and emulsions, comprising: adding an aqueous organopolysiloxane-containing composition comprising: organopolysiloxanes of formula I: HO{Si(A)(CH.sub.3).sub.z (OH).sub.1-z O}.sub.3 {Si(B)(R.sup.2).sub.y (OH).sub.1-y O}.sub.b {Si(C)(CH.sub.3)O}.sub.c {Si(D)(OH)O}.sub.d H.(HX).sub.e (I) wherein A is an aminoalkyl group of formula II: H.sub.2 N(CH.sub.2).sub.f (NH).sub.g (CH.sub.2).sub.h Si(OR).sub.3-z (CH.sub.3).sub.z (II), in which 0≦f≦6, g=0 if f=0 and g=1 if f>0, 0≦h≦6 and 0≦z≦1; B is a fluoroalkyl group of formula III: R.sup.1 --Y--(CH.sub.2).sub.2 Si(R.sup.2).sub.y (OR).sub.3-y(III), wherein R 1 is a mono- oligo- or perfluorinated alkyl group having 1-9 C atoms or a mono-, oligo- or perfluorinated aryl group, Y is a CH 2 , O or S group. R 2 is a linear, branched or cyclic alkyl group having 1-8 C atoms or an aryl group and 0≦y≦1; C is an alkyl group of formula IV: R.sup.3 --Si(CH.sub.3) (OR).sub.2 (IV), and D is an alkyl group of formula V: R.sup.3 --Si(OR).sub.3 (V) wherein R 3 in each case is identical or different and is a linear, branched or cyclic alkyl group having 1-8 C atoms, and R in each case is identical or different and is a linear, branched or cyclic alkyl group having 1-8 C atoms or an aryl group; and wherein HX is an acid, wherein X is an inorganic or organic acid radical, and 0≦y≦1, 0≦z≦1, a>0, b>0, c≧0, d≧0, e≧0 and (a+b+c+d)≧2, the composition being essentially free from organic solvents, having a flash point of more than 70° C. and liberating essentially no alcohols by hydrolysis on dilution with water; to polymer dispersions and emulsions.

Claim 21

A method of improving the rheological properties of polymer dispersions and emulsions, comprising: adding an aqueous organopolysiloxane-containing composition comprising: organopolysiloxanes of formula I: HO{Si(A)(CH.sub.3).sub.z (OH).sub.1-z O}.sub.3 {Si(B)(R.sup.2).sub.y (OH).sub.1-y O}.sub.b {Si(C)(CH.sub.3)O}.sub.c {Si(D)(OH)O}.sub.d H.(HX).sub.e (I) wherein A is an aminoalkyl group of formula II: H.sub.2 N(CH.sub.2).sub.f (NH).sub.g (CH.sub.2).sub.h Si(OR).sub.3-z (CH.sub.3).sub.z (II), in which 0≦f≦6, g=0 if f=0 and g=1 if f>0, 0≦h≦6 and 0≦z≦1; B is a fluoroalkyl group of formula III: R.sup.1 --Y--(CH.sub.2).sub.2 Si(R.sup.2).sub.y (OR).sub.3-y(III), wherein R 1 is a mono- oligo- or perfluorinated alkyl group having 1-9 C atoms or a mono-, oligo- or perfluorinated aryl group, Y is a CH 2 , O or S group. R 2 is a linear, branched or cyclic alkyl group having 1-8 C atoms or an aryl group and 0≦y≦1; C is an alkyl group of formula IV: R.sup.3 --Si(CH.sub.3) (OR).sub.2 (IV), and D is an alkyl group of formula V: R.sup.3 --Si(OR).sub.3 (V) wherein R 3 in each case is identical or different and is a linear, branched or cyclic alkyl group having 1-8 C atoms, and R in each case is identical or different and is a linear, branched or cyclic alkyl group having 1-8 C atoms or an aryl group; and wherein HX is an acid, wherein X is an inorganic or organic acid radical, and 0≦y≦1, 0≦z≦1, a>0, b>0, c≧0, d≧0, e≧0 and (a+b+c+d)≧2, the composition being essentially free from organic solvents, having a flash point of more than 70° C. and liberating essentially no alcohols by hydrolysis on dilution with water; to polymer dispersions and emulsions.

Claim 22

A method of hydrophobizing and oleophobizing textiles, leather, cellulose and starch products, comprising: treating textiles, leather, cellulose and starch products with an aqueous organopolysiloxane-containing composition comprising: organopolysiloxanes of formula I: HO{Si(A)(CH.sub.3).sub.z (OH).sub.1-z O}.sub.3 {Si(B)(R.sup.2).sub.y (OH).sub.1-y O}.sub.b {Si(C)(CH.sub.3)O}.sub.c {Si(D)(OH)O}.sub.d H.(HX).sub.c (I), wherein A is an aminoalkyl group of formula II: H.sub.2 N(CH.sub.2).sub.f (NH).sub.g (CH.sub.2).sub.h Si(OR).sub.3-z (CH.sub.3).sub.z (II), in which 0≦f≦6, g=0 if f=0 and g=1 if f>0, 0≦h≦6 and 0≦z≦1; B is a fluoroalkyl group of formula III: R.sup.1 --Y--(CH.sub.2).sub.2 Si(R.sup.2).sub.y (OR).sub.3-y(III), wherein R 1 is a mono-, oligo- or perfluorinated alkyl group having 1-9 C atoms or a mono-, oligo- or perfluorinated aryl group, Y is a CH 2 , O or S group, R 2 is a linear, branched or cyclic alkyl group having 1-8 C atoms or an aryl group and 0≦y≦1; C is an alkyl group of formula IV: R.sup.3 --Si(CH.sub.3)(OR).sub.2 (IV), and D is an alkyl group of formula V: R.sup.3 --Si(OR).sub.3 (V) wherein R 3 in each case is identical or different and is a linear, branched or cyclic alkyl group having 1-8 C atoms, and R in each case is identical or different and is a linear, branched or cyclic alkyl group having 1-8 C atoms or an aryl group; and wherein HX is an acid, wherein X is an inorganic or organic acid radical, and 0≦y≦1, 0≦z≦1, a>0, b>0, c≧0, d≧0, e≧0 and (a+b+c+d)≧2, the composition being essentially free from organic solvents, having a flash point of more than 70° C. and liberating essentially no alcohols by hydrolysis on dilution with water; and achieving a dirt- and color-repellent effect.

Claim 23

A method of hydrophobizing and oleophobizing textiles, leather, cellulose and starch products, comprising: treating textiles, leather, cellulose and starch products with an aqueous organopolysiloxane-containing composition comprising: organopolysiloxanes of formula I: HO{Si(A)(CH.sub.3).sub.z (OH).sub.1-z O}.sub.3 {Si(B)(R.sup.2).sub.y (OH).sub.1-y O}.sub.b {Si(C)(CH.sub.3)O}.sub.c {Si(D)(OH)O}.sub.d H.(HX).sub.c (I), wherein A is an aminoalkyl group of formula II: H.sub.2 N(CH.sub.2).sub.f (NH).sub.g (CH.sub.2).sub.h Si(OR).sub.3-z (CH.sub.3).sub.z (II), in which 0≦f≦6, g=0 if f=0 and g=1 if f>0, 0≦h≦6 and 0≦z≦1; B is a fluoroalkyl group of formula III: R.sup.1 --Y--(CH.sub.2).sub.2 Si(R.sup.2).sub.y (OR).sub.3-y(III), wherein R 1 is a mono-, oligo- or perfluorinated alkyl group having 1-9 C atoms or a mono-, oligo- or perfluorinated aryl group, Y is a CH 2 , O or S group, R 2 is a linear, branched or cyclic alkyl group having 1-8 C atoms or an aryl group and 0≦y≦1; C is an alkyl group of formula IV: R.sup.3 --Si(CH.sub.3)(OR).sub.2 (IV), and D is an alkyl group of formula V: R.sup.3 --Si(OR).sub.3 (V) wherein R 3 in each case is identical or different and is a linear, branched or cyclic alkyl group having 1-8 C atoms, and R in each case is identical or different and is a linear, branched or cyclic alkyl group having 1-8 C atoms or an aryl group; and wherein HX is an acid, wherein X is an inorganic or organic acid radical, and 0≦y≦1, 0≦z≦1, a>0, b>0, c≧0, d≧0, e≧0 and (a+b+c+d)≧2, the composition being essentially free from organic solvents, having a flash point of more than 70° C. and liberating essentially no alcohols by hydrolysis on dilution with water; and achieving a dirt- and color-repellent effect.

Claim 24

A method of releasing one surface from another, comprising: treating contacting surfaces with an aqueous organopolysiloxane-containing composition comprising organopolysiloxanes of formula I: HO{Si(A)(CH.sub.3).sub.z (OH).sub.1-z O}.sub.a {Si(B)(R.sup.2).sub.y (OH).sub.1-y O}.sub.b {Si(C)(CH.sub.3)O}.sub.c {Si(D)(OH)O}.sub.d H.(HX).sub.e (I), wherein A is an aminoalkyl group of formula II: H.sub.2 N(CH.sub.2).sub.f (NH).sub.g (CH.sub.2).sub.h Si(OR).sub.3-z (CH.sub.3).sub.z (II), in which 0≦f≦6, g =0 if f=0 and g=1 if f>0, 0 ≦h≦6 and 0≦z≦1; B is a fluoroalkyl group of formula III: R.sup.1 --Y--(CH.sub.2).sub.2 Si(R.sup.2).sub.y (OR).sub.3-y(III), wherein R 1 is a mono-, oligo- or perfluorinated alkyl group having 1-9 C atoms or a mono-, oligo- or perfluorinated aryl group, Y is a CH 2 , O or S group. R 2 is a linear, branched or cyclic alkyl group having 1-8 C atoms or an aryl group and 0≦y≦1; C is an alkyl group of formula IV: R.sup.3 --Si(CH.sub.3)(OR).sub.2 (IV), and D is an alkyl group of formula V: R.sup.3 --Si(OR).sub.3 (V) wherein R 3 in each case is identical or different and is a linear, branched or cyclic alkyl group having 1-8 C atoms, and R in each case is identical or different and is a linear, branched or cyclic alkyl group having 1-8 C atoms or an aryl group; and wherein HX is an acid, wherein X is an inorganic or organic acid radical, and 0≦y≦1, 0≦z≦1, a>0, b>0, c≧0, d≧0, e≧0 and (a+b+c+d)≧2, the composition being essentially free from organic solvents, having a flash point of more than 70° C. and liberating essentially no alcohols by hydrolysis on dilution with water; as a release agent.

Claim 25

A method of releasing one surface from another, comprising: treating contacting surfaces with an aqueous organopolysiloxane-containing composition comprising organopolysiloxanes of formula I: HO{Si(A)(CH.sub.3).sub.z (OH).sub.1-z O}.sub.a {Si(B)(R.sup.2).sub.y (OH).sub.1-y O}.sub.b {Si(C)(CH.sub.3)O}.sub.c {Si(D)(OH)O}.sub.d H.(HX).sub.e (I), wherein A is an aminoalkyl group of formula II: H.sub.2 N(CH.sub.2).sub.f (NH).sub.g (CH.sub.2).sub.h Si(OR).sub.3-z (CH.sub.3).sub.z (II), in which 0≦f≦6, g =0 if f=0 and g=1 if f>0, 0 ≦h≦6 and 0≦z≦1; B is a fluoroalkyl group of formula III: R.sup.1 --Y--(CH.sub.2).sub.2 Si(R.sup.2).sub.y (OR).sub.3-y(III), wherein R 1 is a mono-, oligo- or perfluorinated alkyl group having 1-9 C atoms or a mono-, oligo- or perfluorinated aryl group, Y is a CH 2 , O or S group. R 2 is a linear, branched or cyclic alkyl group having 1-8 C atoms or an aryl group and 0≦y≦1; C is an alkyl group of formula IV: R.sup.3 --Si(CH.sub.3)(OR).sub.2 (IV), and D is an alkyl group of formula V: R.sup.3 --Si(OR).sub.3 (V) wherein R 3 in each case is identical or different and is a linear, branched or cyclic alkyl group having 1-8 C atoms, and R in each case is identical or different and is a linear, branched or cyclic alkyl group having 1-8 C atoms or an aryl group; and wherein HX is an acid, wherein X is an inorganic or organic acid radical, and 0≦y≦1, 0≦z≦1, a>0, b>0, c≧0, d≧0, e≧0 and (a+b+c+d)≧2, the composition being essentially free from organic solvents, having a flash point of more than 70° C. and liberating essentially no alcohols by hydrolysis on dilution with water; as a release agent.

Claim 26

A method of formulating a polymer composition, comprising: incorporating an aqueous organopolysiloxane-containing composition comprising: organopolysiloxanes of formula I: HO{Si(A)(CH.sub.3).sub.z (OH).sub.1-z O}.sub.a {Si(B)(R.sup.2).sub.y (OH).sub.1-y O}.sub.b {Si(C)(CH.sub.3)O}.sub.c {Si(D)(OH)O}.sub.d H.(HX).sub.e (I), wherein A is an aminoalkyl group of formula II: H.sub.2 N(CH.sub.2).sub.f (NH).sub.g (CH.sub.2).sub.h Si(OR).sub.3-2 (CH.sub.3).sub.z (II), in which 0≦f≦6, g=0 if f=0 and g=1 if f>0, 0≦h≦6 and 0≦z≦1; B is a fluoroalkyl group of formula III: R.sup.1 --Y--(CH.sub.2).sub.2 Si(R.sup.2).sub.y (OR).sub.3-y(III), wherein R 1 is a mono-, oligo- or perfluorinated alkyl group having 1-9 C atoms or a mono-, oligo- or perfluorinated aryl group, Y is a CH 2 , O or S group, R 2 is a linear, branched or cyclic alkyl group having 1-8 C atoms or an aryl group and 0≦y≦1; C is an alkyl group of formula IV: R.sup.3 --Si(CH.sub.3)(OR).sub.2 (IV), and D is an alkyl group of formula V: R.sup.3 --Si(OR).sub.3 (V) wherein R 3 in each case is identical or different and is a linear, branched or cyclic alkyl group having 1-8 C atoms, and R in each case is identical or different and is a linear, branched or cyclic alkyl group having 1-8 C atoms or an aryl group; and wherein HX is an acid, wherein X is an inorganic or organic acid radical, and 0≦y≦1, 0≦z≦1, a>0, b>0, c≧0, d≧0, e≧0 and (a+b+c+d)≧2, the composition being essentially free from organic solvents, having a flash point of more than 70° C. and liberating essentially no alcohols by hydrolysis on dilution with water as a cross-linking agent in the composition.

Claim 27

A method of formulating a polymer composition, comprising: incorporating an aqueous organopolysiloxane-containing composition comprising: organopolysiloxanes of formula I: HO{Si(A)(CH.sub.3).sub.z (OH).sub.1-z O}.sub.a {Si(B)(R.sup.2).sub.y (OH).sub.1-y O}.sub.b {Si(C)(CH.sub.3)O}.sub.c {Si(D)(OH)O}.sub.d H.(HX).sub.e (I), wherein A is an aminoalkyl group of formula II: H.sub.2 N(CH.sub.2).sub.f (NH).sub.g (CH.sub.2).sub.h Si(OR).sub.3-2 (CH.sub.3).sub.z (II), in which 0≦f≦6, g=0 if f=0 and g=1 if f>0, 0≦h≦6 and 0≦z≦1; B is a fluoroalkyl group of formula III: R.sup.1 --Y--(CH.sub.2).sub.2 Si(R.sup.2).sub.y (OR).sub.3-y(III), wherein R 1 is a mono-, oligo- or perfluorinated alkyl group having 1-9 C atoms or a mono-, oligo- or perfluorinated aryl group, Y is a CH 2 , O or S group, R 2 is a linear, branched or cyclic alkyl group having 1-8 C atoms or an aryl group and 0≦y≦1; C is an alkyl group of formula IV: R.sup.3 --Si(CH.sub.3)(OR).sub.2 (IV), and D is an alkyl group of formula V: R.sup.3 --Si(OR).sub.3 (V) wherein R 3 in each case is identical or different and is a linear, branched or cyclic alkyl group having 1-8 C atoms, and R in each case is identical or different and is a linear, branched or cyclic alkyl group having 1-8 C atoms or an aryl group; and wherein HX is an acid, wherein X is an inorganic or organic acid radical, and 0≦y≦1, 0≦z≦1, a>0, b>0, c≧0, d≧0, e≧0 and (a+b+c+d)≧2, the composition being essentially free from organic solvents, having a flash point of more than 70° C. and liberating essentially no alcohols by hydrolysis on dilution with water as a cross-linking agent in the composition.

Claim 28

A method of preparing a paint or coating formulation, comprising: incorporating an aqueous organopolysiloxane-containing composition comprising: organopolysiloxanes of formula I: HO{Si(A)(CH.sub.3).sub.z (OH).sub.1-z O}.sub.a {Si(B)(R.sup.2).sub.y (OH).sub.1-y O}.sub.b {Si(C)(CH.sub.3)O}.sub.c {Si(D)(OH)O}.sub.d H.(HX).sub.e (I), wherein A is an aminoalkyl group of formula II: H.sub.2 N(CH.sub.2).sub.f (NH).sub.g (CH.sub.2).sub.h Si(OR).sub.3-z (CH.sub.3).sub.z (II), in which 0≦f≦6, g=0 if f=0 and g=1 if f>0, 0≦h≦6 and 0≦z≦1: B is a fluoroalkyl group of formula III: R.sup.1 --Y--(CH.sub.2).sub.2 Si(R.sup.2).sub.y (OR).sub.3-y(III), wherein R 1 is a mono-, oligo- or perfluorinated alkyl group having 1-9 C atoms or a mono-, oligo- or perfluorinated aryl group, Y is a CH 2 , O or S group. R 2 is a linear, branched or cyclic alkyl group having 1-8 C atoms or an aryl group and 0≦y≦1; C is an alkyl group of formula IV: R.sup.3 --Si(CH.sub.3)(OR).sub.2 (IV), and D is an alkyl group of formula V: R.sup.3 --Si(OR).sub.3 (V) wherein R 3 , in each case is identical or different and is a linear, branched or cyclic alkyl group having 1-8 C atoms, and R, in each case is identical or different, and is a linear, branched or cyclic alkyl group having 1-8 C atoms or an aryl group; and wherein HX is an acid, wherein X is an inorganic or organic acid radical, and 0≦y≦1, 0≦z≦1, a>0, b>0, c≧0, d≧0, e≧0 and (a+b+c+d)≧2, the composition being essentially free from organic solvents, having a flash point of more than 70° C. and liberating essentially no alcohols by hydrolysis on dilution with water in a paint or coating formulation.

Claim 29

A method of preparing a paint or coating formulation, comprising: incorporating an aqueous organopolysiloxane-containing composition comprising: organopolysiloxanes of formula I: HO{Si(A)(CH.sub.3).sub.z (OH).sub.1-z O}.sub.a {Si(B)(R.sup.2).sub.y (OH).sub.1-y O}.sub.b {Si(C)(CH.sub.3)O}.sub.c {Si(D)(OH)O}.sub.d H.(HX).sub.e (I), wherein A is an aminoalkyl group of formula II: H.sub.2 N(CH.sub.2).sub.f (NH).sub.g (CH.sub.2).sub.h Si(OR).sub.3-z (CH.sub.3).sub.z (II), in which 0≦f≦6, g=0 if f=0 and g=1 if f>0, 0≦h≦6 and 0≦z≦1: B is a fluoroalkyl group of formula III: R.sup.1 --Y--(CH.sub.2).sub.2 Si(R.sup.2).sub.y (OR).sub.3-y(III), wherein R 1 is a mono-, oligo- or perfluorinated alkyl group having 1-9 C atoms or a mono-, oligo- or perfluorinated aryl group, Y is a CH 2 , O or S group. R 2 is a linear, branched or cyclic alkyl group having 1-8 C atoms or an aryl group and 0≦y≦1; C is an alkyl group of formula IV: R.sup.3 --Si(CH.sub.3)(OR).sub.2 (IV), and D is an alkyl group of formula V: R.sup.3 --Si(OR).sub.3 (V) wherein R 3 , in each case is identical or different and is a linear, branched or cyclic alkyl group having 1-8 C atoms, and R, in each case is identical or different, and is a linear, branched or cyclic alkyl group having 1-8 C atoms or an aryl group; and wherein HX is an acid, wherein X is an inorganic or organic acid radical, and 0≦y≦1, 0≦z≦1, a>0, b>0, c≧0, d≧0, e≧0 and (a+b+c+d)≧2, the composition being essentially free from organic solvents, having a flash point of more than 70° C. and liberating essentially no alcohols by hydrolysis on dilution with water in a paint or coating formulation.

Claim 30

A method of promoting adhesion of an adhesive substance, comprising: incorporating an aqueous organopolysiloxane-containing composition comprising: organopolysiloxanes of formula I: HO{Si(A)(CH.sub.3).sub.z (OH).sub.1-z O}.sub.a {Si(B)(R.sup.2).sub.y (OH).sub.1-y)}.sub.b {Si(C)(CH.sub.3)O}.sub.c {Si(D)(OH)O}.sub.d H.(HX).sub.e (I), wherein A is an aminoalkyl group of formula II: H.sub.2 N(CH.sub.2).sub.f (NH).sub.g (CH.sub.2).sub.h Si(OR).sub.3-z (CH.sub.3).sub.z (II), in which 0≦f≦6, g=0 if f=0 and g=1 if f>0, 0≦h≦6 and 0≦z≦1; B is a fluoroalkyl group of formula III: R.sup.1 --Y--(CH.sub.2).sub.2 Si(R.sup.2).sub.y (OR).sub.3-y(III), wherein R 1 is a mono-, oligo- or perfluorinated alkyl group having 1-9 C atoms or a mono-, oligo- or perfluorinated aryl group, Y is a CH 2 , O or S group, R 2 is a linear, branched or cyclic alkyl group having 1-8 C atoms or an aryl group and 0≦y≦1; C is an alkyl group of formula IV: R.sup.3 --Si(CH.sub.3)(OR).sub.2 (IV), and D is an alkyl group of formula V: R.sup.3 --Si(OR).sub.3 (V) wherein R 3 in each case is identical or different and is a linear, branched or cyclic alkyl group having 1-8 C atoms, and R in each case is identical or different and is a linear, branched or cyclic alkyl group having 1-8 C atoms or an aryl group; and wherein HX is an acid, wherein X is an inorganic or organic acid radical, and 0≦y≦1, 0≦z≦1, a>0, b>0, c≧0, d≧0, e≧0 and (a+b+c+d)≧2, the composition being essentially free from organic solvents, having a flash point of more than 70° C. and liberating essentially no alcohols by hydrolysis on dilution with water into an adhesive formulation.

Claim 31

A method of promoting adhesion of an adhesive substance, comprising: incorporating an aqueous organopolysiloxane-containing composition comprising: organopolysiloxanes of formula I: HO{Si(A)(CH.sub.3).sub.z (OH).sub.1-z O}.sub.a {Si(B)(R.sup.2).sub.y (OH).sub.1-y)}.sub.b {Si(C)(CH.sub.3)O}.sub.c {Si(D)(OH)O}.sub.d H.(HX).sub.e (I), wherein A is an aminoalkyl group of formula II: H.sub.2 N(CH.sub.2).sub.f (NH).sub.g (CH.sub.2).sub.h Si(OR).sub.3-z (CH.sub.3).sub.z (II), in which 0≦f≦6, g=0 if f=0 and g=1 if f>0, 0≦h≦6 and 0≦z≦1; B is a fluoroalkyl group of formula III: R.sup.1 --Y--(CH.sub.2).sub.2 Si(R.sup.2).sub.y (OR).sub.3-y(III), wherein R 1 is a mono-, oligo- or perfluorinated alkyl group having 1-9 C atoms or a mono-, oligo- or perfluorinated aryl group, Y is a CH 2 , O or S group, R 2 is a linear, branched or cyclic alkyl group having 1-8 C atoms or an aryl group and 0≦y≦1; C is an alkyl group of formula IV: R.sup.3 --Si(CH.sub.3)(OR).sub.2 (IV), and D is an alkyl group of formula V: R.sup.3 --Si(OR).sub.3 (V) wherein R 3 in each case is identical or different and is a linear, branched or cyclic alkyl group having 1-8 C atoms, and R in each case is identical or different and is a linear, branched or cyclic alkyl group having 1-8 C atoms or an aryl group; and wherein HX is an acid, wherein X is an inorganic or organic acid radical, and 0≦y≦1, 0≦z≦1, a>0, b>0, c≧0, d≧0, e≧0 and (a+b+c+d)≧2, the composition being essentially free from organic solvents, having a flash point of more than 70° C. and liberating essentially no alcohols by hydrolysis on dilution with water into an adhesive formulation.